The DOI matches its Crossref record; 20 of the 20 references it cites were found in a registry or an index.
Kinetic Study and New Applications of UV Radiation Curing
Abstract
Highly crosslinked polymers can be readily synthesized by photoinitiated polymerization of multifunctional monomers or functionalized polymers. The reaction can be followed in situ by real‐time infrared (RT‐IR) spectroscopy, a technique that records conversion versus time curves in photosensitive resins undergoing ultrafast polymerization upon UV exposure. For acrylate‐based resins, UV‐curing proceeds with long kinetic chains (7700 mol/radical) in spite of the high initiation rate. RT‐IR spectroscopy proved very valuable in assessing the influence of various parameters, such as initiation efficiency, chemical structure of the telechelic oligomer, light intensity, inhibitory effect of oxygen, on polymerization kinetics. Interpenetrating polymer networks can be rapidly synthesized by means of UV irradiation of a mixture of difunctional acrylate and epoxy monomers in the presence of both radical and cationic‐type photoinitiators. The same UV technology can be applied to crosslink solid polymers at ambient temperature, which bear different types of reactive groups (acrylate and vinyl double bonds, epoxy ring). UV radiation curing has been successfully used to produce within seconds weathering resistant protective coatings, high‐resolution relief images, glass laminates and nanocomposites materials. Photoinitiated crosslinking polymerization. magnified imagePhotoinitiated crosslinking polymerization.
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Cites
Alexandre, M., & Dubois, P. (2000) · Materials Science and Engineering: R: Reports · doi:10.1016/s0927-796x(00)00012-7 · Cited by 6,377
Polymeric Materials Encyclopedia
(1996) · Polymers and Polymer Composites · doi:10.1177/147823919600400209 · Cited by 1,678
Photopolymerization kinetics of multifunctional monomers
Andrzejewska, E. (2001) · Progress in Polymer Science · doi:10.1016/s0079-6700(01)00004-1 · Cited by 944
Radiation curing in polymer science and technology
Fouassier, J., & Rabek, J. F. (1993) · Elsevier eBooks · Cited by 700
Photoinitiated crosslinking polymerisation
Decker, C. (1996) · Progress in Polymer Science · doi:10.1016/0079-6700(95)00027-5 · Cited by 686
Self-citationKinetic approach of oxygen inhibition in ultraviolet- and laser-induced polymerizations
Decker, C., & Jenkins, A. D. (1985) · Macromolecules · doi:10.1021/ma00148a034 · Cited by 527
Self-citationCramer, N. B., & Bowman, C. N. (2001) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.1314 · Cited by 510
Network formation by chain crosslinking photopolymerization and its applications in electronics
Kloosterboer, J. G. (2005) · Advances in Polymer Science · doi:10.1007/bfb0025902 · Cited by 492
The use of UV irradiation in polymerization
Decker, C. (1998) · Polymer International · doi:10.1002/(sici)1097-0126(199802)45:2<133::aid-pi969>3.0.co;2-f · Cited by 423
Self-citationThe effect of cure rate on the mechanical properties of dental resins
Lovell, L. G., Lu, H., Elliott, J. E., Stansbury, J. W., & Bowman, C. N. (2001) · Dental Materials · doi:10.1016/s0109-5641(01)00010-0 · Cited by 382
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Rodriguez, E. D., Luo, X., & Mather, P. T. (2011) · ACS Applied Materials & Interfaces · doi:10.1021/am101012c · Cited by 381
Waterborne polyurethane nanocomposites having shape memory effects
Lee, S. K., Yoon, S. H., Chung, I., Hartwig, A., & Kim, B. K. (2011) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.24473 · Cited by 62
3D printing a biocompatible elastomer for modeling muscle regeneration after volumetric muscle loss
Kiratitanaporn, W., Berry, D. B., Mudla, A., Fried, T., Lao, A., Yu, C., Hao, N., Ward, S. R., & Chen, S. (2022) · Biomaterials Advances · doi:10.1016/j.bioadv.2022.213171 · Cited by 20
Metadata
- Authors
- Decker, C.
- Venue
- Macromolecular Rapid Communications
- Publisher
- Wiley
- Published
- 2002-12
- Volume
- 23
- Issue
- 18
- Pages
- 1067-1093
- ISSN
- 1022-1336 (ISSN-L)
- 1521-3927
- OpenAlex
- W1963997294
- Cited by
- 688
- References
- 20
- FWCI
- 8.56
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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