Rate constant for reaction of hydroxyl radicals with bicarbonate ions
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
OH· and SO4·- react with both CO3 2- and HCO3- to form CO3·- as the major species.
“Thus, the OH ● and SO4 ● -react with both CO3 2 -and HCO3 to form CO3 ●-as the major species.”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [51]
The major reactive species are OH· in conventional AOPs and SO4·- in persulfate-based AOPs.
“The major reactive species are OH ● in conventional AOPs and SO4 ●-in persulfate (PS)based AOPs.”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [51]
The reaction kinetics of OH· and SO4·- towards HCO3- are similar, but the rate constant for CO3 2- with OH· is 10^2 times higher than that with SO4·-.
“Even though the reaction kinetics for the reaction of OH ● and SO4 ● -towards HCO3 -are similar, that for CO3 2 -with OH ● is 10 2 times higher than that with SO4 ● -.”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [51]
SO4·- reacts with carbonate and bicarbonate ions with bimolecular rate constants of 6.1 × 10^6 M^-1 s^-1 and 1.6 × 10^6 M^-1 s^-1, respectively.
“The SO4 ●-reacts with carbonate and bicarbonate ions with a bimolecular rate constant of 6.1 × 10 6 M -1 s -1 and 1.6 × 10 6 M -1 s -1 , respectively (Equations (1)-(5)) [51-53].”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [51]
The carbonate radical can be formed in vivo by the reaction of the hydroxyl radical with carbonate or bicarbonate or via the reaction of peroxynitrite with carbon dioxide.
“The carbonate radical can be formed in vivo by the reaction of the hydroxyl radical with carbonate or bicarbonate (138) or via the reaction of peroxynitrite with carbon dioxide (Eq. 30) (112, 608, 640).”
From Sources of Vascular Nitric Oxide and Reactive Oxygen Species and Their Regulation (2019) · cites this paper as [138]
Cites
Aquatic Chemistry. An Introduction Emphasizing Chemical Equilibria in Natural Waters.
Golterman, H. L., Stumm, W., & Morgan, J. J. (1982) · Journal of Ecology · doi:10.2307/2260132 · Cited by 2,182 · see citing works
Aquatic Chemistry. An Introduction Emphasizing Chemical Equilibria in Natural Waters
(1982) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(82)85120-6 · Cited by 965 · see citing works
Harned, H. S., & Davis, R. T. (1943) · Journal of the American Chemical Society · doi:10.1021/ja01250a059 · Cited by 611 · see citing works
Anbar, M., Univ., I. R. L. N. D., Bambenek, M., & Ross, A. B. (1973) · doi:10.2172/4445489 · Cited by 349 · see citing works
The Ionization Constant of HCO3- from 0 to 50°
Harned, H. S., & Scholes, S. R. (1941) · Journal of the American Chemical Society · doi:10.1021/ja01851a058 · Cited by 340 · see citing works
Selected specific rates of reactions of transients from water in aqueous solution. :
Ross, F., & Ross, A. B. (1977) · doi:10.6028/nbs.nsrds.59 · Cited by 300 · see citing works
Schüler, R. H., Hartzell, A. L., & Behar, B. (1981) · The Journal of Physical Chemistry · doi:10.1021/j150602a017 · Cited by 231 · see citing works
Weeks, J. L., & Rabani, J. (1966) · The Journal of Physical Chemistry · doi:10.1021/j100879a005 · Cited by 223 · see citing works
Carbonate radical in flash photolysis and pulse radiolysis of aqueous carbonate solutions
Béhar, D., Czapski, G., & Duchovny, I. (1970) · The Journal of Physical Chemistry · doi:10.1021/j100909a029 · Cited by 211 · see citing works
Chen, S., Cope, V. W., & Hoffman, M. Z. (1973) · The Journal of Physical Chemistry · doi:10.1021/j100628a006 · Cited by 135 · see citing works
Ross, F., & Ross, A. B. (1977) · doi:10.2172/6635906 · Cited by 95 · see citing works
Buxton, G. V. (1969) · Transactions of the Faraday Society · doi:10.1039/tf9696502150 · Cited by 50 · see citing works
Self-citationThe radiation chemistry of aqueous solutions of sodium nitroprusside
Buxton, G. V., Dainton, F. S., & Kaleciński, J. (1969) · International Journal for Radiation Physics and Chemistry · doi:10.1016/0020-7055(69)90040-0 · Cited by 30 · see citing works
Self-citationOxidation of Some Transition-Metal Cyanide Compounds by Hydroxyl Radical
Waltz, W. L., Akhtar, S. S., & Eager, R. L. (1973) · Canadian Journal of Chemistry · doi:10.1139/v73-380 · Cited by 21 · see citing works
THE REACTIONS OF HYDROXYL RADICAL WITH SOME TRANSITION‐METAL COMPOUNDS CONTAINING ORGANIC MOLECULES
Waltz, W. L., Woods, R. J., & Whitburn, K. D. (1978) · Photochemistry and Photobiology · doi:10.1111/j.1751-1097.1978.tb06997.x · Cited by 9 · see citing works
A pulse radiolysis study of the reactions of platinum(II) glycine complexes in aqueous media
Waltz, W. L., Brodovitch, J., & Kundu, K. P. (1977) · Radiation Physics and Chemistry (1977) · doi:10.1016/0146-5724(77)90013-9 · Cited by 5 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Sources of Vascular Nitric Oxide and Reactive Oxygen Species and Their Regulation
Tejero, J., Shiva, S., & Gladwin, M. T. (2019) · Physiological Reviews · doi:10.1152/physrev.00036.2017 · Cited by 541 · see citing works
Bicarbonate-activated persulfate oxidation of acetaminophen
Jiang, M., Lu, J., Ji, Y., & Kong, D. (2017) · Water Research · doi:10.1016/j.watres.2017.03.043 · Cited by 259 · see citing works
Zhou, Y., Chen, C., Guo, K., Wu, Z., Wang, L., Hua, Z., & Fang, J. (2020) · Water Research · doi:10.1016/j.watres.2020.116231 · Cited by 228 · see citing works
Rayaroth, M. P., Boczkaj, G., Aubry, O., Aravind, U. K., & Aravindakumar, C. T. (2023) · Water · doi:10.3390/w15081615 · Cited by 171 · see citing works
“…in co-existing if they have a similar or higher bimolecular rate constant with the reactive species [ The The SO 4 ● − reacts with carbonate and bicarbonate ions with a bimolecular rate constant of 6.1 × 10 6 M − 1 s − 1 and 1.6 × 10 6 M − 1 s − 1 , respectively (Equations (1)–(5)) [51–53].”
InfluentialEnhanced sonochemical degradation of bisphenol-A by bicarbonate ions
Pétrier, C., Torres-Palma, R., Combet, E., Sarantakos, G., Baup, S., & Pulgarin, C. (2010) · Ultrasonics Sonochemistry · doi:10.1016/j.ultsonch.2009.05.010 · Cited by 144 · see citing works
Kanigaridou, Y., Petala, A., Frontistis, Z., Antonopoulou, M., Solakidou, M., Konstantinou, I., Deligiannakis, Y., Mantzavinos, D., & Kondarides, D. I. (2017) · Chemical Engineering Journal · doi:10.1016/j.cej.2016.04.145 · Cited by 136 · see citing works
- Authors
- Buxton, G. V., & Elliot, A. J.
- Affiliations
- Atomic Energy (Canada) (CA)
- Venue
- International Journal of Radiation Applications and Instrumentation. Part C. Radiation Physics and Chemistry
- Publisher
- Elsevier BV
- Published
- 1986-01
- Volume
- 27
- Issue
- 3
- Pages
- 241-243
- ISSN
- 1359-0197 (ISSN-L)
- OpenAlex
- W2077639808
- Cited by
- 182
- References
- 16
- Citations by year
- 2026: 9 · 2025: 14 · 2024: 15 · 2023: 14 · 2022: 16 · 2021: 16 · 2020: 13 · 2019: 9 · 2018: 10 · 2017: 9 · 2016: 6 · 2015: 3 · 2014: 5 · 2013: 4 · 2012: 11
- FWCI
- 2.33
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- International Journal of Radiation Applications and Instrumentation Part C Radiation Physics and Chemistry (publishedVersion)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Physical Sciences › Chemistry › Organic Chemistry › Free Radicals and Antioxidants
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric chemistry and aerosols
- Keywords
- hydroxyl radicals, bicarbonate ions, rate constants, pulsed electron irradiation, carbonate ions, pH dependence, reaction kinetics
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
