Turning an environmental problem into an opportunity: potential use of biochar derived from a harmful marine biomass named Cladophora glomerata as anode electrode for Li-ion batteries
Abstract
The electrochemical performance of lithium ion battery was enhanced by using biochar derived from Cladophora glomerata (C. glomerata) as widespread green macroalgae in most areas of the Iran's Caspian sea coast. By the utilization of the structure of the biochar, micro-/macro-ordered porous carbon with olive-shaped structure was successfully achieved through pyrolysis at 500 °C, which is the optimal temperature for biofuel production, and was activated with HCl. The biochar and HCl treatment biochar (HTB) were applied as anode electrode in lithium ion batteries. Then, electrochemical measurements were conducted on the electrodes via galvanostatic charge-discharge, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) analyses. The electrochemical results indicated a higher specific discharge capacity (700 mAh g-1) and good cycling stability for HTB at the current density of 0.1 A g-1 as compared to the biochar. The reason that HTB electrode works better than the biochar could be due to the higher surface area, formation functional groups, removal impurities, and formation some micropores after HCl treatment. The biochar derived from marine biomass and treatment process developed here could provide a promising path for the low-cost, renewable, and environmentally friendly electrode materials. Graphical abstract Algal-biochar into Li-ion Battery.
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Interconnected pores promote Li+ transfer, introduce heteroatoms, making biochar a good proxy to graphite.
“The interconnected pores promote Li + transfer, introduce heteroatoms, making biochar a good proxy to graphite (Chen et al. 2021b; Ryu et al. 2016; Salimi et al. 2017; Wang et al. 2022g).”
From Role of biochar toward carbon neutrality (2023) · cites this paper as Salimi et al. 2017
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- Authors
- Salimi, P., Javadian, S., Norouzi, O., & Gharibi, H.
- Affiliations
- Tarbiat Modares University (IR)
- University of Tehran (IR)
- Corresponding author
- Javadian, Soheila
- Venue
- Environmental Science and Pollution Research
- Published
- 2017-10-08
- Volume
- 24
- Issue
- 36
- Pages
- 27974-27984
- ISSN
- 0944-1344 (ISSN-L)
- 1614-7499
- OpenAlex
- W2764035731
- Cited by
- 78
- References
- 48
- Citations by year
- 2026: 12 · 2025: 11 · 2024: 7 · 2023: 5 · 2022: 11 · 2021: 7 · 2020: 11 · 2019: 8 · 2018: 5 · 2017: 1
- FWCI
- 2.84
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Environmental Science and Pollution Research (publishedVersion)
- PubMed (publishedVersion)
- Funders
- University of Tehran
- University of Science and Technology Liaoning
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
- Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
- Keywords
- biochar, Cladophora glomerata, seaweed, lithium-ion battery anodes, HCl activation, pyrolysis, porous carbon, discharge specific capacity, cycling stability, Caspian Sea, biomass waste valorization, green electrode materials
- MeSH terms
- Chlorophyta, Charcoal, Electrodes, Hot Temperature, Iran, Lithium, Oceans and Seas, Electric Power Supplies, Surface Properties, Porosity, Biomass
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