Waterborne polyurethane nanocomposites having shape memory effects
Abstract
UV curable waterborne polyurethane/silica nanocomposites were designed and synthesized with functionalized silicas, where the functionalization was made with allyl isocyanate. The incorporated silica particles gave triple effects of multifunctional chemical cross‐links, reinforcing fillers, and stress relaxation retarders. Consequently, functionalized silica incorporated into the polymer chains showed significantly improved mechanical and thermal properties than the simple addition of unmodified silica. Notably, over 99% shape fixity and shape recovery with minimum cyclic hysteresis were obtained for the repeated cycles at 1% loading of the modified silica. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011
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Functionalized silica particles had the function of both reinforcing fillers and stress relaxation retarders.
“It was demonstrated that the functionalized silica particles had the function of both reinforcing fillers and stress relaxation retarders.”
From A review of stimuli-responsive shape memory polymer composites (2013) · cites this paper as [327]
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Photoactive Properties of Nanostructured Titania Modified Polyurethanes
Chen, C. (2017) · Scholarship@Western (Western University)
- Authors
- Lee, S. K., Yoon, S. H., Chung, I., Hartwig, A., & Kim, B. K.
- Affiliations
- Pusan National University (KR)
- Fraunhofer Institute for Manufacturing Technology and Advanced Materials (DE)
- Corresponding author
- Kim, Byung Kyu
- Venue
- Journal of Polymer Science Part A: Polymer Chemistry
- Publisher
- Wiley
- Published
- 2010-12-02
- Volume
- 49
- Issue
- 3
- Pages
- 634-641
- ISSN
- 0887-624X (ISSN-L)
- 1099-0518
- OpenAlex
- W2030757812
- Cited by
- 62
- References
- 40
- Citations by year
- 2024: 1 · 2023: 1 · 2022: 2 · 2021: 4 · 2020: 2 · 2019: 6 · 2018: 3 · 2017: 3 · 2016: 9 · 2015: 4 · 2014: 11 · 2013: 9 · 2012: 4
- FWCI
- 4.23
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Polymer Science Part A Polymer Chemistry (publishedVersion)
- Fraunhofer-Publica (Fraunhofer-Gesellschaft) (submittedVersion)
- Funders
- National Research Foundation of Korea, and organized at PNU
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Chemistry › Organic Chemistry › Photopolymerization techniques and applications
- Keywords
- waterborne polyurethane, silica nanocomposites, shape memory effect, UV-curable polymers, functionalized silica, crosslinking, shape fixity, shape recovery, cyclic hysteresis, mechanical properties, thermal properties
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