Nano‐structured gemini‐based supramolecular solvent for the microextraction of cyhalothrin and fenvalerate
Abstract
A novel supramolecular solvent‐based microextraction followed by high‐performance liquid chromatography with ultraviolet detection method has been developed for the extraction and determination of two pyrethroid analytes, cyhalothrin and fenvalerate, in water and soil samples. The liquid–liquid‐phase separation of surfactants has been used in analytical extraction. The surfactant‐rich phase is a nano‐structured liquid, recently named as a supramolecular solvent, generated from the amphiphiles. The alkyl carboxylic acid based supramolecular solvents were introduced before. Coacervates made up of gemini surfactant, consisting of two amphiphilic moieties, were first used as solvent. The effective parameters on extraction (i.e., type of organic solvent, the amount of surfactant and volume of tetrahydrofuran, sample solution pH, salt addition, ultrasonic and centrifugation time) were investigated and optimized. Under the optimum conditions, preconcentration factors of 110 and 145 were obtained for the analytes. The linearity was 0.5–200.0 μg/L with the correlation of determination of (R2) ≥ 0.9984. The limit of detection of the method was (S/N = 3) 0.2 μg/L, and precisions in the range of 6.3–10.3% (RSDs, n = 5) were obtained. This method has been successfully applied to analyze real samples, and good recoveries in the range of 101.2–108.8% were obtained.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
In 2016, Gemini surfactants were proposed as an alternative in SSME.
“In 2016, Gemini surfactants were proposed as an alternative in SSME [43].”
From Use of green alternative solvents in dispersive liquid‐liquid microextraction: A review (2022) · cites this paper as [43]
Cites
Gemini-surfactants: synthesis and properties
Menger, F. M., & Littau, C. A. (1991) · Journal of the American Chemical Society · doi:10.1021/ja00004a077 · Cited by 989 · see citing works
Gemini surfactants: a new class of self-assembling molecules
Menger, F. M., & Littau, C. A. (1993) · Journal of the American Chemical Society · doi:10.1021/ja00075a025 · Cited by 978 · see citing works
Zana, R. (2002) · Journal of Colloid and Interface Science · doi:10.1006/jcis.2001.8104 · Cited by 715 · see citing works
Carabias-Martı́nez, R., Rodrı́guez-Gonzalo, E., Moreno-Cordero, B., Pérez-Pavón, J. L., Garcı́a-Pinto, C., & Fernández Laespada, E. (2000) · Journal of Chromatography A · doi:10.1016/s0021-9673(00)00837-2 · Cited by 392 · see citing works
Supramolecular solvents in the extraction of organic compounds. A review
Ballesteros‐Gómez, A., Sicilia, M. D., & Rubio, S. (2010) · Analytica Chimica Acta · doi:10.1016/j.aca.2010.07.027 · Cited by 321 · see citing works
Rosen, M. J., & Tracy, D. J. (1998) · Journal of Surfactants and Detergents · doi:10.1007/s11743-998-0057-8 · Cited by 286 · see citing works
Ionic liquids in dispersive liquid-liquid microextraction
Trujillo-Rodríguez, M. J., Rocío-Bautista, P., Pino, V., & Afonso, A. M. (2013) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2013.06.008 · Cited by 276 · see citing works
Saleh, A., Yamini, Y., Faraji, M., Rezaee, M. B., & Ghambarian, M. (2009) · Journal of Chromatography A · doi:10.1016/j.chroma.2009.08.001 · Cited by 262 · see citing works
Self-citationAlkanediyl-α,ω-bis(dimethylalkylammonium bromide) Surfactants
Zana, R. (2002) · Journal of Colloid and Interface Science · doi:10.1006/jcis.2001.7921 · Cited by 197 · see citing works
Casero, I., Sicilia, D., Rubio, S., & Pérez-Bendito, D. (1999) · Analytical Chemistry · doi:10.1021/ac990106g · Cited by 196 · see citing works
Moradi, M., Yamini, Y., Esrafili, A., & Seidi, S. (2010) · Talanta · doi:10.1016/j.talanta.2010.08.002 · Cited by 178 · see citing works
Self-citationTani, H., Kamidate, T., & Watanabe, H. (1997) · Journal of Chromatography A · doi:10.1016/s0021-9673(97)00345-2 · Cited by 176 · see citing works
Ballesteros‐Gómez, A., & Rubio, S. (2011) · Analytical Chemistry · doi:10.1021/ac2026207 · Cited by 160 · see citing works
Ruiz, F.-J., Rubio, S., & Pérez‐Bendito, D. (2007) · Analytical Chemistry · doi:10.1021/ac0708644 · Cited by 150 · see citing works
Ruiz, F.-J., Rubio, S., & Pérez‐Bendito, D. (2006) · Analytical Chemistry · doi:10.1021/ac060427+ · Cited by 118 · see citing works
Yan, H., Liu, B., Du, J., Yang, G., & Row, K. H. (2010) · Journal of Chromatography A · doi:10.1016/j.chroma.2010.06.008 · Cited by 91 · see citing works
Farajzadeh, M. A., Khoshmaram, L., & Nabil, A. A. A. (2014) · Journal of Food Composition and Analysis · doi:10.1016/j.jfca.2014.03.004 · Cited by 90 · see citing works
Bakshi, M. S., & Singh, K. (2005) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2005.01.099 · Cited by 86 · see citing works
Zhang, Y., Zhang, X., & Jiao, B. (2014) · Food Chemistry · doi:10.1016/j.foodchem.2014.03.028 · Cited by 76 · see citing works
Deme, P., Azmeera, T., Devi, B. L. A. P., Jonnalagadda, P. R., Prasad, R. B. N., & Sarathi, U. V. R. V. (2013) · Food Chemistry · doi:10.1016/j.foodchem.2013.07.044 · Cited by 74 · see citing works
Yılmaz, E., & Soylak, M. (2014) · Talanta · doi:10.1016/j.talanta.2014.03.053 · Cited by 70 · see citing works
Rezaei, F., Yamini, Y., Moradi, M., & Ebrahimpour, B. (2012) · Talanta · doi:10.1016/j.talanta.2012.11.035 · Cited by 68 · see citing works
Self-citationAydin, F. A., Yılmaz, E., & Soylak, M. (2015) · RSC Advances · doi:10.1039/c4ra17116k · Cited by 63 · see citing works
Huang, X., Han, Y., Wang, Y., et al. (2008) · Colloids and Surfaces A Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2008.04.028 · Cited by 62 · see citing works
Zeng, J., Chen, J., Lin, Z., et al. (2008) · Analytica Chimica Acta · doi:10.1016/j.aca.2008.02.013 · Cited by 56 · see citing works
Ruiz‐Gil, L., Romero‐González, R., Frenich, A. G., & Vidal, J. L. M. (2007) · Journal of Separation Science · doi:10.1002/jssc.200700299 · Cited by 50 · see citing works
Stir bar sorptive extraction for the determination of pyrethroids in water samples
Hoeck, E. V., David, F., & Sandra, P. J. F. (2007) · Journal of Chromatography A · doi:10.1016/j.chroma.2007.04.036 · Cited by 48 · see citing works
Hu, L., Zhang, P., Shan, W., Wang, X., Li, S., Zhou, W., & Gao, H. (2015) · Talanta · doi:10.1016/j.talanta.2015.05.077 · Cited by 46 · see citing works
Giokas, D. L., Tsogas, G. Z., Vlessidis, A. G., et al. (2004) · Analytical Chemistry · doi:10.1021/ac0303517 · Cited by 43 · see citing works
Ebrahimpour, B., Yamini, Y., & Moradi, M. (2012) · Journal of Pharmaceutical and Biomedical Analysis · doi:10.1016/j.jpba.2012.03.028 · Cited by 40 · see citing works
Self-citationCaballo, C., Sicilia, M. D., & Rubio, S. (2012) · Analytica Chimica Acta · doi:10.1016/j.aca.2012.11.044 · Cited by 32 · see citing works
Yılmaz, E., & Soylak, M. (2014) · RSC Advances · doi:10.1039/c4ra08209e · Cited by 31 · see citing works
Tayyebi, M., Yamini, Y., & Moradi, M. (2012) · Journal of Separation Science · doi:10.1002/jssc.201200150 · Cited by 31 · see citing works
Self-citationYan, H., Du, J., Zhang, X., Yang, G., Row, K. H., & Lv, Y. (2010) · Journal of Separation Science · doi:10.1002/jssc.200900716 · Cited by 30 · see citing works
Rezaei, F., Yamini, Y., & Moradi, M. (2014) · Journal of Chromatography A · doi:10.1016/j.chroma.2013.12.063 · Cited by 27 · see citing works
Self-citationCardeñosa, V., Lunar, M. L., & Rubio, S. (2011) · Journal of Chromatography A · doi:10.1016/j.chroma.2011.10.041 · Cited by 27 · see citing works
Vichapong, J., Srijaranai, S., Santaladchaiyakit, Y., Kanchanamayoon, W., & Burakham, R. (2015) · Food Analytical Methods · doi:10.1007/s12161-015-0291-7 · Cited by 24 · see citing works
Shang, Y., Liu, H., Hu, Y., et al. (2007) · Colloids and Surfaces A Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2007.01.051 · Cited by 24 · see citing works
Caballero‐Casero, N., García-Fonseca, S., & Rubio, S. (2011) · Talanta · doi:10.1016/j.talanta.2011.12.046 · Cited by 17 · see citing works
Bagheri, H., Ghanbarnejad, H., & Khalilian, F. (2009) · Journal of Separation Science · doi:10.1002/jssc.200900044 · Cited by 17 · see citing works
Ferdowsi, M., Taghian, A., Najafi, A., & Moradi, M. (2014) · Journal of Separation Science · doi:10.1002/jssc.201401023 · Cited by 13 · see citing works
Self-citationPirsaheb, M., Ahmadi-Jouibari, T., Fattahi, N., et al. (2013) · Journal of Chromatographic Science · doi:10.1093/chromsci/bmt133 · Cited by 11 · see citing works
Naddaf, E., Ebrahimi, M., Es’haghi, Z., et al. (2015) · Analytical Methods · doi:10.1039/c5ay01344e · Cited by 5 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Aydin, F., Yilmaz, E., & Soylak, M. (2018) · Food Chemistry · doi:10.1016/j.foodchem.2017.09.154 · Cited by 171 · see citing works
Use of green alternative solvents in dispersive liquid‐liquid microextraction: A review
Grau, J., Azorín, C., Benedé, J. L., Chisvert, A., & Salvador, A. (2022) · Journal of Separation Science · doi:10.1002/jssc.202100609 · Cited by 131 · see citing works
Development and challenges of supramolecular solvents in liquid-based microextraction methods
Moradi, M., Yamini, Y., & Feizi, N. (2021) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2021.116231 · Cited by 74 · see citing works
Self-citation
- Authors
- Feizi, N., Yamini, Y., Moradi, M., & Ebrahimpour, B.
- Affiliations
- Tarbiat Modares University (IR)
- Materials and Energy Research Center (IR)
- Corresponding author
- Yamini, Yadollah
- Venue
- Journal of Separation Science
- Publisher
- Wiley
- Published
- 2016-08-03
- Volume
- 39
- Issue
- 17
- Pages
- 3400-3409
- ISSN
- 1615-9306 (ISSN-L)
- 1615-9314
- OpenAlex
- W2463987643
- Cited by
- 18
- References
- 43
- Citations by year
- 2026: 1 · 2024: 1 · 2023: 1 · 2022: 1 · 2021: 3 · 2019: 3 · 2018: 3 · 2017: 4 · 2016: 1
- FWCI
- 2.90
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Separation Science (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Tarbiat Modares University
- Topics
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Physical Sciences › Chemistry › Organic Chemistry › Surfactants and Colloidal Systems
- Life Sciences › Agricultural and Biological Sciences › Food Science › Pesticide Residue Analysis and Safety
- Keywords
- supramolecular solvents, gemini surfactants, coacervates, liquid-liquid extraction, microextraction, cyhalothrin, fenvalerate, pyrethroid insecticides, preconcentration, water and soil samples, surfactant-rich phase
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review