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Tailoring properties of borohydrides for hydrogen storage: A review
Abstract
Hydrogen is recognized as a possible future energy carrier, which can be produced from renewable energy and water. A major challenge in a future ‘hydrogen economy’ is the development of safe, compact, robust, and efficient means of hydrogen storage, in particular for mobile applications. The present review focuses on light metal boron based hydrides, for which the general interest has expanded significantly during the past few years. Synthesis methods, physical, chemical and structural properties of novel boron based hydrides are reviewed along with new approaches for improving kinetic and thermodynamic properties: (i) anion substitution, (ii) reactive hydride composites and (iii) nanoconfinement of hydrides and chemical reactions. The light metal borohydrides reveal a fascinating structural chemistry and have the potential for storing large amounts of hydrogen. A combination of the different approaches may provide a new route to a wide range of interesting energy storage materials in the future.
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Cites
Hydrogen storage: the remaining scientific and technological challenges
Felderhoff, M., Weidenthaler, C., von Helmolt, R., & Eberle, U. (2007) · Physical Chemistry Chemical Physics · doi:10.1039/b701563c · Cited by 532
Improved Hydrogen Storage Kinetics of Nanoconfined NaAlH4 Catalyzed with TiCl3 Nanoparticles
Nielsen, T. K., Polanski, M., Zasada, D., Javadian, P., Besenbacher, F., Bystrzycki, J., Skibsted, J., & Jensen, T. R. (2011) · ACS Nano · doi:10.1021/nn200643b · Cited by 117
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Cited by
Large-scale storage of hydrogen
Andersson, J., & Grönkvist, S. (2019) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2019.03.063 · Cited by 1,356
Hydrogen - A sustainable energy carrier
Møller, K. T., Jensen, T. R., Akiba, E., & Li, H.-W. (2017) · Progress in Natural Science: Materials International · doi:10.1016/j.pnsc.2016.12.014 · Cited by 939
Self-citationLarge-vscale hydrogen production and storage technologies: Current status and future directions
Olabi, A. G., bahri, A. S., Abdelghafar, A. A., Baroutaji, A., Sayed, E. T., Alami, A. H., Rezk, H., & Abdelkareem, M. A. (2021) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2020.10.110 · Cited by 492
Hydrogen Storage Materials for Mobile and Stationary Applications: Current State of the Art
Lai, Q., Paskevicius, M., Sheppard, D. A., Buckley, C. E., Thornton, A. W., Hill, M. R., Gu, Q., Mao, J., Huang, Z., Liu, H. K., et al. (2015) · ChemSusChem · doi:10.1002/cssc.201500231 · Cited by 414
Mechanochemical synthesis of hydrogen storage materials
Huot, J., Ravnsbæk, D. B., Zhang, J., Cuevas, F., Latroche, M., & Jensen, T. R. (2013) · Progress in Materials Science · doi:10.1016/j.pmatsci.2012.07.001 · Cited by 406
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Metadata
- Authors
- Rude, L. H., Nielsen, T. K., Ravnsbæk, D. B., Bösenberg, U., Ley, M. B., Richter, B., Arnbjerg, L. M., Dornheim, M., Filinchuk, Y., Besenbacher, F., & Jensen, T. R.
- Venue
- physica status solidi (a)
- Publisher
- Wiley
- Published
- 2011-07-11
- Volume
- 208
- Issue
- 8
- Pages
- 1754-1773
- ISSN
- 0031-8965 (ISSN-L)
- 1862-6300
- 1862-6319
- OpenAlex
- W1972701798
- Cited by
- 262
- References
- 2
- FWCI
- 15.65
- Type
- journal article
- Language
- en
- Open access
- closed
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- Rude, L. H., Nielsen, T. K., Ravnsbæk, D. B., Bösenberg, U., Ley, M. B., Richter, B., Arnbjerg, L. M., Dornheim, M., Filinchuk, Y., Besenbacher, F., & Jensen, T. R. (2011). Tailoring properties of borohydrides for hydrogen storage: A review. physica status solidi (a). https://doi.org/10.1002/pssa.201001214
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