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Structural studies of polyethers. IX. Planar zigzag modification of poly(ethylene oxide)
Abstract
A new crystal modification was found in poly(ethylene oxide) stretched about two‐fold after necking at room temperature. An x‐ray diffraction analysis indicated that the planar zigzag molecule passes through a triclinic unit cell with parameters α = 4.71 Å, b = 4.44 Å, c (fiber axis) = 7.12 Å, α = 62.8°, β = 93.2°, and γ = 111.4°. The space group is P1−Ci1. Packing of the molecule is very similar to that of monoclinic polyethylene.
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Cited by
Zhu, L., Cheng, S. Z. D., Calhoun, B. H., Ge, Q., Quirk, R. P., Thomas, E. L., Hsiao, B. S., Yeh, F., & Lotz, B. (2000) · Journal of the American Chemical Society · doi:10.1021/ja000275e · Cited by 400
Crystallinity and Chain Conformation in PEO/Layered Silicate Nanocomposites
Chrissopoulou, K., Andrikopoulos, K. S., Fotiadou, S., Bollas, S., Karageorgaki, C., Christofilos, D., Voyiatzis, G. A., & Anastasiadis, S. H. (2011) · Macromolecules · doi:10.1021/ma201711r · Cited by 134
Suzuki, Y., Duran, H., Steinhart, M., Butt, H.-J., & Floudas, G. (2013) · Soft Matter · doi:10.1039/c2sm27618f · Cited by 115
Tuning polymer crystallinity via the appropriate selection of inorganic nanoadditives
Papananou, H., Perivolari, E., Chrissopoulou, K., & Anastasiadis, S. H. (2018) · Polymer · doi:10.1016/j.polymer.2018.10.018 · Cited by 64
Samanta, P., Srivastava, R., Nandan, B., & Chen, H.-L. (2017) · Soft Matter · doi:10.1039/c6sm02748b · Cited by 22
Metadata
- Authors
- Takahashi, Y., Sumita, I., & Tadokoro, H.
- Venue
- Journal of Polymer Science: Polymer Physics Edition
- Publisher
- Wiley
- Published
- 1973-11
- Volume
- 11
- Issue
- 11
- Pages
- 2113-2122
- ISSN
- 0098-1273 (ISSN-L)
- 1542-9385
- OpenAlex
- W2087188308
- Cited by
- 193
- References
- 0
- FWCI
- 3.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Takahashi, Y., Sumita, I., & Tadokoro, H. (1973). Structural studies of polyethers. IX. Planar zigzag modification of poly(ethylene oxide). Journal of Polymer Science: Polymer Physics Edition. https://doi.org/10.1002/pol.1973.180111103
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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