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Isoconversional Kinetic Analysis of Thermally Stimulated Processes in Polymers

Vyazovkin, Sergey, Sbirrazzuoli, Nicolas·2006·Macromolecular Rapid Communications

Abstract

Summary:Isoconversional kinetic analysis involves evaluating a dependence of the effective activation energy on conversion or temperature and using this dependence for making kinetic predictions and for exploring the mechanisms of thermally stimulated processes. The paper discusses major results obtained by the authors in the area of the isoconversional analysis of polymer kinetics over the past decade. It provides a brief introduction to isoconversional methods and surveys the impact made by isoconversional analysis in several application areas that include kinetic predictions, thermal degradation, crosslinking (curing), glass transition, and glass and melt crystallization. It is concluded that isoconversional analysis has been used broadly and fruitfully because it presents a fortunate compromise between the single‐step Arrhenius kinetic treatments and the prevalent occurrence of processes whose kinetics are multi‐step and/or non‐Arrhenius. An isoconversional method applies the Arrhenius equation to a narrow temperature region, Δ T related to a given extent of conversion. magnified imageAn isoconversional method applies the Arrhenius equation to a narrow temperature region, Δ T related to a given extent of conversion.

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Metadata

Authors
Vyazovkin, S., & Sbirrazzuoli, N.
Venue
Macromolecular Rapid Communications
Publisher
Wiley
Published
2006-09-22
Volume
27
Issue
18
Pages
1515-1532
ISSN
  • 1022-1336 (ISSN-L)
  • 1521-3927
OpenAlex
W1969945203
Cited by
1,116
References
44
FWCI
28.00
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Isoconversional Kinetic Analysis of Thermally Stimulated Processes in Polymers. https://app.cochat.ai/papers/10.1002/marc.200600404
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Vyazovkin, S., & Sbirrazzuoli, N. (2006). Isoconversional Kinetic Analysis of Thermally Stimulated Processes in Polymers. Macromolecular Rapid Communications. https://doi.org/10.1002/marc.200600404

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