The DOI matches its Crossref record; 141 of the 141 references it cites were found in a registry or an index.
Synthesis of Cyclic Carbonates from Epoxides and Carbon Dioxide by Using Organocatalysts
Abstract
The synthesis of cyclic carbonates through coupling of carbon dioxide with epoxides is 100 % atom economical and is already performed on an industrial scale. Its impact regarding the use of carbon dioxide as a renewable carbon source is expected to grow significantly in the near future, so that the development of efficient catalysts is of high interest in academia and industry. To improve the carbon footprint and sustainability of the cycloaddition reaction, the use of organocatalytic methods is a promising approach. Herein, available metal‐free catalysts for the preparation of cyclic carbonates are described and elaborated concerning the overall sustainability of the process. Therefore, the required reaction conditions, as well as the activity of the catalysts and their reusability, are compared and evaluated. In addition to ammonium‐, phosphonium‐, or imidazolium‐based single‐component catalysts and their supported analogues, the growing field of research concerning dual catalysts are also discussed in detail.
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Cites
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Self-citationUtilisation of CO2 as a chemical feedstock: opportunities and challenges
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Synthesis of cyclic carbonates from epoxides and CO2
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Cited by
Recent advances in the synthesis of cyclic carbonates via CO2 cycloaddition to epoxides
Rehman, A., Saleem, F., Javed, F., Ikhlaq, A., Ahmad, S. W., & Harvey, A. (2021) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2021.105113 · Cited by 281
The greening of peptide synthesis
Lawrenson, S. B., Arav, R., & North, M. (2017) · Green Chemistry · doi:10.1039/c7gc00247e · Cited by 205
Green catalytic process for cyclic carbonate synthesis from carbon dioxide under mild conditions
Lang, X.-D., & He, L.-N. (2016) · The Chemical Record · doi:10.1002/tcr.201500293 · Cited by 122
Metadata
- Authors
- Cokoja, M., Wilhelm, M. E., Anthofer, M. H., Herrmann, W. A., & Kühn, F. E.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2015-06-26
- Volume
- 8
- Issue
- 15
- Pages
- 2436-2454
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W1510168266
- Cited by
- 498
- References
- 141
- FWCI
- 20.45
- Type
- journal article
- Language
- en
- Open access
- closed
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- Cokoja, M., Wilhelm, M. E., Anthofer, M. H., Herrmann, W. A., & Kühn, F. E. (2015). Synthesis of Cyclic Carbonates from Epoxides and Carbon Dioxide by Using Organocatalysts. ChemSusChem. https://doi.org/10.1002/cssc.201500161
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
