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Identification and visualisation of microplastics by Raman mapping
Abstract
Recently, microplastics (MP) have emerged as global contaminants of serious concern to human and ecological health. However, identification and visualisation of MP are still a challenge, whether from wastewater, oceans, sediment or soil. Particularly when MP are mapped to visualise their distribution, the background signal from sediment and soil might be high and shield the MP signal from the analysis. Raman has recently received increasing attention, as the complementary spectrum of infrared (IR), because it can overcome the drawbacks of IR analysis including water interference, low lateral resolution and a complex spectrum. Here we show that Raman can identify and visualise MP from a soil/sand background, with almost no sample preparation, no dye, no destruction of the sample and no interference from water/organic matter/fluorescence background signals as well. By mapping image via their characteristic and fingerprint peaks, MP including polystyrene (PS), polyethylene terephthalate (PET), polyethylene (PE), polyvinyl chloride (PVC) and polypropylene (PP) can be individually identified and visualised. The lateral resolution along the focal plane is 1 μm/pixel to catch small MP down to 1 μm.
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“More recently, it was shown that it is possible to characterize MP as small as 100 nm using a 100x objective by Raman spectroscopy by reducing the pixel size to 100 Â 100 (Fang et al. 2020;Sobhani et al. 2019;Sobhani et al. 2020).”
From Microplastics and nanoplastics science: collecting and characterizing airborne microplastics in fine particulate matter (2021) · cites this paper as Sobhani et al. 2019
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Cites
Hidalgo-Ruz, V., Gutow, L., Thompson, R. C., & Thiel, M. (2012) · Environmental Science & Technology · doi:10.1021/es2031505 · Cited by 5,440
Water Analysis: Emerging Contaminants and Current Issues
Richardson, S. D., & Ternes, T. A. (2014) · Analytical Chemistry · doi:10.1021/ac500508t · Cited by 2,144
Microplastic pollution in the surface waters of the Laurentian Great Lakes
Eriksen, M., Mason, S., Wilson, S., Box, C., Zellers, A., Edwards, W., Farley, H., & Amato, S. (2013) · Marine Pollution Bulletin · doi:10.1016/j.marpolbul.2013.10.007 · Cited by 1,937
Plastics in soil: Analytical methods and possible sources
Bläsing, M., & Amelung, W. (2018) · Science of The Total Environment · doi:10.1016/j.scitotenv.2017.08.086 · Cited by 1,655
Small-sized microplastics and pigmented particles in bottled mineral water
Oßmann, B. E., Sarau, G., Holtmannspötter, H., Pischetsrieder, M., Christiansen, S. H., & Dicke, W. (2018) · Water Research · doi:10.1016/j.watres.2018.05.027 · Cited by 1,000
Fries, E., Dekiff, J. H., Willmeyer, J., Nuelle, M.-T., Ebert, M., & Remy, D. (2013) · Environmental Science: Processes & Impacts · doi:10.1039/c3em00214d · Cited by 926
Erni-Cassola, G., Gibson, M. I., Thompson, R. C., & Christie-Oleza, J. A. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.7b04512 · Cited by 848
Research works printed but not linked: 29
- Petrie, 2015, A review on emerging contaminants in wastewaters and the environment: current knowledge, understudied areas and recommendations for future monitoring, Water Res., 72, 3, 10.1016/j.watres.2014.08.053 · DOI · Paper page
- Costa, 2010, On the importance of size of plastic fragments and pellets on the strandline: a snapshot of a Brazilian beach, Environ. Monit. Assess., 168, 299, 10.1007/s10661-009-1113-4 · DOI
- Barnes, 2009, Accumulation and fragmentation of plastic debris in global environments, Philos. Trans. R. Soc. Lond. B Biol. Sci., 364, 1985, 10.1098/rstb.2008.0205 · DOI · Paper page
- Murray, 2011, Plastic contamination in the decapod crustacean Nephrops norvegicus (Linnaeus, 1758), Mar. Pollut. Bull., 62, 1207, 10.1016/j.marpolbul.2011.03.032 · DOI
- Lee, 2014, Sorption capacity of plastic debris for hydrophobic organic chemicals, Sci. Total Environ., 470–471, 1545, 10.1016/j.scitotenv.2013.08.023 · DOI
- Song, 2015, A comparison of microscopic and spectroscopic identification methods for analysis of microplastics in environmental samples, Mar. Pollut. Bull., 93, 202, 10.1016/j.marpolbul.2015.01.015 · DOI
- Li, 2018, Microplastics in freshwater systems: a review on occurrence, environmental effects, and methods for microplastics detection, Water Res., 137, 362, 10.1016/j.watres.2017.12.056 · DOI
- Silva, 2018, Microplastics in the environment: challenges in analytical chemistry - a review, Anal. Chim. Acta, 1017, 1, 10.1016/j.aca.2018.02.043 · DOI
- Maes, 2017, A rapid-screening approach to detect and quantify microplastics based on fluorescent tagging with Nile Red, Sci. Rep., 7, 44501, 10.1038/srep44501 · DOI
- Shim, 2016, Identification and quantification of microplastics using Nile Red staining, Mar. Pollut. Bull., 113, 469, 10.1016/j.marpolbul.2016.10.049 · DOI
- Cincinelli, 2017, Microplastic in the surface waters of the Ross Sea (Antarctica): occurrence, distribution and characterization by FTIR, Chemosphere, 175, 391, 10.1016/j.chemosphere.2017.02.024 · DOI
- Tagg, 2015, Identification and quantification of microplastics in wastewater using focal plane array-based reflectance micro-FT-IR imaging, Anal. Chem., 87, 6032, 10.1021/acs.analchem.5b00495 · DOI
- Schymanski, 2018, Analysis of microplastics in water by micro-Raman spectroscopy: release of plastic particles from different packaging into mineral water, Water Res., 129, 154, 10.1016/j.watres.2017.11.011 · DOI
- Käppler, 2015, Identification of microplastics by FTIR and Raman microscopy: a novel silicon filter substrate opens the important spectral range below 1300 cm−1 for FTIR transmission measurements, Anal. Bioanal. Chem., 407, 6791, 10.1007/s00216-015-8850-8 · DOI
- Enders, 2015, Abundance, size and polymer composition of marine microplastics ≥10μm in the Atlantic Ocean and their modelled vertical distribution, Mar. Pollut. Bull., 100, 70, 10.1016/j.marpolbul.2015.09.027 · DOI · Paper page
- Lenz, 2015, A critical assessment of visual identification of marine microplastic using Raman spectroscopy for analysis improvement, Mar. Pollut. Bull., 100, 82, 10.1016/j.marpolbul.2015.09.026 · DOI
- Vašková, 2011, A powerful tool for material identification: Raman spectroscopy, International journal of mathematical models and methods in applied sciences, 5, 1205
- Ivleva, 2017, Microplastic in aquatic ecosystems, Angew. Chem. Int. Ed., 56, 1720, 10.1002/anie.201606957 · DOI
- Fang, 2008, DNA detection using nanostructured SERS substrates with Rhodamine B as Raman label, Biosens. Bioelectron., 24, 216, 10.1016/j.bios.2008.03.032 · DOI
- Fang, 2009, Metallization of silicon nanowires and SERS response from a single metallized nanowire, Chem. Mater., 21, 3542, 10.1021/cm900132j · DOI
- Kolvenbach, 2014, Emerging chemicals and the evolution of biodegradation capacities and pathways in bacteria, Curr. Opin. Biotechnol., 27, 8, 10.1016/j.copbio.2013.08.017 · DOI
- Burkersroda, 2002, Why degradable polymers undergo surface erosion or bulk erosion, Biomaterials, 23, 4221, 10.1016/S0142-9612(02)00170-9 · DOI · Paper page
- Zhao, 2015, Microplastic in three urban estuaries, China, Environ. Pollut., 206, 597, 10.1016/j.envpol.2015.08.027 · DOI
- Clunies-Ross, 2016, Synthetic shorelines in New Zealand? Quantification and characterisation of microplastic pollution on Canterbury's coastlines, N. Z. J. Mar. Freshw. Res., 50, 317, 10.1080/00288330.2015.1132747 · DOI
- Käppler, 2016, Analysis of environmental microplastics by vibrational microspectroscopy: FTIR, Raman or both?, Anal. Bioanal. Chem., 408, 8377, 10.1007/s00216-016-9956-3 · DOI
- Vaughan, 2004, A Raman microprobe study of electrical treeing in polyethylene, J. Mater. Sci., 39, 181, 10.1023/B:JMSC.0000007743.81011.20 · DOI
- Donelli, 2009, Enzymatic surface modification and functionalization of PET: a water contact angle, FTIR, and fluorescence spectroscopy study, Biotechnol. Bioeng., 103, 845, 10.1002/bit.22316 · DOI
- Corrales, 2004, Study of secondary relaxations of poly(ethylene terephthalate) by photoluminescence technique, Polymer, 45, 1545, 10.1016/j.polymer.2003.12.051 · DOI
- Yang, 1997, Fourier transform Raman spectroscopic characterization of humic substances, Vib. Spectrosc., 14, 105, 10.1016/S0924-2031(96)00044-6 · DOI
Cited by
Sorted by citations
Rahman, L., Mallach, G., Kulka, R., & Halappanavar, S. (2021) · Nanotoxicology · doi:10.1080/17435390.2021.2018065 · Cited by 79
Metadata
- Authors
- Sobhani, Z., Al Amin, M., Naidu, R., Megharaj, M., & Fang, C.
- Venue
- Analytica Chimica Acta
- Publisher
- Elsevier BV
- Published
- 2019-10
- Volume
- 1077
- Pages
- 191-199
- ISSN
- 0003-2670
- Cited by
- 232
- References
- 7
- Language
- en
- Funders
- CRC CARE and the setup
- Flinders University of South Australia
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