The DOI matches its Crossref record; 15 of the 15 references it cites were found in a registry or an index.
Effect of (3‐glycidyloxypropyl)trimethoxysilane (GOPS) on the electrical properties of PEDOT:PSS films
Open accessAbstract
Poly(3,4‐ethylenedioxythiophene) doped with poly(styrenesulfonate) (PEDOT:PSS) has been reported as a successful functional material in a broad variety of applications. One of the most important advantages of PEDOT:PSS is its water‐solubility, which enables simple and environmental friendly manufacturing processes. Unfortunately, this also implies that pristine PEDOT:PSS films are unsuitable for applications in aqueous environments. To reach stability in polar solvents, (3‐glycidyloxypropyl)trimethoxysilane (GOPS) is typically used to cross‐link PEDOT:PSS. Although this strategy is widely used, its mechanism and effect on PEDOT:PSS performance have not been articulated yet. Here, we present a broad study that provides a better understanding of the effect of GOPS on the electrical and electronic properties of PEDOT:PSS. We show that the GOPS reacts with the sulfonic acid group of the excess PSS, causing a change in the PEDOT:PSS film morphology, while the oxidation level of PEDOT remains unaffected. This is at the origin of the observed conductivity changes. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017, 55, 814–820
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Poly(3,4-ethylenedioxythiophene) and Its Derivatives: Past, Present, and Future
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Metadata
- Authors
- Håkansson, A., Han, S., Wang, S., Lu, J., Braun, S., Fahlman, M., Berggren, M., Crispin, X., & Fabiano, S.
- Venue
- Journal of Polymer Science Part B: Polymer Physics
- Publisher
- Wiley
- Published
- 2017-03-10
- Volume
- 55
- Issue
- 10
- Pages
- 814-820
- ISSN
- 0887-6266 (ISSN-L)
- 1099-0488
- OpenAlex
- W2591869179
- Cited by
- 292
- References
- 15
- FWCI
- 10.84
- Type
- journal article
- Language
- en
- Open access
- green
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