Cited by 797Carbon dioxide utilization in catalysisbiodegradable polymer synthesis and propertiesOrganometallic Complex Synthesis and Catalysis

Catalysts for CO 2 /epoxide copolymerisation

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Kember, Michael R., Buchard, Antoine, Williams, Charlotte K.·2011·Chem. Commun.

Abstract

The article reviews recent developments (mostly since 2004 until June 2010) in catalysts for CO(2)/epoxide copolymerisation and in the properties of the polycarbonates.

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  • Switching the epoxide from PO to CHO significantly increases the Tg of polycarbonates from 30-40 °C to 80-120 °C.

    “For example, switching the epoxide from PO to CHO significantly increases the Tg of polycarbonates from 30-40 °C to 80-120 °C.351”

    From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [351]

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Authors
Kember, M. R., Buchard, A., & Williams, C. K.
Affiliations
Imperial College London (GB)
Corresponding author
Williams, Charlotte K.
Venue
Chem. Commun.
Published
2011
Volume
47
Issue
1
Pages
141-163
ISSN
  • 1359-7345 (ISSN-L)
  • 1364-548X
OpenAlex
W1927730430
Cited by
797
References
156
Citations by year
2026: 15 · 2025: 26 · 2024: 29 · 2023: 38 · 2022: 37 · 2021: 43 · 2020: 39 · 2019: 50 · 2018: 52 · 2017: 57 · 2016: 59 · 2015: 92 · 2014: 83 · 2013: 76 · 2012: 61
FWCI
2.39
Type
journal article
Language
en
Open access
Licence
other-oa
Locations
  • Chemical Communications (publishedVersion)
  • PubMed (publishedVersion)
  • The University of Bath Online Publications Store (The University of Bath) (submittedVersion)
  • Pure (University of Bath) (submittedVersion, other-oa)
Funders
  • Leverhulme Trust
  • Engineering and Physical Sciences Research Council (EP/C544838/1, EP/H046380/1, EP/C544846/1)
Topics
  • Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
Keywords
catalysts, polycarbonate, CO2 utilization, epoxides, polymerization catalysts
MeSH terms
Carbon Dioxide, Catalysis, Epoxy Compounds, Esters, Ethylenediamines, Organometallic Compounds

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

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