13C/12C partitioning and kinetics of CO2 absorption by hydroxide buffer solutions
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Kinetic fractionation through aqueous carbonate speciation can become dominant and result in a δ13C depletion of -10 to -19‰ for hyper alkaline solutions.
“Specifically, kinetic fractionation through aqueous carbonate speciation (deprotonation of CO2(aq) to HCO3 -or CO 3 2) can become dominant and result in a 𝛿 ¹³C depletion of -10 to -19 ‰ for hyper alkaline solutions [46 -49].”
From Isotope chemistry to trace carbon mineralization in construction materials (2026) · cites this paper as [46]
The similarity between the CO2 flux measured at pH 10 by Usdowski and Hoefs (1986) and our growth rate estimates for samples precipitated at pH >10 suggests that Ca-carbonate floe precipitation and uptake of atmospheric CO2 are coupled.
“The similarity between this value at pH 10 and our growth rate estimates for samples precipitated at pH > 10 suggests that Ca-carbonate floe precipitation and uptake of atmospheric CO2 are coupled”
From Isotopic fractionation accompanying CO2 hydroxylation and carbonate precipitation from high pH waters at The Cedars, California, USA (2021) · cites this paper as Usdowski and Hoefs (1986)
For carbon isotopes, laboratory experiments suggest a KFF between -13.7 ±0.1‰ and -17.2 ±0.6‰.
“For carbon isotopes, laboratory experiments suggest a KFF between -13.7 ±0.1‰ and -17.2 ±0.6‰ (Table 7, Fig. 13a, Craig, 1953; Usdowski and Hoefs, 1986; Clark et al., 1992; Dietzel et al., 2009; Böttcher et al., 2018)”
From Isotopic fractionation accompanying CO2 hydroxylation and carbonate precipitation from high pH waters at The Cedars, California, USA (2021) · cites this paper as Usdowski and Hoefs, 1986
Cites
Craig, H. (1957) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(57)90024-8 · Cited by 4,170 · see citing works
On the Isotopic Chemistry of Carbonates and a Paleotemperature Scale
McCrea, J. M. (1950) · The Journal of Chemical Physics · doi:10.1063/1.1747785 · Cited by 3,742 · see citing works
The physical chemistry of electrolytic solutions
(1950) · Journal of the Franklin Institute · doi:10.1016/0016-0032(50)90436-4 · Cited by 3,034 · see citing works
The geochemistry of the stable carbon isotopes
Craig, H. (1953) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(53)90001-5 · Cited by 1,965 · see citing works
Carbon isotope fractionation between dissolved bicarbonate and gaseous carbon dioxide
Mook, W. G., Bommerson, J. C., & Staverman, W. H. (1974) · Earth and Planetary Science Letters · doi:10.1016/0012-821x(74)90078-8 · Cited by 1,659 · see citing works
Biogeochemistry of Stable Carbon Isotopes
Degens, E. T. (1969) · Springer eBooks · doi:10.1007/978-3-642-87734-6_14 · Cited by 708 · see citing works
Bottinga, Y. (1969) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(69)90092-1 · Cited by 679 · see citing works
Harned, H. S., & Davis, R. T. (1943) · Journal of the American Chemical Society · doi:10.1021/ja01250a059 · Cited by 611 · see citing works
Carbon 13 in Plants and the Relationships between Carbon 13 and Carbon 14 Variations in Nature
Craig, H. (1954) · The Journal of Geology · doi:10.1086/626141 · Cited by 429 · see citing works
Isotopic fractionation between gaseous and dissolved carbon dioxide
Vogel, J. C., Grootes, P. M., & Mook, W. G. (1970) · Zeitschrift für Physik A Hadrons and Nuclei · doi:10.1007/bf01394688 · Cited by 316 · see citing works
Die Fraktionierung der Kohlenstoffisotopen bei der Absorption von Kohlendioxyd
Baertschi, P. (1952) · Helvetica Chimica Acta · doi:10.1002/hlca.19520350345 · Cited by 42 · see citing works
Practical considerations on carbon isotope studies on soil carbon dioxide
Fritz, P., Mozeto, A. A., & Reardon, E. J. (1985) · Chemical Geology Isotope Geoscience section · doi:10.1016/0168-9622(85)90029-6 · Cited by 27 · see citing works
Usdowski, H.-E., Menschel, G., & Hoefs, J. (1982) · Zeitschrift für Physikalische Chemie · doi:10.1524/zpch.1982.130.1.013 · Cited by 6 · see citing works
Self-citation
Flagged first, then by citations
Cited by
Sorted by citations
Clark, I. D., Fontes, J., & Fritz, P. (1992) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(92)90328-g · Cited by 136 · see citing works
Kinetic enrichment of stable isotopes in cryogenic calcites
Clark, I. D., & Lauriol, B. M. (1992) · Chemical Geology · doi:10.1016/0009-2541(92)90157-z · Cited by 130 · see citing works
Washbourne, C.-L., Renforth, P., & Manning, D. A. C. (2012) · Science of The Total Environment · doi:10.1016/j.scitotenv.2012.05.037 · Cited by 129 · see citing works
Darling, W. G., BATH, A. H., Gibson, J. J., & Różański, K. (2006) · Developments in paleoenvironmental research · doi:10.1007/1-4020-2504-1_01 · Cited by 124 · see citing works
Renforth, P., Mayes, W. M., Jarvis, A. P., Burke, I. T., Manning, D. A. C., & Gruiz, K. (2012) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2012.01.046 · Cited by 115 · see citing works
Rapid Removal of Atmospheric CO2 by Urban Soils
Washbourne, C.-L., Lopez-Capel, E., Renforth, P., Ascough, P. L., & Manning, D. A. C. (2015) · Environmental Science & Technology · doi:10.1021/es505476d · Cited by 105 · see citing works
Subarctic Weathering of Mineral Wastes Provides a Sink for Atmospheric CO<sub>2</sub>
Wilson, S., Dipple, G. M., Power, I. M., Barker, S. L. L., Fallon, S. J., & Southam, G. (2011) · Environmental Science & Technology · doi:10.1021/es202112y · Cited by 92 · see citing works
Atmospheric CO2 Sequestration in Iron and Steel Slag: Consett, County Durham, United Kingdom
Mayes, W. M., Riley, A. L., Gomes, H. I., Brabham, P., Hamlyn, J., Pullin, H., & Renforth, P. (2018) · Environmental Science & Technology · doi:10.1021/acs.est.8b01883 · Cited by 89 · see citing works
Teranes, J. L., McKenzie, J. A., Lotter, A. F., & Sturm, M. (1999) · Limnology and Oceanography · doi:10.4319/lo.1999.44.2.0320 · Cited by 74 · see citing works
Teranes, J. L., McKenzie, J. A., Bernasconi, S. M., Lotter, A. F., & Sturm, M. (1999) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(99)00049-6 · Cited by 69 · see citing works
Bade, D. L., & Cole, J. J. (2006) · Journal of Geophysical Research Atmospheres · doi:10.1029/2004jc002684 · Cited by 65 · see citing works
Dietzel, M., Usdowski, E., & Hoefs, J. (1992) · Applied Geochemistry · doi:10.1016/0883-2927(92)90035-2 · Cited by 59 · see citing works
Self-citationCalcium carbonate scaling under alkaline conditions – Case studies and hydrochemical modelling
Rinder, T., Dietzel, M., & Leis, A. (2013) · Applied Geochemistry · doi:10.1016/j.apgeochem.2013.03.019 · Cited by 52 · see citing works
Kosednar-Legenstein, B., Dietzel, M., Leis, A., & Stingl, K. (2008) · Applied Geochemistry · doi:10.1016/j.apgeochem.2008.05.003 · Cited by 49 · see citing works
Schwarzenbach, E. M., Lang, S. Q., Früh‐Green, G. L., Lilley, M. D., Bernasconi, S. M., & Méhay, S. (2013) · Lithos · doi:10.1016/j.lithos.2013.07.009 · Cited by 47 · see citing works
Bishop, P. K. (1990) · Chemical Geology Isotope Geoscience section · doi:10.1016/0168-9622(90)90032-8 · Cited by 45 · see citing works
Fourcade, S., Trotignon, L., Boulvais, P., Técher, I., Élie, M., Vandamme, D., Salameh, E., & Khoury, H. N. (2007) · Applied Geochemistry · doi:10.1016/j.apgeochem.2007.02.012 · Cited by 39 · see citing works
Zwicker, J., Birgel, D., Bach, W., Richoz, S., Smrzka, D., Grasemann, B., Gier, S., Schleper, C., Rittmann, S. K. ‐. R., Koşun, E., et al. (2018) · Chemical Geology · doi:10.1016/j.chemgeo.2018.03.027 · Cited by 36 · see citing works
Kinetic and effects upon dissolution and outgassing of CO2 in the system CO2H2O
Usdowski, E., & Hoefs, J. (1990) · Chemical Geology Isotope Geoscience section · doi:10.1016/0168-9622(90)90019-9 · Cited by 35 · see citing works
Self-citationCarbon Dioxide Emissions from Exhumed Petrocalcic Horizons
Serna‐Pérez, A., Monger, H. C., Herrick, J. E., & Murray, L. W. (2006) · Soil Science Society of America Journal · doi:10.2136/sssaj2005.0099 · Cited by 29 · see citing works
Christensen, J. N., Watkins, J. M., Devriendt, L. S., DePaolo, D. J., Conrad, M. E., Voltolini, M., Yang, W., & Dong, W. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2021.01.003 · Cited by 28 · see citing works
Böttcher, M. E., Neubert, N., Escher, P., von Allmen, K., Samankassou, E., & Nägler, T. F. (2018) · Geochemistry · doi:10.1016/j.chemer.2018.01.001 · Cited by 28 · see citing works
Changes of 14C Concentration in Modern Trees from Upper Silesia Region, Poland
Rakowski, A. Z., Pawełczyk, S., & Pazdur, A. (2001) · Radiocarbon · doi:10.1017/s0033822200041333 · Cited by 24 · see citing works
Létolle, R., Gégout, P., Moranville‐Regourd, M., & Gaveau, B. (1990) · Journal of the American Ceramic Society · doi:10.1111/j.1151-2916.1990.tb04267.x · Cited by 18 · see citing works
Andrews, J. E., Stamatakis, M. G., Mitsis, I., Donnelly, T., González-Barros, M. R., & Fallick, A. E. (2017) · Journal of the Geological Society · doi:10.1144/jgs2017-083 · Cited by 9 · see citing works
13C/12C fractionation during the chemical absorption of C02 gas by the NH3—NH4Cl buffer
Usdowski, E., & Hoefs, J. (1988) · Chemical Geology Isotope Geoscience section · doi:10.1016/0168-9622(88)90022-x · Cited by 6 · see citing works
Self-citation13C/12C‐ und 18O16O‐Signaturen von Calcit‐Abscheidungen in Drainagesystemen
Dietzel, M. (1995) · Acta hydrochimica et hydrobiologica · doi:10.1002/aheh.19950230406 · Cited by 6 · see citing works
Kinetic Oxygen Isotope Fractionation between Water and Aqueous OH– during Hydroxylation of CO2
Bajnai, D., & Herwartz, D. (2021) · ACS Earth and Space Chemistry · doi:10.1021/acsearthspacechem.1c00194 · Cited by 5 · see citing works
Ali, A., Abbasi, İ. A., Nogueira, L. B., Hersi, O. S., Kindi, S. A. N. A., El‐Ghali, M. A. K., & Nasir, S. J. (2021) · Journal of Geophysical Research Solid Earth · doi:10.1029/2020jb021290 · Cited by 5 · see citing works
Holdsworth, C., MacDonald, J., & John, C. M. (2022) · Minerals · doi:10.3390/min12121611 · Cited by 5 · see citing works
Heller, G. (1993) · Springer eBooks · doi:10.1007/978-3-662-06150-3_1 · Cited by 2 · see citing works
Zavadlav, S., Mazej, D., Zavašnik, J., Rečnik, A., Domínguez‐Villar, D., Cukrov, N., & Lojen, S. (2012) · Isotopes in Environmental and Health Studies · doi:10.1080/10256016.2012.645540 · Cited by 1 · see citing works
Isotope chemistry to trace carbon mineralization in construction materials
Jansen, D., Matschei, T., Van Geldern, R., Barth, J., & Snellings, R. (2026) · RILEM Technical Letters · doi:10.21809/rilemtechlett.2026.232
Mechanism of anomalous manifestations δ13C CO2 underground water on Tashkent geodynamic range
Yusupov, S. A., & Shin, L. Y. (2021) · IOP Conference Series Earth and Environmental Science · doi:10.1088/1755-1315/929/1/012034
- Authors
- Usdowski, E., & Hoefs, J.
- Affiliations
- University of Göttingen (DE)
- Venue
- Earth and Planetary Science Letters
- Publisher
- Elsevier BV
- Published
- 1986-10
- Volume
- 80
- Issue
- 1-2
- Pages
- 130-134
- ISSN
- 0012-821X (ISSN-L)
- OpenAlex
- W1993539623
- Cited by
- 35
- References
- 13
- Citations by year
- 2026: 1 · 2022: 1 · 2021: 4 · 2018: 3 · 2017: 1 · 2015: 1 · 2013: 2 · 2012: 3
- FWCI
- 0.54
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Earth and Planetary Science Letters (publishedVersion)
- Funders
- Deutsche Forschungsgemeinschaft
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Physical Sciences › Environmental Science › Global and Planetary Change › Atmospheric and Environmental Gas Dynamics
- Keywords
- CO2 absorption kinetics, stable carbon isotopes, borate buffer, barium hydroxide, barium carbonate precipitation, dissolved carbonate, CO2 diffusion, sample concentration
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