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Der Chelateffekt
Abstract
The chelate effect has been defined as the stability difference between a chelate complex and the corresponding complex with simple ligands. Starting from a simple picture, comprising the chelate effect as a gain in „translational entropy”︁, equations have been derived allowing to predict its magnitude. Most important are the size of the chelate ring and its strain. Complexes with tridentate, quadridentate‐ and hexadentate agents are also discussed.
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Cited by
Anderson, N. C., Hendricks, M. P., Choi, J. J., & Owen, J. S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4086758 · Cited by 874
The biological inorganic chemistry of zinc ions
Krężel, A., & Maret, W. (2016) · Archives of Biochemistry and Biophysics · doi:10.1016/j.abb.2016.04.010 · Cited by 768
Glycomimetics versus Multivalent Glycoconjugates for the Design of High Affinity Lectin Ligands
Cecioni, S., Imberty, A., & Vidal, S. (2015) · Chemical Reviews · doi:10.1021/cr500303t · Cited by 544
Holographic Sensors: Three-Dimensional Analyte-Sensitive Nanostructures and Their Applications
Yetisen, A. K., Naydenova, I., da Cruz Vasconcellos, F., Blyth, J., & Lowe, C. R. (2014) · Chemical Reviews · doi:10.1021/cr500116a · Cited by 224
Ring Closure To Form Metal Chelates in 3D Fragment-Based de Novo Design
Foscato, M., Houghton, B. J., Occhipinti, G., Deeth, R. J., & Jensen, V. R. (2015) · Journal of Chemical Information and Modeling · doi:10.1021/acs.jcim.5b00424 · Cited by 21
Metadata
- Authors
- Schwarzenbach, G.
- Venue
- Helvetica Chimica Acta
- Publisher
- Wiley
- Published
- 1952-12
- Volume
- 35
- Issue
- 7
- Pages
- 2344-2359
- ISSN
- 0018-019X (ISSN-L)
- 1522-2675
- OpenAlex
- W4251755182
- Cited by
- 271
- References
- 0
- FWCI
- 4.32
- Type
- journal article
- Language
- en
- Open access
- closed
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- Schwarzenbach, G. (1952). Der Chelateffekt. Helvetica Chimica Acta. https://doi.org/10.1002/hlca.19520350721
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
