The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Installing earth-abundant metal active centers to covalent organic frameworks for efficient heterogeneous photocatalytic CO2 reduction
Abstract
Abstract Photocatalytic conversion of CO2 into energy carriers has been recognized as a highly promising strategy for achieving the virtuous carbon cycle in nature. The realization of this process depends on an efficient catalyst to reduce the reaction barrier. Herein, we report a series of transition metal ion modified crystalline covalent organic frameworks (COFs) for the heterogeneous photocatalytic reduction of CO2. By coordinating different kinds of open metal active species into COFs, the resultant DQTP (2,6-diaminoanthraquinone - 2,4,6-triformylphloroglucinol) COF-M (M = Co/Ni/Zn) exerts a strong influence on the activity and selectivity of products (CO or HCOOH). Significantly, DQTP COF-Co exhibits a high CO production rate of 1.02 × 103 μmol h−1 g−1, while DQTP COF-Zn has a high selectivity (90% over CO) for formic acid generation (152.5 μmol h−1 g−1). This work highlights the great potential of using stable COFs as platforms to anchor earth-abundant metal active sites for heterogeneous CO2 reduction.
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Citations
Cites
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Photosynthetic energy conversion: natural and artificial
Barber, J. (2009) · Chem. Soc. Rev. · doi:10.1039/b802262n · Cited by 1,843
Future CO 2 Emissions and Climate Change from Existing Energy Infrastructure
Davis, S. J., Caldeira, K., & Matthews, H. D. (2010) · Science · doi:10.1126/science.1188566 · Cited by 1,399
Recent Advances in Heterogeneous Photocatalytic CO 2 Conversion to Solar Fuels
Li, K., Peng, B., & Peng, T. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02089 · Cited by 1,355
Cited by
Covalent Organic Framework Photocatalysts: Structures and Applications
Wang, H., Wang, H., Wang, Z., Tang, L., Zeng, G., Xu, P., Chen, M., Xiong, T., Zhou, C., Li, X., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00278j · Cited by 1,301
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Liu, S., Wang, M., He, Y., Cheng, Q., Qian, T., & Yan, C. (2023) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2022.214882 · Cited by 236
Metadata
- Authors
- Lu, M., Li, Q., Liu, J., Zhang, F.-M., Zhang, L., Wang, J.-L., Kang, Z.-H., & Lan, Y.-Q.
- Venue
- Applied Catalysis B: Environmental
- Publisher
- Elsevier BV
- Published
- 2019-10
- Volume
- 254
- Pages
- 624-633
- ISSN
- 0926-3373 (ISSN-L)
- OpenAlex
- W2944445042
- Cited by
- 334
- References
- 4
- FWCI
- 7.83
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lu, M., Li, Q., Liu, J., Zhang, F.-M., Zhang, L., Wang, J.-L., Kang, Z.-H., & Lan, Y.-Q. (2019). Installing earth-abundant metal active centers to covalent organic frameworks for efficient heterogeneous photocatalytic CO2 reduction. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2019.05.033
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