The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Understanding the Fast Pyrolysis of Lignin
Abstract
In the present study, pyrolysis of corn stover lignin was investigated by using a micro‐pyrolyzer coupled with a GC–MS/FID (FID=flame ionization detector). The system has pyrolysis‐vapor residence times of 15–20 ms, thus providing a regime of minimal secondary reactions. The primary pyrolysis product distribution obtained from lignin is reported. Over 84 % mass balance and almost complete closure on carbon balance is achieved. In another set of experiments, the pyrolysis vapors emerging from the micro‐pyrolyzer are condensed to obtain lignin‐derived bio‐oil. The chemical composition of the bio‐oil is analyzed by using GC–MS and gel permeation chromatography techniques. The comparison between results of two sets of experiments indicates that monomeric compounds are the primary pyrolysis products of lignin, which recombine after primary pyrolysis to produce oligomeric compounds. Further, the effect of minerals (NaCl, KCl, MgCl 2, and CaCl 2) and temperature on the primary pyrolysis product distribution is investigated. The study provides insights into the fundamental mechanisms of lignin pyrolysis and a basis for developing more descriptive models of biomass pyrolysis.
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Cites
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Cited by
Catalytic Transformation of Lignin for the Production of Chemicals and Fuels
Li, C., Zhao, X., Wang, A., Huber, G. W., & Zhang, T. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00155 · Cited by 2,951
Distinguishing primary and secondary reactions of cellulose pyrolysis
Patwardhan, P. R., Dalluge, D. L., Shanks, B. H., & Brown, R. C. (2011) · Bioresource Technology · doi:10.1016/j.biortech.2011.02.018 · Cited by 352
Self-citationPyrolysis behaviors of four lignin polymers isolated from the same pine wood
Wang, S., Ru, B., Lin, H., Sun, W., & Luo, Z. (2015) · Bioresource Technology · doi:10.1016/j.biortech.2015.01.127 · Cited by 348
Leng, E., Guo, Y., Chen, J., Liu, S., E, J., & Xue, Y. (2022) · Fuel · doi:10.1016/j.fuel.2021.122102 · Cited by 286
Bio-oil from fast pyrolysis of lignin: Effects of process and upgrading parameters
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Metadata
- Authors
- Patwardhan, P. R., Brown, R. C., & Shanks, B. H.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2011-09-21
- Volume
- 4
- Issue
- 11
- Pages
- 1629-1636
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2112851854
- Cited by
- 468
- References
- 7
- FWCI
- 11.30
- Type
- journal article
- Language
- en
- Open access
- closed
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