Iron(II) and Zinc(II) Complexes with Tetradentate Bis(pyrazolyl)methane Ligands as Catalysts for the Ring‐Opening Polymerisation of rac‐Lactide
Abstract
A new subgroup of bis(pyrazolyl)methane ligands has been developed through the synthesis of the first N,N,N,N‐tetradentate bis(pyrazolyl)methane compounds, namely, bis(pyrazolyl)bipyridinylmethane [HC(Pz)2 Bipy, L1] and bis(3,5‐methylpyrazolyl)bipyridinylmethane [HC(3,5‐MePz)2 Bipy, L2]. From these ligands, a large variety of new mononuclear Fe II and Zn II complexes with counterions ranging from halides to carboxylates and sulfate were synthesised and characterised by X‐ray crystallography. The complexes [Fe{HC(Pz)2 Bipy}X 2] (X = Cl–, CF 3 CO 2–, CF 3 SO 3–), [Fe{HC(3,5‐MePz)2 Bipy}X 2] (X = Cl–, CF 3 CO 2–) and [Zn{HC(Pz)2 Bipy}X 2] (X = Cl–, CF 3 CO 2–) were tested in the melt ring‐opening polymerisation of sublimed and unsublimed technical‐grade rac‐lactide at 150 °C. The complex [Fe{HC(Pz)2 Bipy}(CF 3 CO 2)2] showed the most promising results and produced a conversion of 87 % after 30 h with molecular weights of Mw ≈ 30000 g mol–1.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Comparatively little research has been directed at using inexpensive iron catalysts for effective ROP reactions.
“Still, comparatively little research has been directed at using inexpensive iron catalysts for effective ROP reactions.”
Cites
Phase annealing in SHELX-90: direct methods for larger structures
Sheldrick, G. M. (1990) · Acta Crystallographica Section A Foundations of Crystallography · doi:10.1107/s0108767390000277 · Cited by 16,335 · see citing works
Addison, A. W., Rao, T. N., Reedijk, J., Rijn, J. V., & Verschoor, G. C. (1984) · Journal of the Chemical Society Dalton Transactions · doi:10.1039/dt9840001349 · Cited by 9,455 · see citing works
ShelXle : a Qt graphical user interface for SHELXL
Hübschle, C. B., Sheldrick, G. M., & Dittrich, B. (2011) · Journal of Applied Crystallography · doi:10.1107/s0021889811043202 · Cited by 3,830 · see citing works
Controlled Ring-Opening Polymerization of Lactide and Glycolide
Dechy-Cabaret, O., Martin-Vaca, B., & Bourissou, D. (2004) · Chemical Reviews · doi:10.1021/cr040002s · Cited by 2,257 · see citing works
Stereocontrolled ring-opening polymerisation of lactide
Stanford, M. J., & Dove, A. P. (2009) · Chemical Society Reviews · doi:10.1039/b815104k · Cited by 878 · see citing works
Thomas, C. M. (2010) · Chem. Soc. Rev. · doi:10.1039/b810065a · Cited by 853 · see citing works
WU, J., YU, T., CHEN, C., & LIN, C. (2006) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2005.07.010 · Cited by 779 · see citing works
Metal derivatives of poly(pyrazolyl)alkanes☆II. Bis(pyrazolyl)alkanes and related systems
Pettinari, C., & Pettinari, R. (2004) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2004.08.017 · Cited by 380 · see citing works
Novel polypyrazolylborate ligands: coordination control through 3-substituents of the pyrazole ring
Trofimenko, S., Calabrese, J. C., & Thompson, J. S. (1987) · Inorganic Chemistry · doi:10.1021/ic00257a010 · Cited by 345 · see citing works
Discrete Cationic Complexes for Ring-Opening Polymerization Catalysis of Cyclic Esters and Epoxides
Sarazin, Y., & Carpentier, J. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00033 · Cited by 301 · see citing works
O'Keefe, B. J., Breyfogle, L. E., Hillmyer, M. A., & Tolman, W. B. (2002) · Journal of the American Chemical Society · doi:10.1021/ja012689t · Cited by 297 · see citing works
Biernesser, A. B., Li, B., & Byers, J. A. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407920d · Cited by 220 · see citing works
Rapid and Controlled Polymerization of Lactide by Structurally Characterized Ferric Alkoxides
O'Keefe, B. J., Monnier, S. M., Hillmyer, M. A., & Tolman, W. B. (2000) · Journal of the American Chemical Society · doi:10.1021/ja003537l · Cited by 207 · see citing works
Kricheldorf, H. R., & Serra, À. (1985) · Polymer Bulletin · doi:10.1007/bf00271606 · Cited by 189 · see citing works
Otero, A., Fernández‐Baeza, J., Lara‐Sánchez, A., & Sánchez‐Barba, L. F. (2013) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2013.01.027 · Cited by 169 · see citing works
Biernesser, A. B., Delle Chiaie, K. R., Curley, J. B., & Byers, J. A. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201511793 · Cited by 165 · see citing works
Stereoelective polymerization of d,l-lactide using N-heterocyclic carbene based compounds
Jensen, T. R., Breyfogle, L. E., Hillmyer, M. A., & Tolman, W. B. (2004) · Chemical Communications · doi:10.1039/b405362a · Cited by 162 · see citing works
Börner, J., Flörke, Ü., Huber, K. P., Döring, A., Kuckling, D., & Herres‐Pawlis, S. (2009) · Chemistry - A European Journal · doi:10.1002/chem.200802128 · Cited by 158 · see citing works
Self-citationHoffmann, A., Citek, C., Binder, S., Goos, A., Rübhausen, M., Troeppner, O., Ivanović‐Burmazović, I., Wasinger, E. C., Stack, T. D. P., & Herres‐Pawlis, S. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201301249 · Cited by 138 · see citing works
Self-citationZinc N-heterocyclic carbene complexes and their polymerization of d,l-lactide
Jensen, T. R., Schaller, C. P., Hillmyer, M. A., & Tolman, W. B. (2005) · Journal of Organometallic Chemistry · doi:10.1016/j.jorganchem.2005.07.070 · Cited by 133 · see citing works
Bulk Ring-Opening Polymerization of Lactides Initiated by Ferric Alkoxides
Wang, X., Liao, K., Quan, D., & Wu, Q. (2005) · Macromolecules · doi:10.1021/ma047545o · Cited by 126 · see citing works
Tris(pyrazolyl)methanesulfonates: A Novel Class of Water-Soluble Ligands
Kläui, W., Berghahn, M., Rheinwald, G., & Lang, H. (2000) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20000717)39:14 · Cited by 126 · see citing works
Lactide Polymerisation with Complexes of Neutral N‐Donors – New Strategies for Robust Catalysts
Vieira, I. D. S., & Herres‐Pawlis, S. (2012) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201101131 · Cited by 124 · see citing works
Self-citationUse of Monocarboxylic Iron Derivatives in the Ring-Opening Polymerization of <scp>l</scp>-Lactide
Stolt, M., & Södergård, A. (1999) · Macromolecules · doi:10.1021/ma9902753 · Cited by 119 · see citing works
A well-defined iron(ii) alkoxide initiator for the controlled polymerisation of lactide
Gibson, V. C., Marshall, E. L., Navarro-Llobet, D., White, A. J. P., & Williams, D. J. (2002) · Journal of the Chemical Society Dalton Transactions · doi:10.1039/b209703f · Cited by 111 · see citing works
Kricheldorf, H. R., Bornhorst, K., & Hachmann‐Thießen, H. (2005) · Macromolecules · doi:10.1021/ma047873o · Cited by 105 · see citing works
Anionic iron(II) alkoxides as initiators for the controlled ring‐opening polymerization of lactide
McGuinness, D. S., Marshall, E. L., Gibson, V. C., & Steed, J. W. (2003) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.10946 · Cited by 96 · see citing works
Anderson, P. A., Astley, T., Hitchman, M. A., Keene, F. R., Moubaraki, B., Murray, K. S., Skelton, B. W., Tiekink, E. R. T., Toftlund, H., & WHITE, A. H. (2000) · Journal of the Chemical Society Dalton Transactions · doi:10.1039/b003299i · Cited by 88 · see citing works
Mechanism of the Living Lactide Polymerization Mediated by Robust Zinc Guanidine Complexes
Börner, J., dos Santos Vieira, I., Pawlis, A., Döring, A., Kuckling, D., & Herres‐Pawlis, S. (2011) · Chemistry – A European Journal · doi:10.1002/chem.201002690 · Cited by 88 · see citing works
Self-citationBeck, A. K., Barth, A., Hübner, E. G., & Burzlaff, N. I. (2003) · Inorganic Chemistry · doi:10.1021/ic034097c · Cited by 87 · see citing works
Higgs, T. C., & Carrano, C. J. (1997) · Inorganic Chemistry · doi:10.1021/ic9610703 · Cited by 85 · see citing works
Alonso‐Moreno, C., Garcés, A., Sánchez‐Barba, L. F., Fajardo, M., Fernández‐Baeza, J., Otero, A., Lara‐Sánchez, A., Antiñolo, A., Broomfield, L. M., López-Solera, I., et al. (2008) · Organometallics · doi:10.1021/om701187s · Cited by 78 · see citing works
Gorczynski, J. L., Chen, J., & Fraser, C. L. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0530927 · Cited by 76 · see citing works
Papish, E. T., Taylor, M. T., Jernigan, F. E., Rodig, M. J., Shawhan, R. R., Yap, G. P. A., & Jove, F. A. (2006) · Inorganic Chemistry · doi:10.1021/ic051579a · Cited by 75 · see citing works
Synthesis and structural studies of iron(II) and iron(III) sulfonates
Haynes, J. S., Sams, J. R., & Thompson, R. C. (1981) · Canadian Journal of Chemistry · doi:10.1139/v81-098 · Cited by 69 · see citing works
Byers, P. K., Canty, A. J., & Honeyman, R. T. (1990) · Journal of Organometallic Chemistry · doi:10.1016/0022-328x(90)85013-o · Cited by 67 · see citing works
Alkylzinc Complexes with Achiral and Chiral Monoanionic N , N , O Heteroscorpionate Ligands
Hegelmann, I., Beck, A. K., Eichhorn, C., Weibert, B., & Burzlaff, N. I. (2003) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.200390046 · Cited by 65 · see citing works
Atkinson, R. C., Gerry, K., Gibson, V. C., Long, N. J., Marshall, E. L., & West, L. J. (2006) · Organometallics · doi:10.1021/om0607144 · Cited by 60 · see citing works
Polylactones, 38. Polymerization of L ‐lactide with Fe(II) lactate and other resorbable Fe(II) salts
Kricheldorf, H. R., & Damrau, D. (1997) · Macromolecular Chemistry and Physics · doi:10.1002/macp.1997.021980606 · Cited by 59 · see citing works
Reger, D. L., Watson, R. P., Smith, M. D., & Pellechia, P. J. (2005) · Organometallics · doi:10.1021/om049112f · Cited by 58 · see citing works
Kopf, H., Holzberger, B., Pietraszuk, C., Hübner, E. G., & Burzlaff, N. I. (2008) · Organometallics · doi:10.1021/om8006129 · Cited by 56 · see citing works
Kopf, H., Pietraszuk, C., Hübner, E. G., & Burzlaff, N. I. (2006) · Organometallics · doi:10.1021/om060050y · Cited by 55 · see citing works
Kricheldorf, H. R., & Boettcher, C. (1993) · Die Makromolekulare Chemie · doi:10.1002/macp.1993.021940209 · Cited by 54 · see citing works
Iron Tris(dibenzoylmethane−polylactide)
Chen, J., Gorczynski, J. L., Zhang, G., & Fraser, C. L. (2010) · Macromolecules · doi:10.1021/ma100333e · Cited by 53 · see citing works
Tuning the Coordination Geometry of Silver in Bis(pyrazolyl)alkane Complexes
Reger, D. L., Gardinier, J. R., & Smith, M. D. (2004) · Inorganic Chemistry · doi:10.1021/ic0497174 · Cited by 52 · see citing works
Copolymerization of Cyclic Esters Controlled by Chiral NNO-Scorpionate Zinc Initiators
Honrado, M., Otero, A., Fernández‐Baeza, J., Sánchez‐Barba, L. F., Garcés, A., Lara‐Sánchez, A., & Rodrı́guez, A. M. (2016) · Organometallics · doi:10.1021/acs.organomet.5b00919 · Cited by 51 · see citing works
Wilfer, C., Liebhäuser, P., Hoffmann, A., Erdmann, H., Grossmann, O., Runtsch, L. S., Paffenholz, E., Schepper, R., Dick, R., Bauer, M., et al. (2015) · Chemistry - A European Journal · doi:10.1002/chem.201501685 · Cited by 46 · see citing works
Self-citationSchwenzer, B., Schleu, J., Burzlaff, N. I., Karl, C. C., & Fischer, H. (2002) · Journal of Organometallic Chemistry · doi:10.1016/s0022-328x(01)01310-9 · Cited by 46 · see citing works
Manna, C. M., Kaur, A., Yablon, L. M., Hæffner, F., Li, B., & Byers, J. A. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b09966 · Cited by 45 · see citing works
Redox-triggered crosslinking of a degradable polymer
Chiaie, K. R. D., Yablon, L. M., Biernesser, A. B., Michalowski, G. R., Sudyn, A. W., & Byers, J. A. (2016) · Polymer Chemistry · doi:10.1039/c6py00975a · Cited by 45 · see citing works
Hoffmann, A., Citek, C., Binder, S., Goos, A., Rübhausen, M., Troeppner, O., Ivanović‐Burmazović, I., Wasinger, E. C., Stack, T. D. P., & Herres‐Pawlis, S. (2013) · Angewandte Chemie · doi:10.1002/ange.201301249 · Cited by 42 · see citing works
Self-citationStrianese, M., Milione, S., Bertolasi, V., Pellecchia, C., & Grassi, A. (2011) · Inorganic Chemistry · doi:10.1021/ic101467s · Cited by 41 · see citing works
Zinc Complexes with Guanidine–Pyridine Hybrid Ligands – Guanidine Effect and Catalytic Activity
Börner, J., Vieira, I. D. S., Jones, M. D., Döring, A., Kuckling, D., Flörke, Ü., & Herres‐Pawlis, S. (2011) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201100540 · Cited by 40 · see citing works
Self-citationReger, D. L., Watson, R. P., Smith, M. D., & Pellechia, P. J. (2005) · Organometallics · doi:10.1021/om0508684 · Cited by 39 · see citing works
Biernesser, A. B., Chiaie, K. R. D., Curley, J. B., & Byers, J. A. (2016) · Angewandte Chemie · doi:10.1002/ange.201511793 · Cited by 39 · see citing works
Hübner, E. G., Haas, T., & Burzlaff, N. I. (2006) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.200600835 · Cited by 38 · see citing works
Ring‐opening polymerization of L‐lactide by means of different iron compounds
Södergård, A., & Stolt, M. (1998) · Macromolecular Symposia · doi:10.1002/masy.19981300133 · Cited by 35 · see citing works
Scheiper, C., Dittrich, D., Wölper, C., Bläser, D., Roll, J., & Schulz, S. (2014) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201301462 · Cited by 35 · see citing works
Metz, A., Plothe, R., Glowacki, B., Koszalkowski, A., Scheckenbach, M., Beringer, A., Rösener, T., Vasconcellos, J. M. D., Haase, R., Flörke, Ü., et al. (2016) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201600870 · Cited by 35 · see citing works
Self-citationJones, M. W., Baldwin, J. E., Cowley, A. R., Dilworth, J. R., Karpov, A., Smiljanic, N., Thompson, A. L., & Adlington, R. M. (2012) · Dalton Transactions · doi:10.1039/c2dt31859h · Cited by 33 · see citing works
Adhikari, D., Zhao, G., Basuli, F., Tomaszewski, J. W., Huffman, J. C., & Mindiola, D. J. (2006) · Inorganic Chemistry · doi:10.1021/ic051704i · Cited by 32 · see citing works
Reger, D. L., Gardinier, J. R., & Smith, M. D. (2004) · Polyhedron · doi:10.1016/j.poly.2003.11.018 · Cited by 32 · see citing works
Tris(pyrazolyl)methansulfonate: eine neue Klasse wasserlöslicher Liganden
Kläui, W., Berghahn, M., Rheinwald, G., & Lang, H. (2000) · Angewandte Chemie · doi:10.1002/1521-3757(20000717)112:14 · Cited by 32 · see citing works
Wilfer, C., Liebhäuser, P., Erdmann, H., Hoffmann, A., & Herres‐Pawlis, S. (2014) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201402957 · Cited by 30 · see citing works
Self-citationKwon, K. S., Nayab, S., & Jeong, J. H. (2014) · Polyhedron · doi:10.1016/j.poly.2014.09.032 · Cited by 30 · see citing works
An enantiopure N,N,S scorpionate ligand derived from (+)-camphor
Godau, T., Platzmann, F., Heinemann, F. W., & Burzlaff, N. I. (2008) · Dalton Transactions · doi:10.1039/b819596j · Cited by 29 · see citing works
Hoffmann, A., Flörke, Ü., Schürmann, M., & Herres‐Pawlis, S. (2010) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201000198 · Cited by 29 · see citing works
Self-citationOne‐Pot Synthesis of an Enantiopure N,N,O Scorpionate Ligand Derived from (+)‐Camphor
Elflein, J., Platzmann, F., & Burzlaff, N. I. (2007) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.200700827 · Cited by 27 · see citing works
Metal Chelates Based on Isoxazoline[60]fullerenes
Ramírez-Monroy, A., & Swager, T. M. (2011) · Organometallics · doi:10.1021/om200238a · Cited by 21 · see citing works
Bis(pyrazolyl)methane Copper Complexes as Robust and Efficient Catalysts for Sonogashira Couplings
Moegling, J., Benischke, A. D., Hammann, J. M., Vepřek, N. A., Zoller, F., Rendenbach, B., Hoffmann, A., Sievers, H., Schuster, M., Knochel, P., et al. (2015) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201501117 · Cited by 20 · see citing works
Self-citationStrinitz, F., Trautner, P., Pfeiffer, H., Schatzschneider, U., & Burzlaff, N. I. (2015) · Tetrahedron · doi:10.1016/j.tet.2015.03.002 · Cited by 20 · see citing works
Paul, T., Rodehutskors, P., Schmidt, J., & Burzlaff, N. I. (2016) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201600026 · Cited by 17 · see citing works
Insights into Different Donor Abilities in Bis(pyrazolyl)pyridinylmethane Transition Metal Complexes
Hoffmann, A., Flörke, Ü., & Herres‐Pawlis, S. (2014) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201400056 · Cited by 16 · see citing works
Self-citationHonrado, M., Otero, A., Fernández‐Baeza, J., Sánchez‐Barba, L. F., Garcés, A., Lara‐Sánchez, A., & Rodríguez, A. M. (2016) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201501347 · Cited by 16 · see citing works
Börner, J., Flörke, Ü., Döring, A., Kuckling, D., & Herres‐Pawlis, S. (2010) · Macromolecular Symposia · doi:10.1002/masy.201051049 · Cited by 14 · see citing works
Self-citationHoffmann, A., & Herres‐Pawlis, S. (2013) · Zeitschrift für anorganische und allgemeine Chemie · doi:10.1002/zaac.201300103 · Cited by 11 · see citing works
Self-citationBis(pyrazol-1-yl)acetic Acid Bearing Ferrocenyl Substituents
Tampier, S., Bleifuss, S. M., Abd‐Elzaher, M. M., Sutter, J., Heinemann, F. W., & Burzlaff, N. I. (2013) · Organometallics · doi:10.1021/om400495f · Cited by 11 · see citing works
Vieira, I. D. S., & Herres‐Pawlis, S. (2012) · Zeitschrift für Naturforschung B · doi:10.5560/znb.2012.67b0320 · Cited by 11 · see citing works
Self-citationN-Donor Competition in Iron Bis(chelate) Bis(pyrazolyl)pyridinylmethane Complexes
Herber, U., Hoffmann, A., Lochenie, C., Weber, B., & Herres‐Pawlis, S. (2014) · Zeitschrift für Naturforschung B · doi:10.5560/znb.2014-4176 · Cited by 7 · see citing works
Self-citationAn Enantiopure N,N,O Heteroscorpionate Ligand Derived from (–)‐Menthone
Bleifuss, S. M., Hofmann, F., & Burzlaff, N. I. (2013) · Zeitschrift für anorganische und allgemeine Chemie · doi:10.1002/zaac.201300085 · Cited by 5 · see citing works
Drumright, R. E., Gruber, P. R., & Henton, D. E. (2000) · Advanced Materials · doi:10.1002/1521-4095(200012)12:23
Flagged first, then by citations
Cited by
Sorted by citations
Hermann, A., Hill, S., Metz, A., Heck, J., Hoffmann, A., Hartmann, L., & Herres‐Pawlis, S. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202008473 · Cited by 109 · see citing works
Self-citationRittinghaus, R. D., Schäfer, P. M., Albrecht, P., Conrads, C., Hoffmann, A., Ksiazkiewicz, A. N., Bienemann, O., Pich, A., & Herres‐Pawlis, S. (2019) · ChemSusChem · doi:10.1002/cssc.201900481 · Cited by 82 · see citing works
Self-citationChampouret, Y., Hashmi, O. H., & Visseaux, M. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.03.015 · Cited by 80 · see citing works
Schäfer, P. M., & Herres‐Pawlis, S. (2020) · ChemPlusChem · doi:10.1002/cplu.202000252 · Cited by 64 · see citing works
Self-citationProgress of Ring-Opening Polymerization of Cyclic Esters Catalyzed by Iron Compounds
Wang, Y., Wang, X., Zhang, W., & Sun, W. (2023) · Organometallics · doi:10.1021/acs.organomet.3c00028 · Cited by 46 · see citing works
Fako, E., Łodziana, Z., & López, N. (2017) · Catalysis Science & Technology · doi:10.1039/c7cy01136a · Cited by 43 · see citing works
Undiscovered Potential: Ge Catalysts for Lactide Polymerization
Rittinghaus, R. D., Tremmel, J., Růžička, A., Conrads, C., Albrecht, P., Hoffmann, A., Ksiazkiewicz, A. N., Pich, A., Jambor, R., & Herres‐Pawlis, S. (2019) · Chemistry - A European Journal · doi:10.1002/chem.201903949 · Cited by 43 · see citing works
Self-citationDriscoll, O. J., Hafford-Tear, C. H., McKeown, P., Stewart, J. A., Kociok-Köhn, G., Mahon, M. F., & Jones, M. D. (2019) · Dalton Transactions · doi:10.1039/c9dt03327k · Cited by 39 · see citing works
N-Heterocyclic carbene iron complexes catalyze the ring-opening polymerization of lactide
Nylund, P. V. S., Monney, B., Weder, C., & Albrecht, M. (2022) · Catalysis Science & Technology · doi:10.1039/d1cy02143e · Cited by 34 · see citing works
Cyclic Polyester Formation with an [OSSO]‐Type Iron(III) Catalyst
Impemba, S., Della Monica, F., Grassi, A., Capacchione, C., & Milione, S. (2020) · ChemSusChem · doi:10.1002/cssc.201902163 · Cited by 32 · see citing works
Beament, J., Mahon, M. F., Buchard, A., & Jones, M. D. (2018) · Organometallics · doi:10.1021/acs.organomet.8b00161 · Cited by 32 · see citing works
Guanidine Carboxy Zinc Complexes for the Chemical Recycling of Renewable Polyesters
Fuchs, M., Walbeck, M., Jagla, E., Hoffmann, A., & Herres‐Pawlis, S. (2022) · ChemPlusChem · doi:10.1002/cplu.202200029 · Cited by 24 · see citing works
Self-citationSteiniger, P., Schäfer, P. M., Wölper, C., Henkel, J., Ksiazkiewicz, A. N., Pich, A., Herres‐Pawlis, S., & Schulz, S. (2018) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201800504 · Cited by 24 · see citing works
Self-citationActive in Sleep: Iron Guanidine Catalyst Performs ROP on Dormant Side of ATRP
Rittinghaus, R. D., Karabulut, A., Hoffmann, A., & Herres‐Pawlis, S. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202109053 · Cited by 23 · see citing works
Self-citationDaneshmand, P., Jiménez-Santiago, J. L., Aragon--Alberti, M., & Schaper, F. (2018) · Organometallics · doi:10.1021/acs.organomet.8b00196 · Cited by 21 · see citing works
Hermann, A., Hill, S., Metz, A., Heck, J., Hoffmann, A., Hartmann, L., & Herres‐Pawlis, S. (2020) · Angewandte Chemie · doi:10.1002/ange.202008473 · Cited by 20 · see citing works
Self-citationRecent Advances in RO(CO)P of Bio-Based Monomers
Santoro, O., Izzo, L., & Monica, F. D. (2022) · Sustainable Chemistry · doi:10.3390/suschem3020017 · Cited by 20 · see citing works
Quilter, H. C., Drewitt, R. H., Mahon, M. F., Kociok-Köhn, G. I., & Jones, M. D. (2017) · Journal of Organometallic Chemistry · doi:10.1016/j.jorganchem.2017.08.014 · Cited by 18 · see citing works
Chen, Y., Zhang, J., Xiao, W., Chen, A., Dong, Z., Xu, J., Xu, W., & Lei, C. (2021) · European Polymer Journal · doi:10.1016/j.eurpolymj.2021.110861 · Cited by 17 · see citing works
Diiminopyrrolide Copper Complexes: Synthesis, Structures, and rac -Lactide Polymerization Activity
Daneshmand, P., Fortun, S., & Schaper, F. (2017) · Organometallics · doi:10.1021/acs.organomet.7b00609 · Cited by 16 · see citing works
Keisers, K., Hüppe, H. M., Iffland‐Mühlhaus, L., Hoffmann, A., Göbel, C., Apfel, U., Weber, B., & Herres‐Pawlis, S. (2020) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.0c02306 · Cited by 16 · see citing works
Self-citationSánchez‐Barba, L. F., Garcés, A., Lara‐Sánchez, A., Navarro, M., & González-Lizana, D. (2024) · Chemical Communications · doi:10.1039/d4cc05014b · Cited by 15 · see citing works
Zubkevich, S. V., Тuskaev, V. А., Gagieva, S., Kayda, A. S., Khrustalev, V. N., Pavlov, A. A., Zarubin, D. N., & Bulychev, B. M. (2020) · Applied Organometallic Chemistry · doi:10.1002/aoc.5873 · Cited by 14 · see citing works
Choe, S., Lee, H., & Nayab, S. (2021) · Applied Organometallic Chemistry · doi:10.1002/aoc.6204 · Cited by 14 · see citing works
Yadav, N., & Chundawat, T. S. (2024) · ChemistrySelect · doi:10.1002/slct.202401619 · Cited by 12 · see citing works
Jayakumar, S., Dharmasivam, M., Selvan, D. A., & Rahiman, A. K. (2019) · Journal of Molecular Structure · doi:10.1016/j.molstruc.2019.06.088 · Cited by 9 · see citing works
Choe, S., Lee, H., & Nayab, S. (2021) · RSC Advances · doi:10.1039/d1ra02365a · Cited by 9 · see citing works
Hashmi, O. H., Capet, F., Visseaux, M., & Champouret, Y. (2022) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.202200073 · Cited by 9 · see citing works
Akintayo, D. C., Munzeiwa, W. A., Jonnalagadda, S. B., & Omondi, B. O. (2021) · Polyhedron · doi:10.1016/j.poly.2021.115589 · Cited by 8 · see citing works
A biodegradable suction patch for sustainable transbuccal peptide delivery
Krupke, H., Zoratto, N., Rabut, L., Gao, D., Paunović, N., Cerrejon, D. K., Dehapiot, B., & Leroux, J. (2025) · Journal of Controlled Release · doi:10.1016/j.jconrel.2025.113947 · Cited by 7 · see citing works
Tiwari, O. S., Rawat, V., Zhang, H., Chibh, S., Rencus‐Lazar, S., Diesendruck, C. E., & Gazit, E. (2024) · Journal of Peptide Science · doi:10.1002/psc.3626 · Cited by 7 · see citing works
Wang, Y., Zhang, W., Wang, X., Zuo, W., Xue, X., Ma, Y., & Sun, W. (2023) · RSC Advances · doi:10.1039/d3ra05867k · Cited by 7 · see citing works
Kirchhecker, S., Nguyen, N., Reichert, S., Lützow, K., Eselem Bungu, P. S., Jacobi von Wangelin, A., Sandl, S., & Neffe, A. T. (2023) · RSC Advances · doi:10.1039/d3ra03112h · Cited by 6 · see citing works
Nachtaktiv: Eisen‐Guanidin‐Komplex katalysiert ROP auf der schlafenden Seite der ATRP
Rittinghaus, R. D., Karabulut, A., Hoffmann, A., & Herres‐Pawlis, S. (2021) · Angewandte Chemie · doi:10.1002/ange.202109053 · Cited by 6 · see citing works
Self-citationSynthesis of Bis(benzotriazol-1-yl)methane Derivatives by Cobalt-Catalyzed Formation of C-C Bonds
Ferraro, V., Bortoluzzi, M., & Castro, J. (2019) · International Electronic Conference on Synthetic Organic Chemistry (ECSOC) · doi:10.3390/ecsoc-23-06469 · Cited by 4 · see citing works
Hao, H., Chen, D.-F., Zhang, W., Li, X., Wang, K.-F., Lei, J., & Tang, L. (2024) · Journal of Coordination Chemistry · doi:10.1080/00958972.2024.2323560 · Cited by 2 · see citing works
Zikode, M., Ngwenya, A., Becker, T., Herres‐Pawlis, S., & Ojwach, S. O. (2025) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.202500126 · Cited by 1 · see citing works
Self-citationSynthesis and crystal structure of [Zn6Br4(C9H18NO)4(OH)4]·2C3H6O2
Scheel, R., Brieger, L., Louven, K., & Carsten Strohmann, B. (2020) · Acta Crystallographica Section E Crystallographic Communications · doi:10.1107/s2056989020007100 · Cited by 1 · see citing works
Bulky Hybrid C‐Scorpionate/Amidinate Complexes of Lithium and Zinc
Mandel, M. J., Krieck, S., Görls, H., & Westerhausen, M. (2022) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.202200249
Meng, Y., Liu, N., Hao, M., Du, P., Song, X., Li, X., Zhang, K., Zhang, G., & Pan, Y. (2026) · Inorganics · doi:10.3390/inorganics14030081
Caballero, M. P., Navarro, M., Buchaca, M. M. D. S., Naranjo, J., Moreno-Fernández, A., Rodríguez‐Diéguez, A., Salcedo‐Abraira, P., Castro‐Osma, J. A., Tejeda, J., de la Cruz‐Martínez, F., et al. (2026) · ChemSusChem · doi:10.1002/cssc.70974
- Authors
- Herber, U., Hegner, K., Wolters, D., Siris, R., Wrobel, K., Hoffmann, A., Lochenie, C., Weber, B., Kuckling, D., & Herres‐Pawlis, S.
- Affiliations
- RWTH Aachen University (DE)
- Ludwig-Maximilians-Universität München (DE)
- University of Bayreuth (DE)
- Paderborn University (DE)
- Corresponding author
- Herres‐Pawlis, Sonja
- Venue
- European Journal of Inorganic Chemistry
- Publisher
- Wiley
- Published
- 2017-03-10
- Volume
- 2017
- Issue
- 10
- Pages
- 1341-1354
- ISSN
- 1099-0682 (ISSN-L)
- 1434-1948
- OpenAlex
- W2565129593
- Cited by
- 41
- References
- 81
- Citations by year
- 2026: 2 · 2025: 2 · 2024: 4 · 2023: 3 · 2022: 5 · 2021: 6 · 2020: 6 · 2019: 7 · 2018: 3 · 2017: 3
- FWCI
- 1.77
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- European Journal of Inorganic Chemistry (publishedVersion)
- RWTH Publications (RWTH Aachen) (submittedVersion)
- Funders
- Deutsche Forschungsgemeinschaft (SeleCa)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Keywords
- iron(II) complexes, zinc(II) complexes, bis(pyrazolyl)methane ligands, tetradentate ligands, ring-opening polymerization, rac-lactide, polylactic acid, triflate counterion
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review