Recent advances in carboxylation of furoic acid into 2, 5-furandicarboxylic acid: Pathways towards bio-based polymers
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Abstract 2,5‐furandicarboxylic acid (FDCA) is one of the most important bio‐sourced building blocks and several routes have been reported for its synthesis. FDCA is presumed to be an ideal green alternative to terephthalate, which is one of the predominant monomers in polymer industry. This Minireview concerns the synthesis of FDCA by using various carboxylation reactions and discusses the synthesis of FDCA starting from furoic acid and CO 2 and using different catalytic and stoichiometric processes. This process is of high interest, as it avoids the glucose isomerization step and selectivity issues observed during the 5‐hydroxymethylfurfural oxidation step of the current alternative route to FDCA. Discussion focuses on the main parameters that govern selectivity and activity in the carboxylation processes. Moreover, various previously described processes, such as the Henkel reaction and enzymatic, homogeneous catalytic, and photoelectrocatalytic processes, are also discussed.
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2,5-Furandicarboxylic acid (FDCA) is currently recognized as one of the most important bio-based synthons due to its potential application as a monomer to synthesize green polymers, and it has become an ideal green alternative to terephthalate.
“Among them, 2,5-furandicarboxylic acid (FDCA) is currently recognized as one of the most important bio-based synthons due to its potential application as a monomer to synthesize green polymers. Thus, FDCA has become an ideal green alternative to terephthalate (Drault et al., 2020), which is used in the synthesis of one of the most popular thermoplastic polyesters (Intratec, 2017).”
From Biorefineries: Achievements and challenges for a bio-based economy (2022) · cites this paper as Drault et al., 2020
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- Authors
- Drault, F., Snoussi, Y., Paul, S., Itabaiana, I., & Wojcieszak, R.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Universidade Federal do Rio de Janeiro (BR)
- Corresponding author
- Wojcieszak, Robert
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2020-08-17
- Volume
- 13
- Issue
- 19
- Pages
- 5164-5172
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W3046187341
- Cited by
- 60
- References
- 66
- Citations by year
- 2026: 8 · 2025: 12 · 2024: 11 · 2023: 9 · 2022: 12 · 2021: 7 · 2020: 1
- FWCI
- 0.81
- Type
- journal article
- Language
- en
- Open access
- green
- lilloa.hal.science
- Licence
- Locations
- ChemSusChem (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion, other-oa)
- LillOA (Université de Lille (University Of Lille)) (submittedVersion)
- Funders
- Agence Nationale de la Recherche
- Topics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Engineering › Biomedical Engineering › Catalysis for Biomass Conversion
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Keywords
- 2,5-furandicarboxylic acid, furoic acid, carboxylation, bio-based polymers, CO2 utilization, 5-hydroxymethylfurfural oxidation, glucose isomerization, homogeneous catalysis, photoelectrocatalysis, reaction selectivity
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