The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
The Chemical and Structural Nature of Proton Exchange Membrane Fuel Cell Properties
Abstract
The chemical and structural (morphological) features of proton exchange membranes are directly tied to their fuel cell relevant transport properties. A large body of research has focused on characterizing the structure or investigating the properties of Nafion® and other proton exchange membranes, but few studies have linked chemical composition to membrane morphology, and resulting transport properties. This paper systematically discusses the key chemical and structural features of proton exchange membranes that impact properties critical for fuel cell applications. We focus our discussion on the fuel cell relevant transport properties of proton conductivity, methanol permeability, water diffusion coefficient, and electro‐osmotic drag coefficient, using evidence from our work and from the literature to illustrate the connection between structure and properties in these materials. It is hoped that this document will serve as a guide to the rational, systematic design of new proton exchange membrane materials with improved properties.
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Cites
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Development of ionomer membranes for fuel cells
Kerres, J. A. (2001) · Journal of Membrane Science · doi:10.1016/s0376-7388(00)00631-1 · Cited by 1,022
Determination of water diffusion coefficients in perfluorosulfonate ionomeric membranes
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New membranes for direct methanol fuel cells
Jörissen, L., Gogel, V., Kerres, J., & Garche, J. (2002) · Journal of Power Sources · doi:10.1016/s0378-7753(01)00952-1 · Cited by 279
Cited by
New Insights into Perfluorinated Sulfonic-Acid Ionomers
Kusoglu, A., & Weber, A. Z. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00159 · Cited by 2,432
Anion-exchange membranes in electrochemical energy systems
Varcoe, J. R., Atanassov, P., Dekel, D. R., Herring, A. M., Hickner, M. A., Kohl, P. A., Kucernak, A. R., Mustain, W. E., Nijmeijer, K., Scott, K., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01303d · Cited by 2,051
Self-citationDirect methanol fuel cell membranes from Nafion-polybenzimidazole blends
Wycisk, R., Chisholm, J., Lee, J., Lin, J., & Pintauro, P. N. (2006) · Journal of Power Sources · doi:10.1016/j.jpowsour.2005.11.056 · Cited by 136
An overview of electro-osmosis in fuel cell polymer electrolytes
Pivovar, B. S. (2006) · Polymer · doi:10.1016/j.polymer.2006.02.071 · Cited by 126
Self-citationWater Uptake of Fuel-Cell Catalyst Layers
Kusoglu, A., Kwong, A., Clark, K. T., Gunterman, H. P., & Weber, A. Z. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.031209jes · Cited by 110
Dickinson, E. J. F., & Smith, G. (2020) · Membranes · doi:10.3390/membranes10110310 · Cited by 109
The Membrane–Electrode Interface in PEFCs
Kim, Y. S., & Pivovar, B. S. (2010) · Journal of The Electrochemical Society · doi:10.1149/1.3481580 · Cited by 22
Self-citation
Metadata
- Authors
- Hickner, M. A., & Pivovar, B. S.
- Venue
- Fuel Cells
- Publisher
- Wiley
- Published
- 2005-04
- Volume
- 5
- Issue
- 2
- Pages
- 213-229
- ISSN
- 1615-6846 (ISSN-L)
- 1615-6854
- OpenAlex
- W2153511419
- Cited by
- 376
- References
- 6
- FWCI
- 17.48
- Type
- journal article
- Language
- en
- Open access
- closed
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