Frontiers of stable isotope geoscience

Eiler, John M.; Bergquist, Brigit; Bourg, Ian; Cartigny, Pierre; Farquhar, James; Gagnon, Alex; Guo, Weifu; Halevy, Itay; Hofmann, Amy; Larson, Toti E.; Levin, Naomi; Schauble, Edwin A.; Stolper, Daniel

doi:10.1016/j.chemgeo.2014.02.006

Cited by 121Geological and Geochemical AnalysisPaleontology and Stratigraphy of FossilsGroundwater and Isotope Geochemistry

Frontiers of stable isotope geoscience

Eiler, John M., Bergquist, Brigit, Bourg, Ian, Cartigny, Pierre, Farquhar, James, Gagnon, Alex, Guo, Weifu, Halevy, Itay +5 more·2014·Chemical Geology

DOI 10.1016/j.chemgeo.2014.02.006

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Questions regarding the fractionation processes of clumped isotopes are still under investigation.
“However, questions regarding the fractionation processes are still under investigation [51].”
From Isotope chemistry to trace carbon mineralization in construction materials (2026) · cites this paper as [51]
Carbonate clumped-isotope thermometry has been shown to yield accurate temperatures of formation for a wide range of geologic environments and synthetic carbonates.
“This approach has been shown to yield accurate temperatures of formation for a wide range of geologic environments and synthetic carbonates.”
From Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks (2016) · cites this paper as Eiler et al., 2014
Most natural and synthetic carbonates precipitate at or near homogenous isotope exchange equilibrium and yield clumped-isotope temperatures generally consistent with expected formation temperatures.
“Most natural and synthetic carbonates precipitate at or near homogenous isotope exchange equilibrium with respect to the carbonate ion contained in the mineral phase ( cf . Eq. (2) and Fig. A2) ( e.g. , Eiler, 2011) and yield clumped-isotope temperatures generally consistent with expected formation temperatures ( e.g. , Eiler et al., 2014).”
From Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks (2016) · cites this paper as Eiler et al., 2014
Nesquehonite records clumped-isotope compositions that result in anomalously warmer temperatures related to kinetic factors associated with dehydroxylation or dehydration of HCO3 and ensuing CO2 degassing.
“Comparable to calcium carbonate speleothems, nesquehonite records clumped-isotope compositions that result in anomalously warmer temperatures related to kinetic factors associated with dehydroxylation (Eiler et al., 2014) or dehydration (Affek and Zaarur, 2014) of HCO3 and ensuing CO2 degassing.”
From Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks (2016) · cites this paper as Eiler et al., 2014
The maximum isotopic disequilibrium that yields lower than expected temperatures in carbonates is recorded in surface corals at ~10 °C and in olivine-magnesite experiments at ~15 °C.
“Although it is possible that cryptocrystalline magnesite may form in disequilibrium with the mineralizing solution, so far the maximum isotopic disequilibrium that yields lower than expected temperatures in carbonates is recorded in surface corals at 10 ° C (Eiler et al., 2014) and the olivine-magnesite experiments at 15 ° C, which may exhibit pH disequilibrium effects (Section 5.1).”
From Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks (2016) · cites this paper as Eiler et al., 2014

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Authors: Eiler, J. M., Bergquist, B., Bourg, I., Cartigny, P., Farquhar, J., Gagnon, A., Guo, W., Halevy, I., Hofmann, A., Larson, T. E., Levin, N., Schauble, E. A., & Stolper, D.
Affiliations: California Institute of Technology (US)
University of Toronto (CA)
Lawrence Berkeley National Laboratory (US)
Institut de physique du globe de Paris (FR)
University of Maryland, College Park (US)
Woods Hole Oceanographic Institution (US)
Weizmann Institute of Science (IL)
Franklin & Marshall College (US)
The University of Texas at Austin (US)
Johns Hopkins University (US)
University of California, Los Angeles (US)
Corresponding author: Eiler, John M.
ORCID: Eiler, John M.
Bourg, Ian
Cartigny, Pierre
Farquhar, James
Guo, Weifu
Halevy, Itay
Hofmann, Amy
Larson, Toti E.
Levin, Naomi
Schauble, Edwin A.
Stolper, Daniel
Venue: Chemical Geology
Publisher: Elsevier BV
Published: 2014-04
Volume: 372
Pages: 119-143
ISSN: 0009-2541 (ISSN-L)
DOI: 10.1016/j.chemgeo.2014.02.006
OpenAlex: W2161266592
Cited by: 121
References: 306
Citations by year: 2026: 3 · 2025: 2 · 2024: 10 · 2023: 8 · 2022: 1 · 2021: 9 · 2020: 8 · 2019: 11 · 2018: 21 · 2017: 10 · 2016: 17 · 2015: 14 · 2014: 4 · 2013: 2
FWCI: 12.67
Type: journal article
Language: en
Open access: closed
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
www.elsevier.com/legal/tdmrep-license (tdm)
Locations: Chemical Geology (publishedVersion)
CaltechAUTHORS (California Institute of Technology) (submittedVersion)
Funders: Basic Energy Sciences
U.S. Department of Energy
Topics: Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
Keywords: stable isotope geochemistry, organic compounds, kinetic isotope effects, vibrational isotope effects, nuclear isotope effects

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