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Recent Progresses in Electrocatalysts for Water Electrolysis
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Abstract The study of hydrogen evolution reaction and oxygen evolution reaction electrocatalysts for water electrolysis is a developing field in which noble metal-based materials are commonly used. However, the associated high cost and low abundance of noble metals limit their practical application. Non-noble metal catalysts, aside from being inexpensive, highly abundant and environmental friendly, can possess high electrical conductivity, good structural tunability and comparable electrocatalytic performances to state-of-the-art noble metals, particularly in alkaline media, making them desirable candidates to reduce or replace noble metals as promising electrocatalysts for water electrolysis. This article will review and provide an overview of the fundamental knowledge related to water electrolysis with a focus on the development and progress of non-noble metal-based electrocatalysts in alkaline, polymer exchange membrane and solid oxide electrolysis. A critical analysis of the various catalysts currently available is also provided with discussions on current challenges and future perspectives. In addition, to facilitate future research and development, several possible research directions to overcome these challenges are provided in this article. Graphical Abstract
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“The primary variables that impact the characteristics of electrocatalyst atom rearrangements include the influence of surface roughness, identification of catalytic center sites, phase transitions, and on the catalytic surface that occur during electrochemical processes [62,63].”
From Silica Aerogels as a Promising Vehicle for Effective Water Splitting for Hydrogen Production (2025) · cites this paper as [62]
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Metadata
- Authors
- Khan, M. A., Zhao, H., Zou, W., Chen, Z., Cao, W., Fang, J., Xu, J., Zhang, L., & Zhang, J.
- Affiliations
- Shanghai University (CN)
- Corresponding author
- Zhao, Hongbin
- Zhang, Jiujun
- Venue
- Electrochemical Energy Reviews
- Published
- 2018-07-28
- Volume
- 1
- Issue
- 4
- Pages
- 483-530
- ISSN
- 2520-8136 (ISSN-L)
- 2520-8489
- OpenAlex
- W2883757223
- Cited by
- 527
- References
- 372
- Citations by year
- 2026: 72 · 2025: 87 · 2024: 77 · 2023: 81 · 2022: 85 · 2021: 56 · 2020: 43 · 2019: 24 · 2018: 1
- FWCI
- 7.16
- Type
- journal article
- Language
- en
- Update notices
- correction (2019-05-17)
- Open access
- hybrid
- doi.org
- Locations
- Electrochemical Energy Reviews (publishedVersion, cc-by)
- INFM-OAR (INFN Catania) (submittedVersion, cc-by)
- Funders
- National Key Research and Development Program of China (2017YFB0102900)
- Shanghai Pujiang Program (17PJD016)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Keywords
- water electrolysis, electrocatalysts, hydrogen evolution reaction, oxygen evolution reaction, non-noble metal catalysts, noble metal replacement, alkaline water electrolysis, solid oxide electrolysis, hydrogen production
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