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High‐Performance Aqueous Zinc–Ion Battery Based on Layered H2V3O8 Nanowire Cathode
Abstract
Rechargeable aqueous zinc–ion batteries have offered an alternative for large‐scale energy storage owing to their low cost and material abundance. However, developing suitable cathode materials with excellent performance remains great challenges, resulting from the high polarization of zinc ion. In this work, an aqueous zinc–ion battery is designed and constructed based on H 2 V 3 O 8 nanowire cathode, Zn(CF 3 SO 3)2 aqueous electrolyte, and zinc anode, which exhibits the capacity of 423.8 mA h g−1 at 0.1 A g−1, and excellent cycling stability with a capacity retention of 94.3% over 1000 cycles. The remarkable electrochemical performance is attributed to the layered structure of H 2 V 3 O 8 with large interlayer spacing, which enables the intercalation/de‐intercalation of zinc ions with a slight change of the structure. The results demonstrate that exploration of the materials with large interlayer spacing is an effective strategy for improving electrochemical stability of electrodes for aqueous Zn ion batteries.
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Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Opportunities and challenges for a sustainable energy future
Chu, S., & Majumdar, A. (2012) · Nature · doi:10.1038/nature11475 · Cited by 12,550
Cited by
Rechargeable Batteries for Grid Scale Energy Storage
Zhu, Z., Jiang, T., Ali, M., Meng, Y., Jin, Y., Cui, Y., & Chen, W. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00289 · Cited by 1,769
A Metal-Organic Framework Host for Highly Reversible Dendrite-free Zinc Metal Anodes
Wang, Z., Huang, J., Guo, Z., Dong, X., Liu, Y., Wang, Y., & Xia, Y. (2019) · Joule · doi:10.1016/j.joule.2019.02.012 · Cited by 938
Layered MgxV2O5·n H2O as Cathode Material for High-Performance Aqueous Zinc Ion Batteries
Ming, F., Liang, H., Lei, Y., Kandambeth, S., Eddaoudi, M., & Alshareef, H. N. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b01423 · Cited by 783
Design Strategies for Vanadium‐based Aqueous Zinc‐Ion Batteries
Wan, F., & Niu, Z. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201903941 · Cited by 759
Ultrafast Zn2+ Intercalation and Deintercalation in Vanadium Dioxide
Ding, J., Du, Z., Gu, L., Li, B., Wang, L., Wang, S., Gong, Y., & Yang, S. (2018) · Advanced Materials · doi:10.1002/adma.201800762 · Cited by 677
Metadata
- Authors
- He, P., Quan, Y., Xu, X., Yan, M., Yang, W., An, Q., He, L., & Mai, L.
- Venue
- Small
- Publisher
- Wiley
- Published
- 2017-11-20
- Volume
- 13
- Issue
- 47
- ISSN
- 1613-6810 (ISSN-L)
- 1613-6829
- OpenAlex
- W2770320004
- Cited by
- 613
- References
- 2
- FWCI
- 24.05
- Type
- journal article
- Language
- en
- Open access
- closed
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- He, P., Quan, Y., Xu, X., Yan, M., Yang, W., An, Q., He, L., & Mai, L. (2017). High‐Performance Aqueous Zinc–Ion Battery Based on Layered H2V3O8 Nanowire Cathode. Small. https://doi.org/10.1002/smll.201702551
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