Cited by 162Gold and Silver Nanoparticles Synthesis and ApplicationsLaser-Ablation Synthesis of NanoparticlesPlasmonic and Surface Plasmon Research

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Scalable Routes to Gold Nanoshells with Tunable Sizes and Response to Near‐Infrared Pulsed‐Laser Irradiation

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Abstract

A simplified synthesis of hollow gold nanoshells 20–50 nm in diameter via the well‐established templated galvanic replacement reaction of silver for gold is presented. The surface plasmon resonance absorbance of the nanoshells is tuned using basic colloid chemistry to control the size of the silver templates. The gold nanoshells have an aqueous core and are varied in size and shell thickness depending on the silver/gold reagent ratios. The template replacement chemistry is rapid, highly scalable, uses minimal amounts of toxic reagents, and in many cases is a true one‐pot synthesis. The smallest nanoshells (20‐nm diameter, 7‐nm wall thickness) reach the highest temperature on irradiation with femtosecond light pulses in the near infrared and anneal to form spherical nanoparticles fastest, even though their plasmon resonance does not overlap as well as the larger nanoshells (50‐nm diameter, 7‐nm wall thickness) with 800‐nm wavelength excitation.

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Metadata

Authors
Prevo, B. G., Esakoff, S. A., Mikhailovsky, A., & Zasadzinski, J. A.
Affiliations
University of California, Santa Barbara (US)
Corresponding author
Zasadzinski, Joseph A.
Venue
Small
Publisher
Wiley
Published
2008-07-31
Volume
4
Issue
8
Pages
1183-1195
ISSN
  • 1613-6810 (ISSN-L)
  • 1613-6829
OpenAlex
W2047742559
Cited by
162
References
2
Citations by year
2026: 1 · 2025: 2 · 2024: 5 · 2023: 6 · 2022: 6 · 2021: 8 · 2020: 6 · 2019: 21 · 2018: 11 · 2017: 12 · 2016: 12 · 2015: 11 · 2014: 15 · 2013: 13 · 2012: 8
FWCI
3.19
Type
journal article
Language
en
Open access
Locations
  • Small (publishedVersion)
  • PubMed (publishedVersion)
  • PubMed Central (acceptedVersion)
Funders
  • National Science Foundation
  • National Heart, Lung, and Blood Institute (HL080718, U01HL080718)
Topics
  • Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Gold and Silver Nanoparticles Synthesis and Applications
  • Physical Sciences › Materials Science › Materials Chemistry › Laser-Ablation Synthesis of Nanoparticles
  • Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Plasmonic and Surface Plasmon Research
Keywords
gold nanoshells, surface plasmon resonance tuning, near-infrared laser irradiation, femtosecond laser heating, one-pot synthesis, scalable synthesis, shell thickness control
MeSH terms
Chlorides, Gold, Infrared Rays, Lasers, Scattering, Radiation, Silver, Spectrophotometry, Ultraviolet, Gold Compounds, Spectroscopy, Near-Infrared, Surface Plasmon Resonance, Metal Nanoparticles

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CoChat. (2026). Citation check: Scalable Routes to Gold Nanoshells with Tunable Sizes and Response to Near‐Infrared Pulsed‐Laser Irradiation. https://app.cochat.ai/papers/10.1002/smll.200701290
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Prevo, B. G., Esakoff, S. A., Mikhailovsky, A., & Zasadzinski, J. A. (2008). Scalable Routes to Gold Nanoshells with Tunable Sizes and Response to Near‐Infrared Pulsed‐Laser Irradiation. Small. https://doi.org/10.1002/smll.200701290