Molecular model of drawing polyethylene and polypropylene
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On drawing, stacked lamella transition to micro-fibrils and eventually to chain-extended crystals.
“On drawing, Peterlin proposed a sequence of processes occur in which stacked lamella transition to micro-fibrils and eventually to chain-extended crystals35.”
From Origin of high thermal conductivity in disentangled ultra-high molecular weight polyethylene films: ballistic phonons within enlarged crystals (2022) · cites this paper as [35]
For 10 ≲ draw ratio ≲ 50, micro-fibrils aggregate with concurrent tautening of tie-molecules and marginal changes in crystallinity.
“Subsequently, for 10 ≲ DR ≲ 50 the micro-fibrils aggregate with concurrent tautening of the tie-molecules and marginal changes in the crystallinity.”
From Origin of high thermal conductivity in disentangled ultra-high molecular weight polyethylene films: ballistic phonons within enlarged crystals (2022) · cites this paper as [35]
For draw ratio > 50, chain extension leads to an extended crystal phase formed from aggregated micro-fibrils and tie-molecules.
“Finally, for DR > 50, chain extension leads to an extended crystal phase formed from the aggregated micro-fibrils and tie-molecules.”
From Origin of high thermal conductivity in disentangled ultra-high molecular weight polyethylene films: ballistic phonons within enlarged crystals (2022) · cites this paper as [35]
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“On drawing, Peterlin proposed a sequence of processes occur in which stacked lamella transition to micro-fibrils and eventually to chain-extended crystals [35].”
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- Authors
- Peterlin, A.
- Affiliations
- RTI International (US)
- Corresponding author
- Peterlin, A.
- ORCID
- Peterlin, A.
- Venue
- Journal of Materials Science
- Published
- 1971-06
- Volume
- 6
- Issue
- 6
- Pages
- 490-508
- ISSN
- 0022-2461 (ISSN-L)
- 1573-4803
- OpenAlex
- W1965831132
- Cited by
- 987
- References
- 0
- Citations by year
- 2026: 18 · 2025: 13 · 2024: 16 · 2023: 16 · 2022: 16 · 2021: 26 · 2020: 27 · 2019: 28 · 2018: 25 · 2017: 22 · 2016: 22 · 2015: 34 · 2014: 28 · 2013: 27 · 2012: 20
- FWCI
- 40.70
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- www.springer.com/tdm (tdm)
- Locations
- Journal of Materials Science (publishedVersion)
- Funders
- Camille and Henry Dreyfus Foundation
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Materials Chemistry › Microstructure and mechanical properties
- Physical Sciences › Chemical Engineering › Fluid Flow and Transfer Processes › Rheology and Fluid Dynamics Studies
- Keywords
- polyethylene, polypropylene, cold drawing, spherulites, fiber structure, microfibrils, draw ratio, molecular weight dependence, adiabatic heating, chain mobility, twinning, chain folding
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
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