Selenium speciation analysis at trace level in soils
Abstract
This paper describes the development of an analytical methodology to determine speciation of selenium present in soils at trace level (μg kg(-1)). The methodology was based on parallel single extractions and high performance liquid chromatography hyphenated to inductively coupled plasma mass spectrometry (HPLC-ICPMS). Two complementary chromatographic separations were used to confirm Se species identity. Different extractants, selected on the basis of sequential extraction schemes, were compared. Ultrapure water, 0.1 molL(-1) phosphate buffer (KH(2)PO(4)/K(2)HPO(4)) at pH 7 and 0.1 molL(-1) sodium hydroxide extractants were finally chosen owing to their efficiency in extracting Se and compatibility with Se species stability. These extractants allow also assessing respectively water-soluble Se (i.e. the most mobile Se fraction), exchangeable Se (i.e. sorbed onto soil component surface) and Se bound to soil organic matter. This methodology gives thus information on Se mobility related to its distribution in soil with preservation of original Se speciation. Detection limits range from 3 to 29ng(Se)L(-1) and from 0.1 to 10 μg(Se)kg(-1), allowing determination of Se species concentrations in extracts from soils containing native Se at trace level. The methodology was applied to three soils with total Se concentrations between 210 and 1560 μg(Se)kg(-1).
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Many studies have reported large amounts of unidentified selenium fractions in soil extracts, up to 100%.
“Many studies have reported large amounts of unidentified Se fractions in soil extracts, up to 100% [150,151,152,153].”
From Selenium Cycling Across Soil-Plant-Atmosphere Interfaces: A Critical Review (2015) · cites this paper as [152]
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Breuninger, E., Tolu, J., Thurnherr, I., et al. (2023) · doi:10.5194/egusphere-2023-1135-rc1
Breuninger, E., Tolu, J., Thurnherr, I., et al. (2023) · doi:10.5194/egusphere-2023-1135-cc1
Comment on egusphere-2023-1135
Breuninger, E., Tolu, J., Thurnherr, I., et al. (2023) · doi:10.5194/egusphere-2023-1135-rc2
Breuninger, E. (2023) · doi:10.5194/egusphere-2023-1135-ac1
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Self-citation
- Authors
- Tolu, J., Le Hécho, I., Bueno, M., Thiry, Y., & Potin-Gautier, M.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Agence Nationale pour la Gestion des Déchets Radioactifs (FR)
- Venue
- Analytica Chimica Acta
- Publisher
- Elsevier BV
- Published
- 2011-01
- Volume
- 684
- Issue
- 1-2
- Pages
- 126-133
- ISSN
- 0003-2670 (ISSN-L)
- OpenAlex
- W2084161683
- Cited by
- 83
- References
- 44
- Citations by year
- 2026: 4 · 2025: 2 · 2024: 4 · 2023: 13 · 2022: 3 · 2021: 7 · 2020: 5 · 2019: 6 · 2018: 3 · 2017: 8 · 2016: 3 · 2015: 6 · 2014: 7 · 2013: 2 · 2012: 6
- FWCI
- 3.13
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Analytica Chimica Acta (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion)
- Funders
- French national radioactive waste management agency (ANDRA)
- Topics
- Health Sciences › Nursing › Nutrition and Dietetics › Selenium in Biological Systems
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Physical Sciences › Environmental Science › Pollution › Heavy metals in environment
- Keywords
- selenium speciation, soil selenium, trace-level analysis, sequential extraction, HPLC-ICP-MS, phosphate buffer extraction, sodium hydroxide extraction, selenium mobility, soil contamination
- MeSH terms
- Chromatography, High Pressure Liquid, Selenium, Soil, Mass Spectrometry, Limit of Detection
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