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Polyelectrolytes near the rod limit
Abstract
The problem of a polyelectrolyte near the rod limit is formulated incorporating both the short‐range stiffness of the backbone (the “wormlike chain”) and the electrostatic interaction between segments taken as a Debye–Húckel potential. By the use of a physically valid approximation an expression is derived for the mean‐square extension length of a short polyelectrolyte chain. Some remarks are made on the relationship between the electrostatic interaction and the usual excluded‐volume problem for polymer solutions.
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Citations
Cited by
Theory of polyelectrolytes in solutions and at surfaces
DOBRYNIN, A., & RUBINSTEIN, M. (2005) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2005.07.006 · Cited by 1,539
Usov, I., Nyström, G., Adamcik, J., Handschin, S., Schütz, C., Fall, A., Bergström, L., & Mezzenga, R. (2015) · Nature Communications · doi:10.1038/ncomms8564 · Cited by 498
Structure and interactions of biological helices
Kornyshev, A. A., Lee, D. J., Leikin, S., & Wynveen, A. (2007) · Reviews of Modern Physics · doi:10.1103/revmodphys.79.943 · Cited by 320
Fong, K. D., Self, J., Diederichsen, K. M., Wood, B. M., McCloskey, B. D., & Persson, K. A. (2019) · ACS Central Science · doi:10.1021/acscentsci.9b00406 · Cited by 239
Metadata
- Authors
- Odijk, T.
- Venue
- Journal of Polymer Science: Polymer Physics Edition
- Publisher
- Wiley
- Published
- 1977-03
- Volume
- 15
- Issue
- 3
- Pages
- 477-483
- ISSN
- 0098-1273 (ISSN-L)
- 1542-9385
- OpenAlex
- W2066139999
- Cited by
- 744
- References
- 0
- FWCI
- 3.47
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Polyelectrolytes near the rod limit. https://app.cochat.ai/papers/10.1002/pol.1977.180150307
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- Odijk, T. (1977). Polyelectrolytes near the rod limit. Journal of Polymer Science: Polymer Physics Edition. https://doi.org/10.1002/pol.1977.180150307
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