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Magnetic Fe2O3/biochar composite prepared in a molten salt medium for antibiotic removal in water
Open accessAbstract
The large-scale use of antibiotics is causing serious water pollution problems, and it is of great significance to develop new technologies to remove antibiotics from water. As an environmentally friendly and economical adsorption material, carbon derived from biomass is a low-cost and feasible material for removing antibiotics in sewage, but the current removal efficiencies are not high enough for large-scale practical application. In this study, poplar wood chips are used as raw material, and a magnetic biochar is prepared by co-pyrolysis of poplar wood chips and FeCl 3/CaCl 2 mixed molten salt. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), N 2-isothermal adsorption and desorption, X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM) techniques showed the successful synthesis of Fe 2 O 3/bioC composite. In-situ formed Fe 2 O 3 makes the biochar possess the characteristic of superparamagnetic, which is conducive to the recycling of biochar. Due to the etching effect of the molten salts, rough surface was formed on Fe 2 O 3/bioC, resulting in a maximum norfloxacin (NOR) adsorption ability up to 38.77 mg g−1 at pH 6.0. The NOR adsorption behavior on Fe 2 O 3/bioC followed the pseudo second order kinetic model and the equilibrium data was best fitted the Langmuir model. In addition, the adsorption process of NOR on Fe 2 O 3/bioC was thermodynamically spontaneous. The results show that this low-cost and reusable magnetic biochar has the potential for rapid and efficient removal of antibiotic from aqueous solution.
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Fe2O3 generated in-situ made magnetic poplar sawdust biochar superparamagnetic, which was beneficial to biochar recycling.
“Fe 2 O3 generated in-situ made biochar superparamagnetic, which was beneficial to biochar recycling.”
From Modified biochar: synthesis and mechanism for removal of environmental heavy metals (2022) · cites this paper as Liang et al. 2022
The low-cost and reusable Fe2O3/biochar had the potential for efficient and fast removal of antibiotics in water.
“The results showed that the low-cost and reusable Fe 2 O3/biochar had the potential for efficient and fast removal of antibiotics in water.”
From Modified biochar: synthesis and mechanism for removal of environmental heavy metals (2022) · cites this paper as Liang et al. 2022
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Metadata
- Authors
- Liang, H., Zhu, C., Ji, S., Kannan, P., & Chen, F.
- Affiliations
- China University of Mining and Technology (CN)
- Jiaxing University (CN)
- Corresponding author
- Ji, Shan
- Venue
- Biochar
- Published
- 2022-01-20
- Volume
- 4
- Issue
- 1
- ISSN
- 2524-7867 (ISSN-L)
- 2524-7972
- OpenAlex
- W4205718766
- Cited by
- 108
- References
- 58
- Citations by year
- 2026: 19 · 2025: 33 · 2024: 24 · 2023: 24 · 2022: 8
- FWCI
- 6.50
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Locations
- Biochar (publishedVersion, cc-by)
- Funders
- national natural science foundation of china (21908242)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Environmental Science › Environmental Engineering › Environmental remediation with nanomaterials
- Physical Sciences › Environmental Science › Pollution › Pharmaceutical and Antibiotic Environmental Impacts
- Keywords
- magnetic biochar, antibiotic removal, molten salt pyrolysis, poplar wood chips, superparamagnetism, adsorption kinetics, adsorption isotherms, adsorption thermodynamics, recyclable adsorbent, water pollution
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