The DOI matches its Crossref record; 204 of the 204 references it cites were found in a registry or an index.
Organic Solvent Effects in Biomass Conversion Reactions
Open accessAbstract
Transforming lignocellulosic biomass into fuels and chemicals has been intensely studied in recent years. A large amount of work has been dedicated to finding suitable solvent systems, which can improve the transformation of biomass into value‐added chemicals. These efforts have been undertaken based on numerous research results that have shown that organic solvents can improve both conversion and selectivity of biomass to platform molecules. We present an overview of these organic solvent effects, which are harnessed in biomass conversion processes, including conversion of biomass to sugars, conversion of sugars to furanic compounds, and production of lignin monomers. A special emphasis is placed on comparing the solvent effects on conversion and product selectivity in water with those in organic solvents while discussing the origins of the differences that arise. We have categorized results as benefiting from two major types of effects: solvent effects on solubility of biomass components including cellulose and lignin and solvent effects on chemical thermodynamics including those affecting reactants, intermediates, products, and/or catalysts. Finally, the challenges of using organic solvents in industrial processes are discussed from the perspective of solvent cost, solvent stability, and solvent safety. We suggest that a holistic view of solvent effects, the mechanistic elucidation of these effects, and the careful consideration of the challenges associated with solvent use could assist researchers in choosing and designing improved solvent systems for targeted biomass conversion processes.
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Cites
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Cited by
Miar, M., Shiroudi, A., Pourshamsian, K., Oliaey, A. R., & Hatamjafari, F. (2021) · Journal of Chemical Research · doi:10.1177/1747519820932091 · Cited by 580
Rezania, S., Oryani, B., Cho, J., Talaiekhozani, A., Sabbagh, F., Hashemi, B., Rupani, P. F., & Mohammadi, A. A. (2020) · Energy · doi:10.1016/j.energy.2020.117457 · Cited by 555
Depolymerization of lignin via a non-precious Ni–Fe alloy catalyst supported on activated carbon
Zhai, Y., Li, C., Xu, G., Ma, Y., Liu, X., & Zhang, Y. (2017) · Green Chemistry · doi:10.1039/c7gc00149e · Cited by 249
Molecular-level driving forces in lignocellulosic biomass deconstruction for bioenergy
Petridis, L., & Smith, J. C. (2018) · Nature Reviews Chemistry · doi:10.1038/s41570-018-0050-6 · Cited by 228
Song, B., Lin, R., Lam, C. H., Wu, H., Tsui, T.-H., & Yu, Y. (2021) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2020.110370 · Cited by 186
Zhang, J.-W., Lu, G.-P., & Cai, C. (2017) · Green Chemistry · doi:10.1039/c7gc02087b · Cited by 101
Thermal Liquefaction of Lignin to Aromatics: Efficiency, Selectivity, and Product Analysis
Kozliak, E. I., Kubátová, A., Artemyeva, A. A., Nagel, E., Zhang, C., Rajappagowda, R. B., & Smirnova, A. L. (2016) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.6b01046 · Cited by 98
Metadata
- Authors
- Shuai, L., & Luterbacher, J.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2015-12-16
- Volume
- 9
- Issue
- 2
- Pages
- 133-155
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2219308151
- Cited by
- 445
- References
- 204
- FWCI
- 11.64
- Type
- journal article
- Language
- en
- Open access
- green
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