Enhanced formation of >C1 Products in Electroreduction of CO2 by Adding a CO2 Adsorption Component to a Gas‐Diffusion Layer‐Type Catalytic Electrode
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The addition of a CO 2‐adsorption component (substituted imidazolate‐based SIM‐1 crystals) to a gas‐diffusion layer‐type catalytic electrode enhances the activity and especially the selectivity towards >C1 carbon chain products (ethanol, acetone, and isopropanol) of a Pt‐based electrocatalyst that is not able to form products of CO 2 reduction involving C−C bond formation under conventional (liquid‐phase) conditions. This indicates that the increase of the effective CO 2 concentration at the electrode active surface is the factor controlling the formation of >C1 products rather than only the intrinsic properties of the electrocatalyst.
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AEMs functionalized with imidazolium have been used to produce CO or syngas at moderate (50 mA/cm2) and high current densities ≥100 mA/cm2, operating with high stability for hours, days, and even months.
“For instance, AEMs functionalized with imidazolium have been used to produce CO or syngas at moderate (50 mA/cm 2 ) and high current densities ≥100 mA/cm 2 , operating with high stability for hours, [163] days, [164] and even months.[165]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [163]
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- Authors
- Marepally, B. C., Ampelli, C., Genovese, C., Saboo, T., Perathoner, S., Wisser, F. M., Veyre, L., Canivet, J., Quadrelli, E. A., & Centi, G.
- Affiliations
- Lyon 1 Université (FR)
- University of Messina (IT)
- Corresponding author
- Ampelli, Claudio
- Canivet, Jérôme
- ORCID
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2017-10-09
- Volume
- 10
- Issue
- 22
- Pages
- 4442-4446
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2754657713
- Cited by
- 62
- References
- 25
- Citations by year
- 2025: 4 · 2024: 8 · 2023: 9 · 2022: 8 · 2021: 7 · 2020: 9 · 2019: 13 · 2018: 3 · 2017: 1
- FWCI
- 1.90
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- ChemSusChem (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion)
- Funders
- Education, Audiovisual and Culture Executive Agency (Erasmus+ Action 1 Programme (FPA 2013-0037), SINCHEM Joint Doctorate, Erasmus+ Action 1 Programme, SINCHEM Joint Doctorate)
- Deutsche Forschungsgemeinschaft ((DFG, Postdoctoral Research Fellowship, grant number WI 4721/1-1)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- electroreduction of CO2, CO2 adsorption, platinum electrocatalysts, C–C bond formation, ethanol, acetone, isopropanol, product selectivity
- MeSH terms
- Acetone, Adsorption, Ethanol, Carbon, Carbon Dioxide, Catalysis, Diffusion, Electrodes, Oxidation-Reduction, Platinum, Surface Properties, 2-Propanol, Electrochemical Techniques
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