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Nano-size IrOx catalyst of high activity and stability in PEM water electrolyzer with ultra-low iridium loading

Open access
Yu, Haoran, Danilovic, Nemanja, Wang, Yang, Willis, William, Poozhikunnath, Abhinav, Bonville, Leonard, Capuano, Chris, Ayers, Katherine, Maric, Radenka·2018·Applied Catalysis B: Environmental

Abstract

Abstract The balance of catalyst loading, activity and stability remains a challenge for the anode of proton exchange membrane (PEM) water electrolyzers. Here we report a nano-size IrOx/Nafion® composite catalyst that exhibits both outstanding activity for oxygen evolution reaction (OER) and stability in a PEM water electrolyzer. The IrOx/Nafion® catalyst layer is fabricated using a flame-based cost-effect process, reactive spray deposition technology. The IrOx/Nafion® catalyst shows >10 times improvement in OER mass activity compared to IrOx nanoparticles synthesized using the wet chemistry method. The IrOx/Nafion® catalyst also achieved ∼4,500 h of stable operation in MEA electrolyzer at 1.8 A cm−2 and 80 °C with ultra-low iridium loading of 0.08 mg cm−2. Analysis of the IrOx structure and the electrochemical performance revealed three key factors for balancing high stability and activity: (1) high ratio of Ir (IV) to Ir (III) species and high content of hydroxide on the surface; (2) high anodic charge and surface area due to nano-size IrOx particles that are well-dispersed in the Nafion® ionomer electrolyte; (3) homogeneous anode catalyst layer morphology.

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Metadata

Authors
Yu, H., Danilovic, N., Wang, Y., Willis, W., Poozhikunnath, A., Bonville, L., Capuano, C., Ayers, K., & Maric, R.
Venue
Applied Catalysis B: Environmental
Publisher
Elsevier BV
Published
2018-12
Volume
239
Pages
133-146
ISSN
0926-3373 (ISSN-L)
OpenAlex
W2884958793
Cited by
201
References
6
FWCI
3.90
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Nano-size IrOx catalyst of high activity and stability in PEM water electrolyzer with ultra-low iridium loading. https://app.cochat.ai/papers/10.1016/j.apcatb.2018.07.064
The paper
Yu, H., Danilovic, N., Wang, Y., Willis, W., Poozhikunnath, A., Bonville, L., Capuano, C., Ayers, K., & Maric, R. (2018). Nano-size IrOx catalyst of high activity and stability in PEM water electrolyzer with ultra-low iridium loading. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2018.07.064

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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