Relating physical and chemical properties of four different biochars and their application rate to biomass production of Lolium perenne on a Calcic Cambisol during a pot experiment of 79days
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Three pyrolysis biochars (B1: wood, B2: paper-sludge, B3: sewage-sludge) and one kiln-biochar (B4: grapevine wood) were characterized by determining different chemical and physical properties which were related to the germination rates and to the plant biomass production during a pot experiment of 79 days in which a Calcic Cambisol from SW Spain was amended with 10, 20 and 40 t ha(-1) of the four biochars. Biochar 1, B2 and B4 revealed comparable elemental composition, pH, water holding capacity and ash content. The H/C and O/C atomic ratios suggested high aromaticity of all biochars, which was confirmed by (13)C solid-state NMR spectroscopy. The FT-IR spectra confirmed the aromaticity of all the biochars as well as several specific differences in their composition. The FESEM-EDS distinguished compositional and structural differences of the studied biochars such as macropores on the surface of B1, collapsed structures in B2, high amount of mineral deposits (rich in Al, Si, Ca and Fe) and organic phases in B3 and vessel structures for B4. Biochar amendment improved germination rates and soil fertility (excepting for B4), and had no negative pH impact on the already alkaline soil. Application of B3, the richest in minerals and nitrogen, resulted in the highest soil fertility. In this case, increase of the dose went along with an enhancement of plant production. Considering costs due to production and transport of biochar, for all used chars with the exception of B3, the application of 10 t ha(-1) turned out as the most efficient for the crop and soil used in the present incubation experiment.
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Their concentrations increase with the pyrolysis temperature and vary with the type of biomass.
“Their concentrations increase with the pyrolysis temperature (Saletnik et al. 2016) and vary with the type of biomass (de la Rosa et al. 2014).”
From Biochar physicochemical properties: pyrolysis temperature and feedstock kind effects (2020) · cites this paper as de la Rosa et al. 2014
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“…2010; Moško et al., 2021; Wiedemeier et al., 2015; Wurster et al., 2013; Xiao et al., 2018) and how it affects its properties (Brewer et al., 2012; Chun et al., 2004; de la Rosa et al., 2014; Fan et al., 2020; Harvey et al., 2011; Singh, Cowie, et al., 2012; Sun et al., 2013; Wei et al., 2017).”
- Authors
- de la Rosa, J. M., Paneque, M., Miller, A. Z., & Knicker, H.
- Affiliations
- Consejo Superior de Investigaciones Científicas (ES)
- Venue
- Science of The Total Environment
- Publisher
- Elsevier BV
- Published
- 2014-11
- Volume
- 499
- Pages
- 175-184
- ISSN
- 0048-9697 (ISSN-L)
- OpenAlex
- W2011621093
- Cited by
- 162
- References
- 38
- Citations by year
- 2026: 6 · 2025: 13 · 2024: 13 · 2023: 17 · 2022: 19 · 2021: 16 · 2020: 19 · 2019: 14 · 2018: 13 · 2017: 11 · 2016: 15 · 2015: 6
- FWCI
- 15.04
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Licence
- Locations
- The Science of The Total Environment (publishedVersion)
- PubMed (publishedVersion)
- DIGITAL.CSIC (Spanish National Research Council (CSIC)) (submittedVersion, other-oa)
- Funders
- Marie Curie Actions of the European Union's Seventh Framework People Programme (PCIG12-GA-2012-333784)
- Spanish Ministry of Economy and Competitiveness (GCL2012-37041)
- European Regional Development Funds
- Topics
- Life Sciences › Agricultural and Biological Sciences › Soil Science › Soil Carbon and Nitrogen Dynamics
- Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
- Life Sciences › Agricultural and Biological Sciences › Soil Science › Agricultural Science and Fertilization
- Keywords
- biochar, biochar amendment, perennial ryegrass, soil fertility, seed germination, biochar physicochemical properties, sewage sludge biochar, soil pH
- MeSH terms
- Charcoal, Lolium, Oxides, Sewage, Soil, Soil Pollutants, Spain, Calcium Compounds, Biomass
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