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Understanding the Fast Pyrolysis of Lignin
Abstract
In the present study, pyrolysis of corn stover lignin was investigated by using a micro‐pyrolyzer coupled with a GC–MS/FID (FID=flame ionization detector). The system has pyrolysis‐vapor residence times of 15–20 ms, thus providing a regime of minimal secondary reactions. The primary pyrolysis product distribution obtained from lignin is reported. Over 84 % mass balance and almost complete closure on carbon balance is achieved. In another set of experiments, the pyrolysis vapors emerging from the micro‐pyrolyzer are condensed to obtain lignin‐derived bio‐oil. The chemical composition of the bio‐oil is analyzed by using GC–MS and gel permeation chromatography techniques. The comparison between results of two sets of experiments indicates that monomeric compounds are the primary pyrolysis products of lignin, which recombine after primary pyrolysis to produce oligomeric compounds. Further, the effect of minerals (NaCl, KCl, MgCl 2, and CaCl 2) and temperature on the primary pyrolysis product distribution is investigated. The study provides insights into the fundamental mechanisms of lignin pyrolysis and a basis for developing more descriptive models of biomass pyrolysis.
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Citations
Cites
Characteristics of hemicellulose, cellulose and lignin pyrolysis
Yang, H., Yan, R., Chen, H., Lee, D. H., & Zheng, C. (2007) · Fuel · doi:10.1016/j.fuel.2006.12.013 · Cited by 8,155
The Catalytic Valorization of Lignin for the Production of Renewable Chemicals
Zakzeski, J., Bruijnincx, P. C. A., Jongerius, A. L., & Weckhuysen, B. M. (2010) · Chemical Reviews · doi:10.1021/cr900354u · Cited by 4,468
Holladay, J. E., White, J. F., Bozell, J. J., & Johnson, D. (2007) · doi:10.2172/921839 · Cited by 905
Influence of inorganic salts on the primary pyrolysis products of cellulose
Patwardhan, P. R., Satrio, J. A., Brown, R. C., & Shanks, B. H. (2010) · Bioresource Technology · doi:10.1016/j.biortech.2010.01.112 · Cited by 799
Self-citationA systematic study of the kinetics of lignin pyrolysis
Jiang, G., Nowakowski, D. J., & Bridgwater, A. V. (2010) · Thermochimica Acta · doi:10.1016/j.tca.2009.10.003 · Cited by 352
Effect of the Temperature on the Composition of Lignin Pyrolysis Products
Jiang, G., Nowakowski, D. J., & Bridgwater, A. V. (2010) · Energy & Fuels · doi:10.1021/ef100363c · Cited by 332
Pyrolysis of Lignins: Experimental and Kinetics Studies
Ferdous, D., Dalai, A. K., Bej, S. K., & Thring, R. W. (2002) · Energy & Fuels · doi:10.1021/ef0200323 · Cited by 310
Garcia-Perez, M., Wang, S., Shen, J., Rhodes, M., Lee, W. J., & Li, C.-Z. (2008) · Energy & Fuels · doi:10.1021/ef7007634 · Cited by 235
Murugan, P., Mahinpey, N., Johnson, K. E., & Wilson, M. (2008) · Energy & Fuels · doi:10.1021/ef700730u · Cited by 86
Research works printed but not linked: 32
- 10.1002/ange.200604504 · DOI
- 10.1002/anie.200604504 · DOI · Paper page
- T. Marker J. Petri T. Kalnes M. McCall D. Mackowiak B. Jerosky B. Reagan L. Nemeth M. Krawczyk S. Czernik D. Elliott D. Shonnard Opportunities for Biorenewables in Oil Refineries U. S. Department of Energy Des Plaines IL 2004. · DOI
- 10.1016/j.jaap.2009.08.007 · DOI · Paper page
- P. R. Patwardhan J. A. Satrio R. C. Brown B. H. Shanks AIChE Conference Nashville Tennessee.2009.
- 10.1021/bk-2000-0742.ch015 · DOI · Paper page
- 10.1002/app.1970.070140518 · DOI · Paper page
- 10.1016/0040-6031(85)87093-3 · DOI
- 10.1016/j.indcrop.2007.07.006 · DOI · Paper page
- 10.1021/ie8013605 · DOI
- 10.1016/S0360-5442(98)00037-1 · DOI
- 10.1007/BF00353322 · DOI
- 10.1021/jf00106a042 · DOI
- 10.1016/j.jaap.2008.03.007 · DOI · Paper page
- 10.1016/S0040-6031(97)00059-2 · DOI · Paper page
- 10.1016/0165-2370(87)85044-1 · DOI
- 10.1080/02773818308085170 · DOI
- 10.1016/S0146-6380(86)80024-9 · DOI · Paper page
- 10.1016/S0165-2370(96)00965-5 · DOI
- 10.1016/0165-2370(86)80012-2 · DOI · Paper page
- 10.1016/S0960-8524(00)00180-2 · DOI · Paper page
- 10.1016/S0961-9534(97)10024-1 · DOI · Paper page
- 10.1016/S0165-2370(00)00173-X · DOI · Paper page
- 10.1021/la051990a · DOI
- 10.1021/bk-1977-0043.ch005 · DOI · Paper page
- Daugaard D. E., 2006, The Transport Phase of Pyrolytic Oil Exiting a Fluidized Bed Reactor, in Proceedings of Science in Thermal and Chemical Biomass Conversion, 1189
- Piskorz J. M., 1999, Pyrolysis of Biomass–Aerosol Generation: Properties, Applications and Significance for Process Engineers, in Biomass: A Growth Opportunity in Green Energy and Value‐Added Products Vol. 2, 1153
- 10.1021/es034672b · doi:10.1021/es034672b
- 10.1021/es950943 · doi:10.1021/es950943
- 10.1080/02773810701515143 · DOI
- 10.1205/095758204322777651 · doi:10.1205/095758204322777651
- 10.1021/bp034054z · DOI
Cited by
Catalytic Transformation of Lignin for the Production of Chemicals and Fuels
Li, C., Zhao, X., Wang, A., Huber, G. W., & Zhang, T. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00155 · Cited by 2,951
Distinguishing primary and secondary reactions of cellulose pyrolysis
Patwardhan, P. R., Dalluge, D. L., Shanks, B. H., & Brown, R. C. (2011) · Bioresource Technology · doi:10.1016/j.biortech.2011.02.018 · Cited by 352
Self-citationPyrolysis behaviors of four lignin polymers isolated from the same pine wood
Wang, S., Ru, B., Lin, H., Sun, W., & Luo, Z. (2015) · Bioresource Technology · doi:10.1016/j.biortech.2015.01.127 · Cited by 348
Leng, E., Guo, Y., Chen, J., Liu, S., E, J., & Xue, Y. (2022) · Fuel · doi:10.1016/j.fuel.2021.122102 · Cited by 286
Bio-oil from fast pyrolysis of lignin: Effects of process and upgrading parameters
Fan, L., Zhang, Y., Liu, S., Zhou, N., Chen, P., Cheng, Y., Addy, M., Lu, Q., Omar, M. M., Liu, Y., et al. (2017) · Bioresource Technology · doi:10.1016/j.biortech.2017.05.129 · Cited by 265
Dai, L., Wang, Y., Liu, Y., He, C., Ruan, R., Yu, Z., Jiang, L., Zeng, Z., & Wu, Q. (2020) · Science of The Total Environment · doi:10.1016/j.scitotenv.2020.142386 · Cited by 264
Recent Progress in Quantum Chemistry Modeling on the Pyrolysis Mechanisms of Lignocellulosic Biomass
Hu, B., Zhang, B., Xie, W.-L., Jiang, X.-Y., Liu, J., & Lu, Q. (2020) · Energy & Fuels · doi:10.1021/acs.energyfuels.0c01948 · Cited by 161
Figueirêdo, M. B., Hita, I., Deuss, P. J., Venderbosch, R. H., & Heeres, H. J. (2022) · Green Chemistry · doi:10.1039/d2gc00302c · Cited by 146
Fast Pyrolysis of Four Lignins from Different Isolation Processes Using Py-GC/MS
Lin, X., Sui, S., Tan, S., Pittman, C., Sun, J., & Zhang, Z. (2015) · Energies · doi:10.3390/en8065107 · Cited by 114
Yang, M., Shao, J., Yang, Z., Yang, H., Wang, X., Wu, Z., & Chen, H. (2019) · Journal of Analytical and Applied Pyrolysis · doi:10.1016/j.jaap.2018.12.003 · Cited by 95
Wang, T.-P., Li, H., Yuan, J.-M., Li, W.-X., Li, K., Huang, Y.-B., Xiao, L.-P., & Lu, Q. (2021) · Industrial Crops and Products · doi:10.1016/j.indcrop.2021.113912 · Cited by 92
Dalluge, D. L., Kim, K. H., & Brown, R. C. (2017) · Journal of Analytical and Applied Pyrolysis · doi:10.1016/j.jaap.2017.07.011 · Cited by 88
Self-citationOjha, D. K., Viju, D., & Vinu, R. (2017) · Bioresource Technology · doi:10.1016/j.biortech.2017.05.084 · Cited by 81
Fast pyrolysis of lignins with different molecular weight: Experiments and modelling
Marathe, P. S., Westerhof, R. J. M., & Kersten, S. R. A. (2019) · Applied Energy · doi:10.1016/j.apenergy.2018.12.058 · Cited by 71
Wang, C., Xia, S., Cui, C., Kang, S., Zheng, A., Yu, Z., & Zhao, Z. (2022) · Fuel · doi:10.1016/j.fuel.2022.125215 · Cited by 62
Identifying the primary reactions and products of fast pyrolysis of alkali lignin
Supriyanto, Usino, D. O., Ylitervo, P., Dou, J., Sipponen, M. H., & Richards, T. (2020) · Journal of Analytical and Applied Pyrolysis · doi:10.1016/j.jaap.2020.104917 · Cited by 54
Jampa, S., Puente-Urbina, A., Ma, Z., Wongkasemjit, S., Luterbacher, J. S., & van Bokhoven, J. A. (2019) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b05498 · Cited by 45
Thermal degradation of lignins fractionated by gradient acid precipitation
Cao, X., Shao, L., Huang, W., Wang, C., Mao, J., Xu, F., & Zhang, X. (2021) · Journal of Analytical and Applied Pyrolysis · doi:10.1016/j.jaap.2021.105200 · Cited by 25
Wu, S., Shen, D., Hu, J., Zhang, H., & Xiao, R. (2014) · BioResources · doi:10.15376/biores.9.2.2259-2273 · Cited by 22
Wörner, M., Werner, L., Hornung, U., Islongo Canabarro, N., Baudouin, D., & Dahmen, N. (2024) · Energy & Fuels · doi:10.1021/acs.energyfuels.3c04737 · Cited by 21
Metadata
- Authors
- Patwardhan, P. R., Brown, R. C., & Shanks, B. H.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2011-09-21
- Volume
- 4
- Issue
- 11
- Pages
- 1629-1636
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2112851854
- Cited by
- 468
- References
- 9
- FWCI
- 11.30
- Type
- journal article
- Language
- en
- Open access
- closed
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