Gas phase electrocatalytic conversion of CO2 to syn-fuels on Cu based catalysts-electrodes
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In H cells, solutions with weak buffering abilities have been shown to increase the ratio of C2H4 to CH4.
“Thus in H cells, solutions with weak buffering abilities have been shown to increase the ratio of C2H4 to CH4. [205][206][207]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [205]
Larger cations Cs+ and K+ can suppress the HER.
“suppress the HER, [205,211]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [205]
Larger, less hydrated cations adsorb easier on the catalyst surface, making the potential at the outer Helmholtz plane more positive and thereby reducing the concentration of H+ ions and impeding the formation of H2 and CH4.
“The larger, less hydrated, cations adsorb easier on the catalyst surface making the potential at the outer Helmholtz plane more positive and thereby reducing the concentration of H + ions and impeding the formation of H2 and CH4.[205,209,211,212,214]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [205]
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- Authors
- Gutiérrez-Guerra, N., Moreno-López, L., Serrano-Ruiz, J. C., Valverde, J. L., & de Lucas-Consuegra, A.
- Affiliations
- University of Castilla-La Mancha (ES)
- ORCID
- Valverde, J.L.
- Venue
- Applied Catalysis B: Environmental
- Publisher
- Elsevier BV
- Published
- 2016-07
- Volume
- 188
- Pages
- 272-282
- ISSN
- 0926-3373 (ISSN-L)
- OpenAlex
- W2270836175
- Cited by
- 103
- References
- 40
- Citations by year
- 2026: 4 · 2025: 5 · 2024: 7 · 2023: 10 · 2022: 8 · 2021: 11 · 2020: 18 · 2019: 11 · 2018: 12 · 2017: 11 · 2016: 6
- FWCI
- 3.62
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Applied Catalysis B: Environmental (publishedVersion)
- RUIdeRA - Institutional University Repository (University of Castilla-La Mancha) (submittedVersion, other-oa)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- electrochemical CO2 reduction, copper catalysts, proton exchange membranes, membrane electrode assembly, activated carbon support, carbon nanofibers, graphite support, methanol synthesis, acetaldehyde production, syngas, energy consumption, renewable energy
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