Interactions of Ionic Liquids with Polysaccharides – 7: Thermal Stability of Cellulose in Ionic Liquids and N‐Methylmorpholine‐N‐oxide
Abstract
The thermal behavior of cellulose dissolved in ionic liquids was studied in comparison to NMMO solutions. The cellulose solutions were characterized by reaction calorimetry and UV‐vis spectroscopy. Generation of chromophoric substances in cellulose/IL solutions is minimized by exposing to temperatures of above 100 °C for longer time periods. Dynamic calorimetric investigations revealed first thermal activities above 180 °C applying EMIMac and above 200 °C for BMIMCl and five other ILs tested. Moreover, even in the case of modified cellulose/IL solutions, e.g., activated charcoal, only a slight decline of onset temperatures was registered compared to modified cellulose/NMMO solutions. magnified image
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A range of ionic liquids, typically with 1,3-dialkylimidazolium cations, are effective cellulose solvents.
“More recently, it has been demonstrated that a range of ionic liquids, typically with 1,3-dialkylimidazolium cations, are also effective cellulose solvents.69”
From Deconstruction of lignocellulosic biomass with ionic liquids (2013) · cites this paper as [69]
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- Authors
- Dorn, S., Wendler, F., Meister, F., & Heinze, T.
- Affiliations
- Friedrich Schiller University Jena (DE)
- Thuringian Institute of Textile and Plastics Research (DE)
- Corresponding author
- Wendler, Frank
- Heinze, Thomas
- Venue
- Macromolecular Materials and Engineering
- Publisher
- Wiley
- Published
- 2008-11-03
- Volume
- 293
- Issue
- 11
- Pages
- 907-913
- ISSN
- 1438-7492 (ISSN-L)
- 1439-2054
- OpenAlex
- W2009072736
- Cited by
- 44
- References
- 21
- Citations by year
- 2023: 2 · 2022: 1 · 2021: 3 · 2020: 4 · 2019: 4 · 2018: 4 · 2017: 5 · 2016: 2 · 2015: 3 · 2014: 1 · 2013: 2 · 2012: 3
- FWCI
- 1.43
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecular Materials and Engineering (publishedVersion)
- Funders
- Deutsche Bundesstiftung Umwelt (24762-31)
- Topics
- Physical Sciences › Materials Science › Biomaterials › Advanced Cellulose Research Studies
- Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
- Physical Sciences › Engineering › Biomedical Engineering › Lignin and Wood Chemistry
- Keywords
- ionic liquids, cellulose, thermal stability, N-methylmorpholine N-oxide, cellulose dissolution, reaction calorimetry, activated carbon, modified cellulose
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