The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Diffusivity fractionations of HO/HO and HO/HO in air and their implications for isotope hydrology
Abstract
We have determined the isotope effects of 17 O and 18 O substitution of 16 O in H 2 O on molecular diffusivities of water vapor in air by the use of evaporation experiments. The derived diffusion fractionation coefficients 17 α diff and 18 α diff are 1.0146 ± 0.0002 and 1.0283 ± 0.0003, respectively. We also determined, for the first time, the ratio ln( 17 α diff )/ln( 18 α diff ) as 0.5185 ± 0.0002. This ratio, which is in excellent agreement with the theoretical value of 0.5184, is significantly smaller than the ratio in vapor‐liquid equilibrium (0.529). We show how this new experimental information gives rise to 17 O excess in meteoric water, and how it can be applied in isotope hydrology. Copyright © 2007 John Wiley & Sons, Ltd.
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Horita, J., & Wesolowski, D. J. (1994) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(94)90096-5 · Cited by 940
Cited by
Stable isotopes in atmospheric water vapor and applications to the hydrologic cycle
Galewsky, J., Steen‐Larsen, H. C., Field, R. D., Worden, J., Risi, C., & Schneider, M. (2016) · Reviews of Geophysics · doi:10.1002/2015rg000512 · Cited by 489
Variations of 17O/16O and 18O/16O in meteoric waters
Luz, B., & Barkan, E. (2010) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2010.08.016 · Cited by 354
Self-citationIsotope effects in the evaporation of water: a status report of the Craig–Gordon model
Horita, J., Rozanski, K., & Cohen, S. (2008) · Isotopes in Environmental and Health Studies · doi:10.1080/10256010801887174 · Cited by 277
Equilibrium mass-dependent fractionation relationships for triple oxygen isotopes
Cao, X., & Liu, Y. (2011) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2011.09.048 · Cited by 152
Frontiers of stable isotope geoscience
Eiler, J. M., Bergquist, B., Bourg, I., Cartigny, P., Farquhar, J., Gagnon, A., Guo, W., Halevy, I., Hofmann, A., Larson, T. E., et al. (2014) · Chemical Geology · doi:10.1016/j.chemgeo.2014.02.006 · Cited by 121
Metadata
- Authors
- Barkan, E., & Luz, B.
- Venue
- Rapid Communications in Mass Spectrometry
- Publisher
- Wiley
- Published
- 2007-08-20
- Volume
- 21
- Issue
- 18
- Pages
- 2999-3005
- ISSN
- 0951-4198 (ISSN-L)
- 1097-0231
- OpenAlex
- W2016080370
- Cited by
- 255
- References
- 1
- FWCI
- 9.87
- Type
- journal article
- Language
- en
- Open access
- closed
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- Barkan, E., & Luz, B. (2007). Diffusivity fractionations of HO/HO and HO/HO in air and their implications for isotope hydrology. Rapid Communications in Mass Spectrometry. https://doi.org/10.1002/rcm.3180
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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