Equilibrium mass-dependent fractionation relationships for triple oxygen isotopes

Cao, Xiaobin; Liu, Yun

doi:10.1016/j.gca.2011.09.048

Cited by 152Geological and Geochemical AnalysisGroundwater and Isotope GeochemistryPaleontology and Stratigraphy of Fossils

Equilibrium mass-dependent fractionation relationships for triple oxygen isotopes

Cao, Xiaobin, Liu, Yun·2011·Geochimica et Cosmochimica Acta

DOI 10.1016/j.gca.2011.09.048

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The coordination environment of carbonate ions has limited importance in determining κ.
“These are in fact quite close to estimates for CO3 2- (g) from both Cao and Liu (2011) and the present study, suggesting that the coordination environment of carbonate ions has limited importance in determining κ .”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Cao and Liu (2011)
At 25°C our value of κ for CO3 2-(g) of 0.52880 is not resolvable from the result of Cao and Liu (2011).
“At 25 ° C our value of κ for CO3 2(g) of 0.52880 is not resolvable from their result.”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Cao and Liu (2011)
At 0, 50, 100, and 500°C our κ for CO2(g) (0.52784, 0.52810, 0.52835, and 0.52959) are within ~2x10^-5 of Cao and Liu (2011) results, and our results agree with Guo and Zhou (2019) in seeing very little difference between CO3 2-(aq), HCO3-(aq), and H2CO3(aq).
“At 0, 50, 100, and 500 ° C our κ for CO2(g) (0.52784, 0.52810, 0.52835, and 0.52959) (Table 4) are likewise within ~2x10 -5 of Cao and Liu (2011) results, and our results agree with Guo and Zhou (2019) in seeing very little difference between CO3 2- (aq), HCO3 - (aq), and H2CO3(aq).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Cao and Liu (2011)
Our κ values for CO2(g) and CO3 2-(g) using the B3LYP/6-311++G(2d,2p) method agree very closely with those of Cao and Liu (2011) and Guo and Zhou (2019).
“Our κ values for CO2(g) and CO3 2- (g) using the B3LYP/6-311++G(2d,2p) agree very closely with those of Cao and Liu (2011) and Guo and Zhou (2019), which is not surprising since both studies use very similar electronic structure methods.”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Cao and Liu (2011)

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Equilibrium Fe isotope fractionation between inorganic aqueous Fe(III) and the siderophore complex, Fe(III)-desferrioxamine B
Dideriksen, K., Baker, J. A., & Stipp, S. L. S. (2008) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2008.02.022 · Cited by 139 · see citing works

Authors: Cao, X., & Liu, Y.
Affiliations: Chinese Academy of Sciences (CN)
Corresponding author: Liu, Yun
ORCID: Cao, Xiaobin
Liu, Yun
Venue: Geochimica et Cosmochimica Acta
Publisher: Elsevier BV
Published: 2011-12
Volume: 75
Issue: 23
Pages: 7435-7445
ISSN: 0016-7037 (ISSN-L)
DOI: 10.1016/j.gca.2011.09.048
OpenAlex: W2098488652
Cited by: 152
References: 78
Citations by year: 2026: 3 · 2025: 14 · 2024: 9 · 2023: 8 · 2022: 11 · 2021: 31 · 2020: 17 · 2019: 13 · 2018: 9 · 2017: 9 · 2016: 14 · 2015: 4 · 2014: 6 · 2013: 2 · 2012: 2
FWCI: 2.86
Type: journal article
Language: en
Open access: closed
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
Locations: Geochimica et Cosmochimica Acta (publishedVersion)
Topics: Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
Keywords: triple oxygen isotopes, mass-dependent fractionation, kappa parameter, carbonates

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Equilibrium mass-dependent fractionation relationships for triple oxygen isotopes

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