The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
S‐Doped Carbon Nanospheres: An Efficient Electrocatalyst toward Artificial N2 Fixation to NH3
Abstract
Industrial NH 3 synthesis mainly relies on the carbon‐emitting Haber–Bosch process operating under severe conditions. Electrocatalytic N 2 to NH 3 fixation at ambient conditions is an attractive approach to reduce energy consumption and avoid direct carbon emission. In this communication, it is reported that the S‐doped carbon nanosphere (S‐CNS) acts as an efficient and stable nitrogen reduction reaction (NRR) catalyst for ambient N 2 to NH 3 conversion with excellent selectivity. In 0.1 m Na 2 SO 4, the S‐CNS achieves a large NH 3 yield of 19.07 μg h−1 mg−1cat. and a high Faradic efficiency of 7.47% at –0.7 V versus reversible hydrogen electrode, much higher than those of undoped CNS (3.70 μg h−1 mg−1cat., 1.45%). Notably, this catalyst also demonstrates high electrochemical and structure stability.
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Wang, H., Maiyalagan, T., & Wang, X. (2012) · ACS Catalysis · doi:10.1021/cs200652y · Cited by 3,618
Carbon-based electrocatalysts for advanced energy conversion and storage
Zhang, J., Xia, Z., & Dai, L. (2015) · Science Advances · doi:10.1126/sciadv.1500564 · Cited by 735
Energy efficiency improvements in ammonia production—perspectives and uncertainties
Rafiqul, I., Weber, C., Lehmann, B., & Voss, A. (2005) · Energy · doi:10.1016/j.energy.2004.12.004 · Cited by 439
Cited by
Can sustainable ammonia synthesis pathways compete with fossil-fuel based Haber–Bosch processes?
Wang, M., Khan, M. A., Mohsin, I., Wicks, J., Ip, A. H., Sumon, K. Z., Dinh, C.-T., Sargent, E. H., Gates, I. D., & Kibria, M. G. (2021) · Energy & Environmental Science · doi:10.1039/d0ee03808c · Cited by 518
Recent Progress in MXene‐Based Materials: Potential High‐Performance Electrocatalysts
Liu, A., Liang, X., Ren, X., Guan, W., Gao, M., Yang, Y., Yang, Q., Gao, L., Li, Y., & Ma, T. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202003437 · Cited by 386
Identification of FeN4 as an Efficient Active Site for Electrochemical N2 Reduction
He, C., Wu, Z.-Y., Zhao, L., Ming, M., Zhang, Y., Yi, Y., & Hu, J.-S. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b00959 · Cited by 287
Metadata
- Authors
- Xia, L., Wu, X., Wang, Y., Niu, Z., Liu, Q., Li, T., Shi, X., Asiri, A. M., & Sun, X.
- Venue
- Small Methods
- Publisher
- Wiley
- Published
- 2018-12-07
- Volume
- 3
- Issue
- 6
- ISSN
- 2366-9608 (ISSN-L)
- OpenAlex
- W2903909502
- Cited by
- 195
- References
- 3
- FWCI
- 8.06
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xia, L., Wu, X., Wang, Y., Niu, Z., Liu, Q., Li, T., Shi, X., Asiri, A. M., & Sun, X. (2019). S‐Doped Carbon Nanospheres: An Efficient Electrocatalyst toward Artificial N2 Fixation to NH3. Small Methods. https://doi.org/10.1002/smtd.201800251
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