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Accessing the Synthetic Chemistry of Radical Ions
Abstract
Organic reactions involving radical cation and radical anion intermediates are synthetically powerful umpolung processes that enable electronically mismatched couplings between pairs of electron‐rich or pairs of electron‐poor organic fragments. Nevertheless, the adoption of these reactions as synthetic methods has been relatively slow in comparison with that of reactions involving more conventional reactive intermediates such as carbanions, carbocations, and neutral radicals. This Microreview provides a brief survey of radical ion chemistry and highlights the use of transition metal photocatalysis as a convenient means to investigate radical‐ion‐mediated transformations.
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Citations
Cited by
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Dual Catalysis Strategies in Photochemical Synthesis
Skubi, K. L., Blum, T. R., & Yoon, T. P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00018 · Cited by 2,686
Self-citationSynthetic applications of photoredox catalysis with visible light
Xi, Y., Yi, H., & Lei, A. (2013) · Organic & Biomolecular Chemistry · doi:10.1039/c3ob40137e · Cited by 658
Liu, J., Liu, Q., Yi, H., Qin, C., Bai, R., Qi, X., Lan, Y., & Lei, A. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201308614 · Cited by 451
Asymmetric catalysis activated by visible light
Meggers, E. (2015) · Chemical Communications · doi:10.1039/c4cc09268f · Cited by 373
Metadata
- Authors
- Ischay, M. A., & Yoon, T. P.
- Venue
- European Journal of Organic Chemistry
- Publisher
- Wiley
- Published
- 2012-05-04
- Volume
- 2012
- Issue
- 18
- Pages
- 3359-3372
- ISSN
- 1099-0690 (ISSN-L)
- 1434-193X
- OpenAlex
- W2027436647
- Cited by
- 212
- References
- 0
- FWCI
- 13.41
- Type
- journal article
- Language
- en
- Open access
- closed
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