Catalysts for CO 2 /epoxide copolymerisation
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The article reviews recent developments (mostly since 2004 until June 2010) in catalysts for CO(2)/epoxide copolymerisation and in the properties of the polycarbonates.
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Switching the epoxide from PO to CHO significantly increases the Tg of polycarbonates from 30-40 °C to 80-120 °C.
“For example, switching the epoxide from PO to CHO significantly increases the Tg of polycarbonates from 30-40 °C to 80-120 °C.351”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [351]
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- Authors
- Kember, M. R., Buchard, A., & Williams, C. K.
- Affiliations
- Imperial College London (GB)
- Corresponding author
- Williams, Charlotte K.
- Venue
- Chem. Commun.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 47
- Issue
- 1
- Pages
- 141-163
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W1927730430
- Cited by
- 797
- References
- 156
- Citations by year
- 2026: 15 · 2025: 26 · 2024: 29 · 2023: 38 · 2022: 37 · 2021: 43 · 2020: 39 · 2019: 50 · 2018: 52 · 2017: 57 · 2016: 59 · 2015: 92 · 2014: 83 · 2013: 76 · 2012: 61
- FWCI
- 2.39
- Type
- journal article
- Language
- en
- Open access
- green
- purehost.bath.ac.uk
- Licence
- other-oa
- Locations
- Chemical Communications (publishedVersion)
- PubMed (publishedVersion)
- The University of Bath Online Publications Store (The University of Bath) (submittedVersion)
- Pure (University of Bath) (submittedVersion, other-oa)
- Funders
- Leverhulme Trust
- Engineering and Physical Sciences Research Council (EP/C544838/1, EP/H046380/1, EP/C544846/1)
- Topics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Keywords
- catalysts, polycarbonate, CO2 utilization, epoxides, polymerization catalysts
- MeSH terms
- Carbon Dioxide, Catalysis, Epoxy Compounds, Esters, Ethylenediamines, Organometallic Compounds
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