Single step in-syringe system for ionic liquid based liquid microextraction combined with flame atomic absorption spectrometry for lead determination
Abstract
A simple, novel and quick single step in-syringe system for ionic liquid based liquid microextraction (SSLME) has been presented in this paper. The objective of this study is to present a novel extraction alternative which avoids the centrifugation step, thermal dispersion and usage of hazardous organic solvents. In this procedure, the hydrophobic Pb–dithizone complex was extracted into the fine droplets of 1-butyl-3-methylimidazolium hexafluorophosphate [C4mim][PF6] within a syringe including Triton X-114 (TX-114) as dispersant. Several variables including pH of sample, [C4mim][PF6] volume, TX-114 volume, ligand concentration, incubation time and diluents nature were considered to be studied. At optimum experimental values of significant variables, detection limit and the enhancement factor were observed to be 0.281 μg L−1 and 82.6, respectively. The repeatability of the proposed method expressed as RSD (n = 5) was 3.51%. The validity of the developed method was checked out by Pb determination in certified reference material (TMDA-54.4 fortified lake water) and the results were found in good agreement with the certified values. The method was applied satisfactorily for the preconcentration of Pb in real samples.
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The LOD of 0.008 μg L−1 for the developed DES-ME was between those of other microextraction methods.
“The limits of detection of 0.008 µg L−1 for the developed DES-ME were between those of the other methods, as shown in Table 5.”
From Deep Eutectic Solvent-Based Microextraction of Lead(II) Traces from Water and Aqueous Extracts before FAAS Measurements (2020) · cites this paper as [33]
Cites
Determination of organic compounds in water using dispersive liquid–liquid microextraction
Rezaee, M., Assadi, Y., Milani Hosseini, M.-R., Aghaee, E., Ahmadi, F., & Berijani, S. (2006) · Journal of Chromatography A · doi:10.1016/j.chroma.2006.03.007 · Cited by 3,402 · see citing works
Solvent Microextraction into a Single Drop
Jeannot, M. A., & Cantwell, F. F. (1996) · Analytical Chemistry · doi:10.1021/ac960042z · Cited by 1,282 · see citing works
Analytical Chemistry in a Drop. Solvent Extraction in a Microdrop
Liu, H., & Dasgupta, P. Κ. (1996) · Analytical Chemistry · doi:10.1021/ac960145h · Cited by 751 · see citing works
Ionic liquids in analytical chemistry
Sun, P., & Armstrong, D. W. (2010) · Analytica Chimica Acta · doi:10.1016/j.aca.2009.12.007 · Cited by 727 · see citing works
Solvent extraction of strontium nitrate by a crown ether using room-temperature ionic liquids †
Dai, S., Ju, Y., & Barnes, C. E. (1999) · Journal of the Chemical Society Dalton Transactions · doi:10.1039/a809672d · Cited by 710 · see citing works
He, Y., & Lee, H. K. (1997) · Analytical Chemistry · doi:10.1021/ac970242q · Cited by 682 · see citing works
Extraction of organic compounds with room temperature ionic liquids
Poole, C. F., & Poole, S. K. (2010) · Journal of Chromatography A · doi:10.1016/j.chroma.2009.09.011 · Cited by 493 · see citing works
Luo, H., Dai, S., Bonnesen, P. V., Buchanan, A. C., Holbrey, J. D., Bridges, N. J., & Rogers, R. D. (2004) · Analytical Chemistry · doi:10.1021/ac049949k · Cited by 256 · see citing works
Biosorption of Pb(II) and Ni(II) from aqueous solution by lichen (Cladonia furcata) biomass
Sarı, A., Tüzen, M., Uluözlü, Ö. D., & Soylak, M. (2007) · Biochemical Engineering Journal · doi:10.1016/j.bej.2007.04.007 · Cited by 244 · see citing works
Self-citationEvaluation of status of toxic metals in biological samples of diabetes mellitus patients
Afridi, H. I., Kazi, T. G., Kazi, N. G., Jamali, M. K., Arain, M. B., Jalbani, N. B., Baig, J. A., & Sarfraz, R. A. (2008) · Diabetes Research and Clinical Practice · doi:10.1016/j.diabres.2007.12.021 · Cited by 193 · see citing works
Self-citationCheng, Y., Schwartz, J. D., Sparrow, D., Aro, A., Weiss, S. T., & Hu, H. (2001) · American Journal of Epidemiology · doi:10.1093/aje/153.2.164 · Cited by 187 · see citing works
Effect of added ionic liquid on aqueous Triton X-100 micelles
Behera, K., Dahiya, P., & Pandey, S. (2006) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2006.11.009 · Cited by 175 · see citing works
On the Extraction of Aromatic Compounds from Hydrocarbons by Imidazolium Ionic Liquids
Cassol, C. C., Umpierre, A. P., Ebeling, G., Ferrera, B. C., Chiaro, S. S. X., & Dupont, J. (2007) · International Journal of Molecular Sciences · doi:10.3390/i8070593 · Cited by 156 · see citing works
One-step in-syringe ionic liquid-based dispersive liquid–liquid microextraction
Cruz-Vera, M., Lucena, R., Cárdenas, S., & Valcárcel, M. (2009) · Journal of Chromatography A · doi:10.1016/j.chroma.2009.07.040 · Cited by 154 · see citing works
Are free radicals involved in lead poisoning?
Hermes‐Lima, M., Pereira, B., & Bechara, E. J. H. (1991) · Xenobiotica · doi:10.3109/00498259109039548 · Cited by 154 · see citing works
Direct Coupling of Ionic Liquid Based Single-Drop Microextraction and GC/MS
Aguilera-Herrador, E., Lucena, R., Cárdenas, S., & Valcárcel, M. (2008) · Analytical Chemistry · doi:10.1021/ac071555g · Cited by 144 · see citing works
Soylak, M., & Yılmaz, E. (2011) · Desalination · doi:10.1016/j.desal.2011.03.008 · Cited by 137 · see citing works
Self-citationSchwartz, B. S., Lee, B. K., Lee, G.-S., Stewart, W. F., Lee, S. S., Hwang, K. Y., Ahn, K. D., Kim, Y.-B., Bolla, K. I., Simon, D., et al. (2001) · American Journal of Epidemiology · doi:10.1093/aje/153.5.453 · Cited by 106 · see citing works
Shah, F., Kazi, T. G., Afridi, H. I., Baig, J. A., Khan, S., Kolachi, N. F., Wadhwa, S. K., & Shah, A. Q. (2010) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2010.07.091 · Cited by 99 · see citing works
Self-citationShah, F., Kazi, T. G., Naeemullah, Afridi, H. I., & Soylak, M. (2011) · Microchemical Journal · doi:10.1016/j.microc.2011.09.009 · Cited by 90 · see citing works
Self-citationShah, F., Kazi, T. G., Afridi, H. I., Kazi, N. G., Baig, J. A., Shah, A. Q., Khan, S., Kolachi, N. F., & Wadhwa, S. K. (2010) · Biological Trace Element Research · doi:10.1007/s12011-010-8736-8 · Cited by 80 · see citing works
Self-citationDisruption of the zinc finger domain: a common target that underlies many of the effects of lead.
Zawia, N. H., Crumpton, T. L., Brydie, M., Reddy, G. R., & Razmiafshari, M. (2000) · PubMed · Cited by 77 · see citing works
Martinis, E. M., & Wuilloud, R. G. (2010) · Journal of Analytical Atomic Spectrometry · doi:10.1039/c004678g · Cited by 73 · see citing works
Soylak, M., Elçı, L., & Doğan, M. (1993) · Analytical Letters · doi:10.1080/00032719308017446 · Cited by 71 · see citing works
Self-citationShah, F., Kazi, T. G., Afridi, H. I., Naeemullah, Arain, M. B., & Baig, J. A. (2011) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2011.06.017 · Cited by 69 · see citing works
Self-citationZhao, F., Li, J., & Zeng, B. (2008) · Journal of Separation Science · doi:10.1002/jssc.200800308 · Cited by 66 · see citing works
Preliminary synchrotron analysis of lead in hair from a lead smelter worker
Martin, R. R., Kempson, I. M., Naftel, S. J., & Skinner, W. M. (2004) · Chemosphere · doi:10.1016/j.chemosphere.2004.09.087 · Cited by 55 · see citing works
Monasterio, R. P., & Wuilloud, R. G. (2010) · Journal of Analytical Atomic Spectrometry · doi:10.1039/c000040j · Cited by 48 · see citing works
The influence of environmental exposure on lead concentrations in scalp hair of children in Pakistan
Shah, F., Kazi, T. G., Afridi, H. I., Khan, S., Kolachi, N. F., Arain, M. B., & Baig, J. A. (2010) · Ecotoxicology and Environmental Safety · doi:10.1016/j.ecoenv.2010.10.036 · Cited by 37 · see citing works
Self-citationStereochemical effects on the mode of facilitated ion transfer into room-temperature ionic liquids
Dietz, M. L., Jakab, S., Yamato, K., & Bartsch, R. A. (2007) · Green Chemistry · doi:10.1039/b713750h · Cited by 33 · see citing works
Zeng, C., Zhou, N., & Luo, J. (2011) · Journal of Analytical Atomic Spectrometry · doi:10.1039/c1ja10262a · Cited by 26 · see citing works
Tokalıoğlu, Ş., & Yıldız, S. (2008) · Microchimica Acta · doi:10.1007/s00604-008-0110-6 · Cited by 15 · see citing works
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Sorted by citations
Pirouz, M. J., Beyki, M. H., & Shemirani, F. (2014) · Food Chemistry · doi:10.1016/j.foodchem.2014.08.046 · Cited by 105 · see citing works
Ten years of dispersive liquid–liquid microextraction and derived techniques
Campillo, N., Viñas, P., Šandrejová, J., & Andruch, V. (2017) · Applied Spectroscopy Reviews · doi:10.1080/05704928.2016.1224240 · Cited by 102 · see citing works
Ionic liquid-based microextraction techniques for trace-element analysis
Martinis, E. M., Bertón, P., & Wuilloud, R. G. (2014) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2014.04.012 · Cited by 68 · see citing works
In-syringe dispersive liquid-liquid microextraction
Lemos, V. A., Barreto, J. A., Santos, L. B., de Assis, R. D. S., Novaes, C. G., & Cassella, R. J. (2021) · Talanta · doi:10.1016/j.talanta.2021.123002 · Cited by 43 · see citing works
Barreto, J. A., de Assis, R. D. S., Cassella, R. J., & Lemos, V. A. (2018) · Talanta · doi:10.1016/j.talanta.2018.09.082 · Cited by 42 · see citing works
ALOthman, Z. A., Yılmaz, E., Habila, M. A., Shabaka, A., & Soylak, M. (2013) · Microchimica Acta · doi:10.1007/s00604-013-0979-6 · Cited by 40 · see citing works
Self-citationHabila, M. A., AlMasoud, N., Alomar, T. S., AlOthman, Z. A., Yilmaz, E., & Soylak, M. (2020) · Molecules · doi:10.3390/molecules25204794 · Cited by 38 · see citing works
“[33] developed an in-syringe system using ionic liquid for microextraction of Pb(II) with an LOD of 0.”
BackgroundResultSelf-citationAsadollahi, T., Dadfarnia, S., Shabani, A. M. H., & Amirkavei, M. (2013) · Journal of Food Science and Technology · doi:10.1007/s13197-013-1077-9 · Cited by 35 · see citing works
Shah, F., Soylak, M., Kazi, T. G., & Afridi, H. I. (2013) · Journal of Analytical Atomic Spectrometry · doi:10.1039/c3ja30387j · Cited by 33 · see citing works
Self-citationNaeemullah, N., Tüzen, M., & Kazi, T. G. (2016) · RSC Advances · doi:10.1039/c6ra04588j · Cited by 33 · see citing works
Self-citationNaeemullah, N., Shah, F., Kazi, T. G., Afridi, H. I., Khan, A. R., Arain, S. S., Arain, M. S., & Panhwar, A. H. (2015) · Analytical Methods · doi:10.1039/c5ay02882e · Cited by 32 · see citing works
Self-citationPourshamsi, T., Amri, F., & Abniki, M. (2020) · Journal of the Iranian Chemical Society · doi:10.1007/s13738-020-02025-7 · Cited by 31 · see citing works
Khan, S., Kazi, T. G., & Soylak, M. (2015) · Journal of Industrial and Engineering Chemistry · doi:10.1016/j.jiec.2014.12.028 · Cited by 28 · see citing works
Self-citationNizamani, S., Kazi, T. G., & Afridi, H. I. (2017) · Ultrasonics Sonochemistry · doi:10.1016/j.ultsonch.2017.07.024 · Cited by 26 · see citing works
Self-citationEffect of phase transformation on physical and biological properties of PVA/CaFe2O4 nanocomposite
Naseri, M., Naderi, E., & Sadrolhosseini, A. R. (2016) · Fibers and Polymers · doi:10.1007/s12221-016-6030-x · Cited by 25 · see citing works
Memon, Z. M., Yılmaz, E., & Soylak, M. (2017) · Journal of the Iranian Chemical Society · doi:10.1007/s13738-017-1187-9 · Cited by 25 · see citing works
Self-citationLiang, P., Yang, E., Juan, Y., & Wen, L. (2014) · Analytical Methods · doi:10.1039/c4ay00019f · Cited by 25 · see citing works
Wen, S., & Zhu, X. (2013) · Food Analytical Methods · doi:10.1007/s12161-013-9626-4 · Cited by 22 · see citing works
Shah, F., Kazi, T. G., Ullah, N., & Afridi, H. I. (2013) · Biological Trace Element Research · doi:10.1007/s12011-013-9677-9 · Cited by 21 · see citing works
Self-citationStanisz, E., Zgoła‐Grześkowiak, A., & Matusiewicz, H. (2014) · Talanta · doi:10.1016/j.talanta.2014.05.048 · Cited by 20 · see citing works
Lum, J. T.-S., Tsoi, Y., & Leung, K. S. (2013) · Journal of Analytical Atomic Spectrometry · doi:10.1039/c3ja50316j · Cited by 19 · see citing works
Bilal, M., Kazi, T. G., Afridi, H. I., Ali, J., Baig, J. A., Arain, M. B., & Khan, M. (2017) · Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · doi:10.1016/j.saa.2017.04.037 · Cited by 19 · see citing works
Self-citationErulaş, F. A., Şaylan, M., Topal, S., Zaman, B. T., Bakırdere, E. G., & Bakırdere, S. (2020) · Journal of Food Composition and Analysis · doi:10.1016/j.jfca.2020.103623 · Cited by 17 · see citing works
Ullah, N., & Tüzen, M. (2022) · Critical Reviews in Analytical Chemistry · doi:10.1080/10408347.2022.2128635 · Cited by 16 · see citing works
Shah, F., Muhammad, H., Naeemullah, & Ullah, A. (2016) · Talanta · doi:10.1016/j.talanta.2016.03.070 · Cited by 15 · see citing works
Self-citationLashari, A. A., Kazi, T. G., Baig, J. A., & Afridi, H. I. (2020) · Environmental Progress & Sustainable Energy · doi:10.1002/ep.13439 · Cited by 15 · see citing works
Self-citationArain, M. S., Kazi, T. G., Afridi, H. I., Khan, N., & Ali, J. (2017) · Applied Organometallic Chemistry · doi:10.1002/aoc.4157 · Cited by 14 · see citing works
Self-citationManoochehri, M., Asgharinezhad, A. A., & Safaei, M. (2014) · Journal of Chromatographic Science · doi:10.1093/chromsci/bmu131 · Cited by 14 · see citing works
Sadeghi, S., & Sarrafi, N. (2018) · Journal of the Iranian Chemical Society · doi:10.1007/s13738-018-1388-x · Cited by 12 · see citing works
Wang, X., Wang, M., Wang, X., Du, L., Chu, F., Ding, W., Gu, H., & Wang, H. (2018) · Ultrasonics Sonochemistry · doi:10.1016/j.ultsonch.2018.04.006 · Cited by 11 · see citing works
Alharthi, S. S., & Al‐Saidi, H. M. (2022) · Arabian Journal of Chemistry · doi:10.1016/j.arabjc.2022.104094 · Cited by 10 · see citing works
Gösterişli, T. U., Borahan, T., Girgin, A., & Bakırdere, S. (2020) · Environmental Monitoring and Assessment · doi:10.1007/s10661-020-8104-x · Cited by 10 · see citing works
Shaikh, R., Kazi, T. G., Afridi, H. I., Akhtar, A., Baig, J. A., & Arain, M. B. (2019) · Environmental Pollution · doi:10.1016/j.envpol.2019.113305 · Cited by 8 · see citing works
Self-citationShah, F., Naeemullah, Shah, M. R., Kazi, T. G., Afridi, H. I., & Shah, K. (2016) · Journal of Separation Science · doi:10.1002/jssc.201501400 · Cited by 7 · see citing works
Self-citationShah, F., Naeemullah, N., Shah, M. R., Khan, R. A., Ismail, B., Khan, A. M., Khan, A. R., & Ajaz, H. (2017) · New Journal of Chemistry · doi:10.1039/c7nj01948c · Cited by 5 · see citing works
Self-citationFarahani, H., Rasekh, B., & Shokouhi, M. (2023) · Arabian Journal for Science and Engineering · doi:10.1007/s13369-023-07961-z · Cited by 4 · see citing works
Geostandards and Geoanalytical Research Bibliographic Review 2012
Jochum, K. P., Nohl, U., Rothbarth, N., Schwager, B., Stoll, B., & Weis, U. (2013) · Geostandards and Geoanalytical Research · doi:10.1111/j.1751-908x.2013.00286.x · Cited by 4 · see citing works
Ionic liquid-based liquid-phase microextraction techniques
Azorín, C., Benedé, J. L., & Chisvert, A. (2021) · Elsevier eBooks · doi:10.1016/b978-0-12-823334-4.00006-0 · Cited by 3 · see citing works
Mokhtari, B., & pourabdollah, K. E. (2013) · Arabian Journal for Science and Engineering · doi:10.1007/s13369-013-0837-1 · Cited by 1 · see citing works
- Authors
- Shah, F., Soylak, M., Kazi, T. G., & Afridi, H. I.
- Affiliations
- University of Sindh (PK)
- Erciyes University (TR)
- Corresponding author
- Shah, Faheem
- Venue
- Journal of Analytical Atomic Spectrometry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 27
- Issue
- 11
- Pages
- 1960
- ISSN
- 0267-9477 (ISSN-L)
- 1364-5544
- OpenAlex
- W2059958132
- Cited by
- 40
- References
- 32
- Citations by year
- 2023: 1 · 2022: 2 · 2021: 2 · 2020: 5 · 2019: 1 · 2018: 3 · 2017: 5 · 2016: 5 · 2015: 2 · 2014: 5 · 2013: 9
- FWCI
- 5.00
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Analytical Atomic Spectrometry (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Physical Sciences › Chemistry › Electrochemistry › Electrochemical Analysis and Applications
- Physical Sciences › Engineering › Mechanical Engineering › Extraction and Separation Processes
- Keywords
- lead determination, 1-butyl-3-methylimidazolium hexafluorophosphate, Triton X-114, preconcentration, lake water, flame atomic absorption spectrometry
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