Cited by 84Free Radicals and AntioxidantsSurfactants and Colloidal SystemsElectron Spin Resonance Studies

The DOI matches its Crossref record; 47 of the 47 references it cites were found in a registry or an index.

Singlet Oxygen and Superoxide: Experimental Differentiation and Analysis

Open access

Abstract

Superoxide produced by either pulse radiolysis or from KO 2 undergoes no reaction with furfuryl alcohol competitive to the corresponding endo‐peroxide formation with singlet oxygen. Thus, furfuryl alcohol can be used as a specific chemical quencher of singlet oxygen. Superoxide can be quantitatively analyzed by its electron transfer reaction with 1, 4‐benzoquinone. The differentiation of the two activated species of oxygen has been realized in microemulsions. Singlet oxygen is known to penetrate the interfaces of surfactant aggregates and may be analyzed in the hydrophobic core by known methods. Charged surfaces on such aggregates, specially those formed by anionic surfactants, prevent the passage of superoxide and restrict its presence and the need for analysis to the bulk aqueous phase. Hydrated electrons may penetrate the interface depending on the dose per pulse applied. 2, 5‐Di (t‐butyl)‐1, 4‐benzoquinone has been taken as an acceptor for electron transfer reactions within the hydrophobic core.

Overview

Integrity signals

Registry

Crossref · 10.1002/hlca.19830660236

Cites

47 of 47 references verified0 citation errors · 0 not checkable

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Verification

Claims the paper makes

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Claims other papers make about this one

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  • Mechanism 3 shows the formation of O2•− from 1O2 using furfuryl alcohol, fullerenes or quinones as specific inhibitors of 1O2.

    “Mechanism 3 shows the formation of O2•− from 1O2 (1O2 is generated from O2 sensitisation by rose bengal) using furfuryl alcohol [42], fullerenes [43] or quinones [44] as specific inhibitors of 1O2, Figure 25.”

Citations

Cites

Flagged first, then by citations

Research works printed but not linked: 7

  1. Foote C. S., Tetrahedron Lett., 1968, 3267
  2. Foote C. S., Tetrahedron Lett., 1975, 1247
  3. Foote C. S., 1979, Singlet Oxygen, 139
  4. Graf G. A., 1980, Chimia, 34, 234
  5. Simić M., 1975, Fast Processes in Radiation Chemistry and Biology, 162
  6. Farrington J. A., J. Chem. Soc., Faraday I, 1978, 665
  7. Fargues R., 1979, Nouv. J. Chim., 3, 487

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Metadata

Authors
Maurette, M., Oliveros, E., Infelta, P. P., Ramsteiner, K., & Braun, A. M.
Affiliations
  • Université Toulouse III - Paul Sabatier (FR)
  • École Polytechnique Fédérale de Lausanne (CH)
Corresponding author
Braun, André M.
Venue
Helvetica Chimica Acta
Publisher
Wiley
Published
1983-03-16
Volume
66
Issue
2
Pages
722-733
ISSN
  • 0018-019X (ISSN-L)
  • 1522-2675
OpenAlex
W2081439747
Cited by
84
References
47
Citations by year
2026: 3 · 2025: 4 · 2024: 2 · 2023: 2 · 2022: 3 · 2021: 2 · 2020: 3 · 2019: 2 · 2018: 2 · 2017: 6 · 2016: 1 · 2015: 1 · 2014: 2 · 2013: 4 · 2012: 1
FWCI
5.74
Type
journal article
Language
en
Open access
Locations
  • Helvetica Chimica Acta (publishedVersion)
  • Infoscience (Ecole Polytechnique Fédérale de Lausanne) (submittedVersion)
  • Infoscience (Ecole Polytechnique Fédérale de Lausanne) (submittedVersion, cc-by-nc-nd)
Topics
  • Physical Sciences › Chemistry › Organic Chemistry › Free Radicals and Antioxidants
  • Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Surfactants and Colloidal Systems
  • Physical Sciences › Chemistry › Spectroscopy › Electron Spin Resonance Studies
Keywords
singlet oxygen, superoxide, furfuryl alcohol, singlet oxygen quenching, p-benzoquinone, electron transfer, microemulsions, surfactant aggregates, anionic surfactants, hydrated electrons, endoperoxide formation, pulse radiolysis, potassium superoxide

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