Thermal Degradation of Ionic Liquids at Elevated Temperatures
Abstract
Ionic liquids based on the imidazolium cation are found to degrade, yielding volatile degradation products, at temperatures significantly lower than previously reported and thus a parameter T z / x (the maximum operating temperature) is developed to provide a more appropriate estimate of thermal stability.
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Emel′yanenko, V. N., Verevkin, S. P., & Heintz, A. (2007) · Journal of the American Chemical Society · doi:10.1021/ja0679174 · Cited by 367 · see citing works
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“[6] A1% degradation of the salt is at constant temperature only marginally accelerated by air.[47] The RTIL [C10mim][PF6] is carbonized in heating in air at 200◦C.”
BackgroundA physicochemical investigation of ionic liquid mixtures
Clough, M. T., Crick, C. R., Gräsvik, J., Hunt, P. A., Niedermeyer, H., Welton, T., & Whitaker, O. P. (2014) · Chemical Science · doi:10.1039/c4sc02931c · Cited by 185 · see citing works
Practical considerations associated with voltammetric studies in room temperature ionic liquids
Zhang, J., & Bond, A. M. (2005) · The Analyst · doi:10.1039/b504721h · Cited by 184 · see citing works
Basile, A., Hilder, M., Makhlooghiazad, F., Pozo‐Gonzalo, C., MacFarlane, D. R., Howlett, P. C., & Forsyth, M. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201703491 · Cited by 179 · see citing works
Self-citationIonic liquids: not always innocent solvents for cellulose
Clough, M. T., Geyer, K., Hunt, P. A., Son, S., Vagt, U., & Welton, T. (2014) · Green Chemistry · doi:10.1039/c4gc01955e · Cited by 177 · see citing works
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Ghaedi, H., Ayoub, M., Sufian, S. B., Lal, B., & Uemura, Y. (2017) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2017.07.016 · Cited by 173 · see citing works
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Abedin, S. Z. E., & Endres, F. (2007) · Accounts of Chemical Research · doi:10.1021/ar700049w · Cited by 168 · see citing works
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Rickert, P. G., Antonio, M. R., Firestone, M. A., Kubatko, K. H., Szreder, T., Wishart, J. F., & Dietz, M. L. (2007) · The Journal of Physical Chemistry B · doi:10.1021/jp0671751 · Cited by 166 · see citing works
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Philippi, F., & Welton, T. (2021) · Physical Chemistry Chemical Physics · doi:10.1039/d1cp00216c · Cited by 155 · see citing works
‘Green’ leaching: recyclable and selective leaching of gold-bearing ore in an ionic liquid
Whitehead, J. A., Lawrance, G. A., & McCluskey, A. (2004) · Green Chemistry · doi:10.1039/b406148a · Cited by 153 · see citing works
Kohagen, M., Brehm, M., Thar, J., et al. (2010) · The Journal of Physical Chemistry B · doi:10.1021/jp109612k · Cited by 152 · see citing works
Whitehead, J. A., Zhang, J., Pereira, N. G. A., et al. (2007) · Hydrometallurgy · doi:10.1016/j.hydromet.2007.03.009 · Cited by 144 · see citing works
Ohtani, H., Ishimura, S., & Kumai, M. (2008) · Analytical Sciences · doi:10.2116/analsci.24.1335 · Cited by 143 · see citing works
Purity specification methods for ionic liquids
Stark, A., Behrend, P., Braun, O., Müller, A., Ranke, J., Ondruschka, B., & Jastorff, B. (2008) · Green Chemistry · doi:10.1039/b808532c · Cited by 143 · see citing works
Seeberger, A., Andresen, A.-K., & Jess, A. (2009) · Physical Chemistry Chemical Physics · doi:10.1039/b909624h · Cited by 141 · see citing works
Thermal Stability of Ionic Liquids for Their Application as New Absorbents
Villanueva, M., Coronas, A., Garcı́a, J., & Salgado, J. (2013) · Industrial & Engineering Chemistry Research · doi:10.1021/ie401656e · Cited by 139 · see citing works
Heym, F., Etzold, B. J. M., Kern, C., et al. (2011) · Green Chemistry · doi:10.1039/c0gc00876a · Cited by 139 · see citing works
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Chambreau, S. D., Schneider, S., Rosander, M., et al. (2008) · The Journal of Physical Chemistry A · doi:10.1021/jp8038175 · Cited by 137 · see citing works
Yan, H., Peng, J., Hu, S., et al. (2010) · Thermochimica Acta · doi:10.1016/j.tca.2010.01.013 · Cited by 136 · see citing works
Thermostability of imidazolium ionic liquids as direct solvents for cellulose
Wendler, F., Todi, L.-N., & Meister, F. (2012) · Thermochimica Acta · doi:10.1016/j.tca.2011.11.015 · Cited by 134 · see citing works
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Self-citationConfined rapid thermolysis/FTIR/ToF studies of imidazolium-based ionic liquids
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Paulechka, Y. U., Kabo, G. J., Blokhin, A. V., et al. (2006) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2006.05.008 · Cited by 124 · see citing works
Vo Dinh, T., Saravana, P. S., Woo, H. C., & Chun, B. S. (2018) · Separation and Purification Technology · doi:10.1016/j.seppur.2017.06.009 · Cited by 120 · see citing works
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Pereiro, A. B., Veiga, H. I. M., Esperança, J. M. S. S., et al. (2009) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2009.06.020 · Cited by 115 · see citing works
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Haerens, K., Deuren, S. V., Matthijs, E., & der Bruggen, B. V. (2010) · Green Chemistry · doi:10.1039/c0gc00406e · Cited by 110 · see citing works
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Cassity, C. G., Mirjafari, A., Mobarrez, N., Strickland, K. J., O’Brien, R. A., & Davis, J. H. (2013) · Chemical Communications · doi:10.1039/c3cc44118k · Cited by 108 · see citing works
Łachwa, J., Morgado, P., Esperança, J. M. S. S., et al. (2006) · Journal of Chemical & Engineering Data · doi:10.1021/je060307z · Cited by 106 · see citing works
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“[13] A.”
BackgroundHeym, F., Etzold, B. J. M., Kern, C., et al. (2010) · Physical Chemistry Chemical Physics · doi:10.1039/c0cp00097c · Cited by 102 · see citing works
Pretreatment of eucalyptus with recycled ionic liquids for low-cost biorefinery
Xu, J., Liu, B., Hou, H., et al. (2017) · Bioresource Technology · doi:10.1016/j.biortech.2017.03.081 · Cited by 101 · see citing works
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Kamavaram, V., & Reddy, R. G. (2007) · International Journal of Thermal Sciences · doi:10.1016/j.ijthermalsci.2007.06.012 · Cited by 101 · see citing works
Chen, Y., Cao, Y., Shi, Y., et al. (2012) · Industrial & Engineering Chemistry Research · doi:10.1021/ie300247v · Cited by 101 · see citing works
Chancelier, L., Diallo, A.-O., Santini, C. C., et al. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp54225d · Cited by 92 · see citing works
Fox, D. M., Gilman, J. W., Long, H. C. D., et al. (2005) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2005.04.020 · Cited by 92 · see citing works
Badgujar, K. C., Wilson, L. D., & Bhanage, B. M. (2018) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2018.12.007 · Cited by 91 · see citing works
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Lovelock, K. R. J., Deyko, A., Licence, P., et al. (2010) · Physical Chemistry Chemical Physics · doi:10.1039/c004197a · Cited by 90 · see citing works
Sans, V., Karbass, N., Burguete, M. I., et al. (2011) · Chemistry - A European Journal · doi:10.1002/chem.201001873 · Cited by 89 · see citing works
Ghaedi, H., Ayoub, M., Sufian, S. B., Lal, B., & Shariff, A. M. (2017) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2017.05.020 · Cited by 89 · see citing works
Shaplov, A. S., Morozova, S. M., Lozinskaya, E. I., et al. (2015) · Polymer Chemistry · doi:10.1039/c5py01553g · Cited by 88 · see citing works
Thermophysical properties of phosphonium-based ionic liquids
Bhattacharjee, A., Lopes‐da‐Silva, J. A., Freire, M. G., et al. (2015) · Fluid Phase Equilibria · doi:10.1016/j.fluid.2015.05.009 · Cited by 87 · see citing works
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Baker, G. A., & Baker, S. N. (2005) · Australian Journal of Chemistry · doi:10.1071/ch05028 · Cited by 83 · see citing works
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Leones, R., Sentanin, F., Rodrigues, L. C., Marrucho, I. M., Esperança, J. M. S. S., Pawlicka, A., & Silva, M. M. P. (2012) · eXPRESS Polymer Letters · doi:10.3144/expresspolymlett.2012.106 · Cited by 82 · see citing works
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Kar, M., Plechkova, N. V., Seddon, K. R., et al. (2018) · Australian Journal of Chemistry · doi:10.1071/ch18541 · Cited by 81 · see citing works
Self-citationRegeneration, Recovery and Removal of Ionic Liquids
Fernández, J. F., Neumann, J., & Thöming, J. (2011) · Current Organic Chemistry · doi:10.2174/138527211795703676 · Cited by 80 · see citing works
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Piper, S. L., Kar, M., MacFarlane, D. R., et al. (2021) · Green Chemistry · doi:10.1039/d1gc03420k · Cited by 79 · see citing works
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Shiddiky, M. J. A., Torriero, A. A. J., Zhao, C., et al. (2009) · Journal of the American Chemical Society · doi:10.1021/ja8092295 · Cited by 77 · see citing works
Tao, R., Tamas, G. G., Xue, L., et al. (2014) · Journal of Chemical & Engineering Data · doi:10.1021/je500185r · Cited by 75 · see citing works
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Chambreau, S. D., Boatz, J. A., Vaghjiani, G. L., et al. (2011) · The Journal of Physical Chemistry A · doi:10.1021/jp209389d · Cited by 70 · see citing works
- Authors
- Baranyai, K. J., Deacon, G. B., MacFarlane, D. R., Pringle, J. M., & Scott, J. L.
- Venue
- Australian Journal of Chemistry
- Publisher
- CSIRO Publishing
- Published
- 2004-01-29
- Volume
- 57
- Issue
- 2
- Pages
- 145-147
- ISSN
- 0004-9425 (ISSN-L)
- 1445-0038
- OpenAlex
- W2149540480
- Cited by
- 338
- References
- 0
- Citations by year
- 2026: 1 · 2025: 8 · 2024: 10 · 2023: 8 · 2022: 9 · 2021: 13 · 2020: 15 · 2019: 13 · 2018: 11 · 2017: 27 · 2016: 20 · 2015: 20 · 2014: 25 · 2013: 23 · 2012: 19
- FWCI
- 7.39
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Australian Journal of Chemistry (publishedVersion)
- Topics
- Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
- Physical Sciences › Engineering › Mechanical Engineering › Lubricants and Their Additives
- Physical Sciences › Chemistry › Organic Chemistry › N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Keywords
- ionic liquids, thermal degradation, imidazolium cations, thermal stability, degradation products, maximum operating temperature
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