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Ultrathin 2D Zirconium Metal–Organic Framework Nanosheets: Preparation and Application in Photocatalysis
Abstract
Synthesizing ultrathin 2D metal–organic framework nanosheets in high yields has received increasing research interest but remains a great challenge. In this work, ultrathin zirconium‐porphyrinic metal–organic framework (MOF) nanosheets with thickness down to ≈1.5 nm are synthesized through a pseudoassembly–disassembly strategy. Owing to the their unique properties originating from their ultrathin thickness and highly exposed active sites, the as‐prepared ultrathin nanosheets exhibit far superior photocatalysis performance compared to the corresponding bulk MOF. This work highlights new opportunities in designing ultrathin MOF nanosheets and paves the way to expand the potential applications of MOFs.
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Cited by
Two-dimensional metal–organic framework nanosheets: synthesis and applications
Zhao, M., Huang, Y., Peng, Y., Huang, Z., Ma, Q., & Zhang, H. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00268a · Cited by 1,348
Chakraborty, G., Park, I.-H., Medishetty, R., & Vittal, J. J. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01049 · Cited by 928
Dhakshinamoorthy, A., Asiri, A. M., & Garcia, H. (2019) · Advanced Materials · doi:10.1002/adma.201900617 · Cited by 462
Liu, W., Yin, R., Xu, X., Zhang, L., Shi, W., & Cao, X. (2019) · Advanced Science · doi:10.1002/advs.201802373 · Cited by 304
Huang, H., Feng, W., & Chen, Y. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01138j · Cited by 285
Metadata
- Authors
- He, T., Ni, B., Zhang, S., Gong, Y., Wang, H., Gu, L., Zhuang, J., Hu, W., & Wang, X.
- Venue
- Small
- Publisher
- Wiley
- Published
- 2018-03-13
- Volume
- 14
- Issue
- 16
- Pages
- e1703929-e1703929
- ISSN
- 1613-6810 (ISSN-L)
- 1613-6829
- OpenAlex
- W2794303694
- Cited by
- 231
- References
- 0
- FWCI
- 9.28
- Type
- journal article
- Language
- en
- Open access
- closed
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- He, T., Ni, B., Zhang, S., Gong, Y., Wang, H., Gu, L., Zhuang, J., Hu, W., & Wang, X. (2018). Ultrathin 2D Zirconium Metal–Organic Framework Nanosheets: Preparation and Application in Photocatalysis. Small. https://doi.org/10.1002/smll.201703929
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