The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.
PBI‐Based Polymer Membranes for High Temperature Fuel Cells – Preparation, Characterization and Fuel Cell Demonstration
Abstract
Proton exchange membrane fuel cell (PEMFC) technology based on perfluorosulfonic acid (PFSA) polymer membranes is briefly reviewed. The newest development in alternative polymer electrolytes for operation above 100 °C is summarized and discussed. As one of the successful approaches to high operational temperatures, the development and evaluation of acid doped polybenzimidazole (PBI) membranes are reviewed, covering polymer synthesis, membrane casting, acid doping, physicochemical characterization and fuel cell testing. A high temperature PEMFC system, operational at up to 200 °C based on phosphoric acid‐doped PBI membranes, is demonstrated. It requires little or no gas humidification and has a CO tolerance of up to several percent. The direct use of reformed hydrogen from a simple methanol reformer, without the need for any further CO removal, has been demonstrated. A lifetime of continuous operation, for over 5000 h at 150 °C, and shutdown‐restart thermal cycle testing for 47 cycles has been achieved. Other issues such as cooling, heat recovery, possible integration with fuel processing units, associated problems and further development are discussed.
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Cites
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Cited by
Scientific Aspects of Polymer Electrolyte Fuel Cell Durability and Degradation
Borup, R., Meyers, J., Pivovar, B., Kim, Y. S., Mukundan, R., Garland, N., Myers, D., Wilson, M., Garzon, F., Wood, D., et al. (2007) · Chemical Reviews · doi:10.1021/cr050182l · Cited by 3,402
Water transport in polymer electrolyte membrane fuel cells
Jiao, K., & Li, X. (2011) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2010.06.002 · Cited by 1,086
Haider, R., Wen, Y., Ma, Z.-F., Wilkinson, D. P., Zhang, L., Yuan, X., Song, S., & Zhang, J. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00296h · Cited by 785
Asensio, J. A., Sánchez, E. M., & Gómez-Romero, P. (2010) · Chemical Society Reviews · doi:10.1039/b922650h · Cited by 746
Aliphatic/Aromatic Polyimide Ionomers as a Proton Conductive Membrane for Fuel Cell Applications
Asano, N., Aoki, M., Suzuki, S., Miyatake, K., Uchida, H., & Watanabe, M. (2006) · Journal of the American Chemical Society · doi:10.1021/ja0571491 · Cited by 657
Metadata
- Authors
- Li, Q., He, R., Jensen, J. O., & Bjerrum, N. J.
- Venue
- Fuel Cells
- Publisher
- Wiley
- Published
- 2004-07-29
- Volume
- 4
- Issue
- 3
- Pages
- 147-159
- ISSN
- 1615-6846 (ISSN-L)
- 1615-6854
- OpenAlex
- W1982511023
- Cited by
- 637
- References
- 13
- FWCI
- 18.31
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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