Isotopic fractionation between gaseous and condensed carbon dioxide
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
The calculated fractionation factor 10^3 ln α for CO2(g)-CO2(l) at 0°C is -0.58.
“1 1 CO2(g)-CO2( 1 ) Continued | 0 | -0.42 | -0.58 | Grootes, Mook, and Vogel (1969).”
From Compilation of stable isotope fractionation factors of geochemical interest (1977) · cites this paper as Grootes, Mook, and Vogel (1969)
The measured fractionation factor 10^3 ln α for CO2(g)-CO2(l) at 20°C is -0.21.
“| | 20 | -.21 | | | |”
From Compilation of stable isotope fractionation factors of geochemical interest (1977) · cites this paper as Grootes, Mook, and Vogel (1969)
The measured fractionation factor 10^3 ln α for CO2(g)-CO2(l) at 30°C is -0.06.
“| | 30 | -.06 | | | |”
From Compilation of stable isotope fractionation factors of geochemical interest (1977) · cites this paper as Grootes, Mook, and Vogel (1969)
The measured fractionation factor 10^3 ln α for CO2(g)-CO2(l) at 0°C is -0.42.
“1 1 CO2(g)-CO2( 1 ) Continued | 0 | -0.42 | -0.58 | Grootes, Mook, and Vogel (1969).”
From Compilation of stable isotope fractionation factors of geochemical interest (1977) · cites this paper as Grootes, Mook, and Vogel (1969)
The measured fractionation factor 10^3 ln α for CO2(g)-CO2(l) at 10°C is -0.32.
“| | 10 | -.32 | | | |”
From Compilation of stable isotope fractionation factors of geochemical interest (1977) · cites this paper as Grootes, Mook, and Vogel (1969)
Cited by
Sorted by citations
Compilation of stable isotope fractionation factors of geochemical interest
Friedman, I., & O'Neil, J. R. (1977) · Professional Paper · doi:10.3133/pp440kk · Cited by 2,646 · see citing works
Isotopic studies of nitrogen pollution in the hydrosphere and atmosphere: A review
Heaton, T. H. E. (1986) · Chemical Geology Isotope Geoscience section · doi:10.1016/0168-9622(86)90059-x · Cited by 1,038 · see citing works
Normalization of measured stable isotopic compositions to isotope reference scales – a review
Paul, D., Skrzypek, G., & Fórizs, I. (2007) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.3185 · Cited by 536 · see citing works
Equilibrium Oxygen, Hydrogen and Carbon Isotope Fractionation Factors Applicable to Geologic Systems
Chacko, T., Cole, D. R., & Horita, J. (2001) · Reviews in Mineralogy and Geochemistry · doi:10.2138/gsrmg.43.1.1 · Cited by 462 · see citing works
Singer, K., Taylor, A., & Singer, J. V. L. (1977) · Molecular Physics · doi:10.1080/00268977700101451 · Cited by 360 · see citing works
Physical and chemical basis of carbon isotope fractionation in plants
O'Leary, M. H., Madhavan, S., & Paneth, P. (1992) · Plant Cell & Environment · doi:10.1111/j.1365-3040.1992.tb01660.x · Cited by 239 · see citing works
Carbon and chlorine isotope fractionation of chlorinated aliphatic hydrocarbons by evaporation
Huang, L., Sturchio, N. C., Abrajano, T. A., Heraty, L. J., & Holt, B. D. (1999) · Organic Geochemistry · doi:10.1016/s0146-6380(99)00060-1 · Cited by 142 · see citing works
Wang, Y., & Huang, Y. (2003) · Applied Geochemistry · doi:10.1016/s0883-2927(03)00076-3 · Cited by 78 · see citing works
Hydrogen isotope fractionation of low molecular weight n -alkanes during progressive vaporization
Wang, Y., & Huang, Y. (2001) · Organic Geochemistry · doi:10.1016/s0146-6380(01)00065-1 · Cited by 59 · see citing works
Deines, P., & Haggerty, S. E. (2000) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(99)00211-2 · Cited by 50 · see citing works
Li, J., Pu, J., & Zhang, T. (2021) · Water Research · doi:10.1016/j.watres.2021.117905 · Cited by 47 · see citing works
Solubilities of hydrogen and deuterium gases in water and their isotope fractionation factor
Muccitelli, J. A., & Wen, W.-Y. (1978) · Journal of Solution Chemistry · doi:10.1007/bf00644273 · Cited by 44 · see citing works
Equilibrium and kinetic nitrogen and oxygen isotope fractionations between dissolved and gaseous N2O
INOUE, H. Y., & Mook, W. G. (1994) · Chemical Geology · doi:10.1016/0009-2541(94)90009-4 · Cited by 39 · see citing works
Self-citationHigh accuracy CO2 Fourier transform measurements in the range 6000–7000 cm−1
Birk, M., Röske, C., & Wagner, G. (2021) · Journal of Quantitative Spectroscopy and Radiative Transfer · doi:10.1016/j.jqsrt.2021.107791 · Cited by 37 · see citing works
Holmstrand, H., Mandalakis, M., Zencak, Z., Gustafsson, Ö., & Andersson, P. (2005) · Journal of Chromatography A · doi:10.1016/j.chroma.2005.11.009 · Cited by 36 · see citing works
Gaseous, liquid, and supercritical fluid H2O and CO2: Oxygen isotope fractionation behavior
Rosenbaum, J. M. (1997) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(97)00362-1 · Cited by 35 · see citing works
Zimbelman, D. R., Rye, R. O., & Landis, G. P. (2000) · Journal of Volcanology and Geothermal Research · doi:10.1016/s0377-0273(99)00180-8 · Cited by 35 · see citing works
Oxygen isotope fractionation in the mantle
Rosenbaum, J. M., Walker, D., & Kyser, T. K. (1994) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(94)90207-0 · Cited by 32 · see citing works
Xiao, Q., Sun, Y., Zhang, Y., & Chai, P. (2012) · Organic Geochemistry · doi:10.1016/j.orggeochem.2012.06.003 · Cited by 31 · see citing works
The effect of N 2 O on the isotopic composition of air‐CO 2 samples
Ghosh, P., & Brand, W. A. (2004) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.1560 · Cited by 27 · see citing works
Carbon isotope fractionation of benzene and toluene by progressive evaporation
Shin, W., & Lee, K. (2010) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.4562 · Cited by 27 · see citing works
Eiler, J. M., Cartigny, P., Hofmann, A. E., & Piasecki, A. M. (2013) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2012.12.048 · Cited by 26 · see citing works
Rahn, T., & Eiler, J. (2001) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(00)00592-5 · Cited by 26 · see citing works
Tang, C., Tan, J., Xiong, S., Liu, J., Fan, Y., & Peng, X. (2017) · Journal of Chromatography A · doi:10.1016/j.chroma.2017.07.058 · Cited by 24 · see citing works
Kang, Z., Chen, J., Yuan, D., He, S., Li, Y., Chang, Y., Deng, Y., Yang, C., Liu, Y., Jiang, G., et al. (2020) · Journal of Hydrology · doi:10.1016/j.jhydrol.2020.125246 · Cited by 21 · see citing works
Eiler, J., Kitchen, N., & Rahn, T. (2000) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(99)00327-0 · Cited by 19 · see citing works
Bilkadi, Z., Lee, M. W., & Bigeleisen, J. (1975) · The Journal of Chemical Physics · doi:10.1063/1.430772 · Cited by 18 · see citing works
Raman spectroscopic measurement guidelines for carbon isotopic composition of CO2
Wang, W. Q., Cui, S., & Sun, Q. (2022) · Vibrational Spectroscopy · doi:10.1016/j.vibspec.2022.103449 · Cited by 17 · see citing works
Yato, Y., Lee, M. W., & Bigeleisen, J. (1975) · The Journal of Chemical Physics · doi:10.1063/1.431478 · Cited by 16 · see citing works
Room temperature oxygen isotope exchange between liquid CO2 and H2O
Rosenbaum, J. M. (1993) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(93)90303-e · Cited by 15 · see citing works
Carbon isotope fractionation between CO2 and carbon in silicate melts at high temperature
Lee, H., Moussallam, Y., Aubaud, C., Iacono–Marziano, G., Hammond, K. G., & EBEL, D. S. (2024) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2024.07.015 · Cited by 12 · see citing works
“This is explained by isotope fractionation rules (Grootes et al., 1969), which is the preference of the heavy isotope 13 C for lower coordination numbers and symmetric molecules, CO 2 .”
BackgroundNowak, M. E., van Geldern, R., Myrttinen, A., Zimmer, M., & Barth, J. A. C. (2014) · Applied Geochemistry · doi:10.1016/j.apgeochem.2014.05.009 · Cited by 9 · see citing works
Isotope enrichment in neon clusters grown in helium nanodroplets
Tiefenthaler, L., Kollotzek, S., Gatchell, M., Hansen, K., Scheier, P., & Echt, O. (2020) · The Journal of Chemical Physics · doi:10.1063/5.0028056 · Cited by 8 · see citing works
Viallon, J., Flores, E., Moussay, P., Chubchenko, I. K., Rolle, F., Zhang, T., Webber, E. M., & Wielgosz, R. I. (2020) · Metrologia · doi:10.1088/1681-7575/ab948c · Cited by 8 · see citing works
Li, Q., Wang, H., Jin, Z., Xiong, W., Wu, X., Zhang, Y., & Liu, C. (2015) · Environmental Earth Sciences · doi:10.1007/s12665-015-4553-x · Cited by 6 · see citing works
Effects of volatilization on the hydrogen isotope composition of selected n-alkanes
Bai, H., Peng, L., Cao, J., Liu, X., Zhang, J., & Mu, L. (2013) · Atmospheric Research · doi:10.1016/j.atmosres.2013.05.012 · Cited by 5 · see citing works
“Isotope fractionation during evaporation is driven by the molecular forces betweenmolecules rather than the breaking of chemical bonds within a molecule, and this phenomenon has been explained in terms of binding energies (Grootes et al., 1969) and molecular structure (Bradley, 1954).”
BackgroundHESSEL DE VRIES: RADIOCARBON PIONEER FROM GRONINGEN
Grootes, P. M., & van der Plicht, J. (2021) · Radiocarbon · doi:10.1017/rdc.2021.63 · Cited by 4 · see citing works
“P. M. (Piet) Grootes did a masters project on isotope fractionation with Wim starting fall 1964 (Grootes et al. 1969; Vogel et al. 1970).”
BackgroundSelf-citationAn isotopic mass effect on the intermolecular potential
Herman, M. F., Currier, R. P., & Clegg, S. M. (2015) · Chemical Physics Letters · doi:10.1016/j.cplett.2015.09.041 · Cited by 3 · see citing works
Effects of Isotopes on the Triple Points of Carbon Dioxide and Sulfur Hexafluoride
Yu, L., Zhang, J., & Feng, X. J. (2021) · International Journal of Thermophysics · doi:10.1007/s10765-021-02882-1 · Cited by 3 · see citing works
Carbon isotope fractionation between CO2 and carbon in silicate melts at high temperaturePreprint
Lee, H. J., Moussallam, Y., Aubaud, C., Iacono–Marziano, G., Hammond, K. G., & EBEL, D. S. (2024) · doi:10.31223/x5nh6r · Cited by 3 · see citing works
A test of the significance of intermolecular vibrational coupling in isotopic fractionation
Herman, M. F., Currier, R. P., Peery, T. B., & Clegg, S. M. (2017) · Chemical Physics · doi:10.1016/j.chemphys.2017.06.005 · Cited by 1 · see citing works
Socki, R. A., & Jacksier, T. (2021) · ACS Omega · doi:10.1021/acsomega.1c00474 · Cited by 1 · see citing works
Partitioning of oxygen isotopes during the aqueous solvation of nitric acid
Larson, T. E., Perkins, G., Williams, R. F., Fessenden, J. E., Clegg, S. M., & Currier, R. P. (2019) · Fluid Phase Equilibria · doi:10.1016/j.fluid.2019.112364
Referencing Strategies and Quality Assurance for Compound-specific Stable Isotope Analysis
(2012) · Royal Society of Chemistry eBooks · doi:10.1039/bk9781849731577-00185
Ge, Y., Luan, Z., Li, L., Xi, S., Du, Z., & Zhang, X. (2025) · Geoscience Frontiers · doi:10.1016/j.gsf.2025.102180
- Authors
- Grootes, P. M., Mook, W. G., & Vogel, J. C.
- Affiliations
- University of Groningen (NL)
- ORCID
- Grootes, P. M.
- Venue
- Zeitschrift für Physik A Hadrons and nuclei
- Published
- 1969-06
- Volume
- 221
- Issue
- 3
- Pages
- 257-273
- ISSN
- 0939-7922 (ISSN-L)
- OpenAlex
- W2025140676
- Cited by
- 45
- References
- 0
- Citations by year
- 2025: 1 · 2024: 2 · 2022: 1 · 2021: 5 · 2020: 3 · 2019: 1 · 2017: 2 · 2015: 2 · 2014: 1 · 2013: 2 · 2012: 2
- FWCI
- 0.00
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- www.springer.com/tdm (tdm)
- Locations
- Zeitschrift für Physik A Hadrons and Nuclei (publishedVersion)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Phase Equilibria and Thermodynamics
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Thermodynamics and Molecular Structure
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
- Keywords
- isotope fractionation, carbon dioxide, vapor-liquid equilibrium, carbon isotopes, oxygen isotopes, critical points, binding energy, hindered rotation, two-phase equilibria
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review