Review on solid-solid phase change materials for thermal energy storage: molecular structure and thermal properties
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The use of TES in the energy system increases the overall efficiency of systems by eliminating differences between supply and demand for energy.
“The use of Thermal Energy Storage (TES) in the energy system allows to conserving energy, increase the overall efficiency of the systems by eliminating differences between supply and demand for energy [4]”
From Latent thermal energy storage technologies and applications: A review (2020) · cites this paper as [4]
Materials changing the solid-solid phase are characterised by high energy storage density and small volume changes.
“Materials changing the solid-solid phase are characterised by high energy storage density and small volume changes.”
From Latent thermal energy storage technologies and applications: A review (2020) · cites this paper as [4]
The use of thermal energy storage (TES) in the energy system allows conserving energy.
“The use of Thermal Energy Storage (TES) in the energy system allows to conserving energy, increase the overall efficiency of the systems by eliminating differences between supply and demand for energy [4]”
From Latent thermal energy storage technologies and applications: A review (2020) · cites this paper as [4]
Solid-solid phase change materials are not at risk of leakage and do not require encapsulation.
“In addition, they are not at risk of leakage and do not require encapsulation.”
From Latent thermal energy storage technologies and applications: A review (2020) · cites this paper as [4]
Solid-solid phase change materials are more likely to be used than solids and liquids.
“Thus, they are more likely to be used than solids and liquids [4].”
From Latent thermal energy storage technologies and applications: A review (2020) · cites this paper as [4]
The nucleation process begins depending on the cooling rate, the type of particles and the presence of impurities when the temperature drops below the phase transition temperature.
“The nucleation process begins depending on the cooling rate, the type of particles and the presence of impurities when the temperature drops below the phase transition temperature [4].”
From Latent thermal energy storage technologies and applications: A review (2020) · cites this paper as [4]
In the presence of air, the SS-PCM organometallic transition exhibits slow decomposition at temperatures above 500 K.
“and additionally it was found that in the presence of air exhibit slow decomposition at temperatures above 500 K.”
From Latent thermal energy storage technologies and applications: A review (2020) · cites this paper as [4]
PCMs have the potential to store thermal energy during phase change at nearly constant temperature.
“PCMs have the potential to store thermal energy, during phase change, at an nearly constant temperature”
From Latent thermal energy storage technologies and applications: A review (2020) · cites this paper as [4]
Organometallic SS-PCMs are a group of layer perovskite organometallics with a crystalline structure in which organic and inorganic layers alternate.
“Organometallic SS-PCMs (solid-solid transition) are a group of layer perovskite organometallics.They have a crystalline structure in which organic and inorganic layers alternate [4].”
From Latent thermal energy storage technologies and applications: A review (2020) · cites this paper as [4]
The SS-PCM organometallic transition was found to be chemically stable at moderately high temperatures, completely reversible after 1000 thermal cycles, with a small volume change of 5-10% during the transition.
“In study [4], the SS-PCM organometallic transition was found to be chemically stable at moderately high temperatures, completely reversible after 1000 thermal cycles, with a small volume change of 5À10% during the transition”
From Latent thermal energy storage technologies and applications: A review (2020) · cites this paper as [4]
PCMs ensure a much higher density of thermal energy storage than sensible thermal energy storage material.
“and they ensure a much higher density of thermal energy storage than sensible thermal energy storage material therefore are widely used to store latent heat [4,12].”
From Latent thermal energy storage technologies and applications: A review (2020) · cites this paper as [4]
Inorganic PCMs are best suited for industrial plants to recover heat from high-temperature waste heat.
“Therefore, they are best suited for industrial plants to recover heat from hightemperature waste heat [4].”
From Latent thermal energy storage technologies and applications: A review (2020) · cites this paper as [4]
Inorganic solid PCMs are able to store/release heat energy in the solid phase through one or a combination of energy storage techniques such as magnetic transformations, crystallographic structure transformations, order-disorder transformations, and transformations between amorphous and crystal structure.
“Inorganic solids PCM (SS-PCM) are able to store/release heat energy in the solid phase through one or a combination of energy storage techniques such as magnetic transformations, crystallographic structure transformations, orderÀdisorder transformations, transformations between amorphous structure and crystal structure”
From Latent thermal energy storage technologies and applications: A review (2020) · cites this paper as [4]
Organic molecules capable of reorganising supramolecular interactions can theoretically experience highly exothermic solid-solid phase transitions based on temperature.
“Organic molecules that are capable of reorganising supramolecular interactions, can theoretically experience highly exothermic solid-solid phase transitions based on temperature.”
From Latent thermal energy storage technologies and applications: A review (2020) · cites this paper as [4]
These organic molecules are made of extremely symmetrical and voluminous alcohols: neopentyl glycol (NPG), pentaerythritol (PE), trimethylol propane (TMP), and pentaglycine (PG).
“These are indicated to be made of extremely symmetrical and voluminous alcohols namely as neopentyl glycol (NPG), pentaerythritol (PE), trimethylol propane (TMP), and pentaglycine (PG) [4].”
From Latent thermal energy storage technologies and applications: A review (2020) · cites this paper as [4]
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- Authors
- Fallahi, A., Guldentops, G., Tao, M., Granados-Focil, S., & Van Dessel, S.
- Affiliations
- Worcester Polytechnic Institute (US)
- Venue
- Applied Thermal Engineering
- Publisher
- Elsevier BV
- Published
- 2017-12
- Volume
- 127
- Pages
- 1427-1441
- ISSN
- 1359-4311 (ISSN-L)
- OpenAlex
- W2750691930
- Cited by
- 502
- References
- 77
- Citations by year
- 2026: 55 · 2025: 77 · 2024: 67 · 2023: 66 · 2022: 67 · 2021: 53 · 2020: 67 · 2019: 34 · 2018: 15 · 2017: 1
- FWCI
- 24.87
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- www.elsevier.com/tdm/userlicense/1.0/ (tdm)
- www.elsevier.com/legal/tdmrep-license (tdm)
- www.elsevier.com/open-access/userlicense/1.0/ (am, 278 d)
- doi.org/10.15223/policy-017 (stm-asf)
- doi.org/10.15223/policy-037 (stm-asf)
- doi.org/10.15223/policy-012 (stm-asf)
- doi.org/10.15223/policy-029 (stm-asf)
- doi.org/10.15223/policy-004 (stm-asf)
- Locations
- Applied Thermal Engineering (acceptedVersion)
- Clark Digital Commons (Clark University) (submittedVersion)
- Funders
- National Science Foundation (CMMI-1662903, 1662675)
- Directorate for Engineering, Division of Civil, Mechanical and Manufacturing Innovation (CMMI)
- Structural and Architectural Engineering and Materials program (SAEM)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Phase Change Materials Research
- Physical Sciences › Engineering › Mechanical Engineering › Adsorption and Cooling Systems
- Physical Sciences › Materials Science › Materials Chemistry › Phase-change materials and chalcogenides
- Keywords
- solid-solid phase change materials, thermal energy storage, molecular structure, thermal properties, phase transitions, structure-property relationships, latent heat storage
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