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Copolymerization of carbon dioxide and epoxide with organometallic compounds
Abstract
Attempts to copolymerize carbon dioxide with epoxide led us to the first success in using carbon dioxide as a direct starting material for synthesizing high polymers. Some organometallic catalyst systems were found to catalyze the alternate copolymerization of carbon dioxide and epoxide, resulting in the formation of polycarbonates, the structures of which were confirmed with the aid of IR, NMR and elemental analysis. Diethylzinc‐water system produced a methanol insoluble aliphatic polycarbonate of much higher molecular weight than that produced by polycondensation. Thermal properties of the methanol insoluble polycarbonate were studied by differential thermal analysis and thermogravimetric analysis.
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Citations
Cited by
Darensbourg, D. J. (2007) · Chemical Reviews · doi:10.1021/cr068363q · Cited by 1,593
Coates, G. W., & Moore, D. R. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200460442 · Cited by 1,154
Reactive Applications of Cyclic Alkylene Carbonates
Clements, J. H. (2003) · Industrial & Engineering Chemistry Research · doi:10.1021/ie020678i · Cited by 784
Recent advances in CO2/epoxide copolymerization—New strategies and cooperative mechanisms
Klaus, S., Lehenmeier, M. W., Anderson, C. E., & Rieger, B. (2011) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2010.12.002 · Cited by 710
Stereoselective Epoxide Polymerization and Copolymerization
Childers, M. I., Longo, J. M., Van Zee, N. J., LaPointe, A. M., & Coates, G. W. (2014) · Chemical Reviews · doi:10.1021/cr400725x · Cited by 471
Metadata
- Authors
- Inoue, S., Koinuma, H., & Tsuruta, T.
- Venue
- Die Makromolekulare Chemie
- Publisher
- Wiley
- Published
- 1969-12-29
- Volume
- 130
- Issue
- 1
- Pages
- 210-220
- ISSN
- 0025-116X (ISSN-L)
- OpenAlex
- W1897876079
- Cited by
- 571
- References
- 0
- FWCI
- 4.86
- Type
- journal article
- Language
- en
- Open access
- closed
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- Inoue, S., Koinuma, H., & Tsuruta, T. (1969). Copolymerization of carbon dioxide and epoxide with organometallic compounds. Die Makromolekulare Chemie. https://doi.org/10.1002/macp.1969.021300112
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