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Silver‐Catalyzed Incorporation of Carbon Dioxide into Propargylic Alcohols
Abstract
The combined use of a catalytic amount of silver acetate and a stoichiometric amount of DBU efficiently catalyzed the incorporation of CO 2 under mild reaction conditions into a wide range of propargylic alcohols bearing a terminal or an internal triple bond to afford the corresponding cyclic carbonates in high‐to‐excellent yields. All the cyclic carbonates obtained from the reaction were found to be single isomers. The geometries were determined to be (Z) by X‐ray crystal structure analysis and NOE experiments.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
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Citations
Cited by
The synthesis of organic carbonates from carbon dioxide
Sakakura, T., & Kohno, K. (2009) · Chemical Communications · doi:10.1039/b819997c · Cited by 1,067
Recent Advances in the Catalytic Preparation of Cyclic Organic Carbonates
Martín, C., Fiorani, G., & Kleij, A. W. (2015) · ACS Catalysis · doi:10.1021/cs5018997 · Cited by 1,037
Wu, Y., Zhao, Y., Li, R., Yu, B., Chen, Y., Liu, X., Wu, C., Luo, X., & Liu, Z. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01422 · Cited by 126
Green catalytic process for cyclic carbonate synthesis from carbon dioxide under mild conditions
Lang, X.-D., & He, L.-N. (2016) · The Chemical Record · doi:10.1002/tcr.201500293 · Cited by 122
Synthesis of cyclic carbonates with carbon dioxide and cesium carbonate
Reithofer, M. R., Sum, Y. N., & Zhang, Y. (2013) · Green Chemistry · doi:10.1039/c3gc40790j · Cited by 95
Metadata
- Authors
- Yamada, W., Sugawara, Y., Cheng, H. M., Ikeno, T., & Yamada, T.
- Venue
- European Journal of Organic Chemistry
- Publisher
- Wiley
- Published
- 2007-05-10
- Volume
- 2007
- Issue
- 16
- Pages
- 2604-2607
- ISSN
- 1099-0690 (ISSN-L)
- 1434-193X
- OpenAlex
- W2016184770
- Cited by
- 199
- References
- 0
- FWCI
- 9.80
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yamada, W., Sugawara, Y., Cheng, H. M., Ikeno, T., & Yamada, T. (2007). Silver‐Catalyzed Incorporation of Carbon Dioxide into Propargylic Alcohols. European Journal of Organic Chemistry. https://doi.org/10.1002/ejoc.200700169
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