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Mesoporous magnetic biochar composite for enhanced adsorption of malachite green dye: Characterization, adsorption kinetics, thermodynamics and isotherms
Abstract
Abstract This study aimed to prepare a corn straw-derived biochar supported nZVI magnetic composite (nZVI/BC) and evaluate its efficiency in adsorption of malachite green dye (MG). The prepared nZVI/BC composite was characterized by XRD, FTIR, TEM, TEM-EDS, VSM, XPS, TGA, zeta potential and BET surface area. The prepared mesoporous composite showed enhanced efficiency for the adsorption of MG dye. Adsorption models and kinetic results indicated that the adsorption of MG onto nZVI/BC composite was more fitted to Langmuir isotherm and follows second order kinetics. Intraparticle diffusion model indicated that the adsorption follows a three steps mechanism. The maximum adsorption capacity of nZVI/BC composite (515.77 mg MG/g composite) was much higher than most of reported biochar adsorbents. The removal process of MG onto nZVI/BC composite does not only proceed via adsorption mechanism, but also through an oxidative degradation mechanism. The Magnetic character of the biochar enables its easy separation and reuse for many cycles.
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Cites
Characteristics of hemicellulose, cellulose and lignin pyrolysis
Yang, H., Yan, R., Chen, H., Lee, D. H., & Zheng, C. (2007) · Fuel · doi:10.1016/j.fuel.2006.12.013 · Cited by 8,155
Biochar-supported zerovalent iron for removal of various contaminants from aqueous solutions
Zhou, Y., Gao, B., Zimmerman, A. R., Chen, H., Zhang, M., & Cao, X. (2014) · Bioresource Technology · doi:10.1016/j.biortech.2013.11.021 · Cited by 421
Cited by
Osman, A. I., Fawzy, S., Farghali, M., El-Azazy, M., Elgarahy, A. M., Fahim, R. A., Maksoud, M. I. A. A., Ajlan, A. A., Yousry, M., Saleem, Y., et al. (2022) · Environmental Chemistry Letters · doi:10.1007/s10311-022-01424-x · Cited by 515
Eltaweil, A. S., Elgarhy, G. S., El-Subruiti, G. M., & Omer, A. M. (2020) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2020.03.122 · Cited by 382
Self-citationPerspectives of Engineered Biochar for Environmental Applications: A Review
Haghighi Mood, S., Pelaez-Samaniego, M. R., & Garcia-Perez, M. (2022) · Energy & Fuels · doi:10.1021/acs.energyfuels.2c01201 · Cited by 104
Metadata
- Authors
- Eltaweil, A. S., Ali Mohamed, H., Abd El-Monaem, E. M., & El-Subruiti, G. M.
- Venue
- Advanced Powder Technology
- Publisher
- Elsevier BV
- Published
- 2020-03
- Volume
- 31
- Issue
- 3
- Pages
- 1253-1263
- ISSN
- 0921-8831 (ISSN-L)
- OpenAlex
- W2999312880
- Cited by
- 406
- References
- 2
- FWCI
- 18.67
- Type
- journal article
- Language
- en
- Open access
- closed
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- Eltaweil, A. S., Ali Mohamed, H., Abd El-Monaem, E. M., & El-Subruiti, G. M. (2020). Mesoporous magnetic biochar composite for enhanced adsorption of malachite green dye: Characterization, adsorption kinetics, thermodynamics and isotherms. Advanced Powder Technology. https://doi.org/10.1016/j.apt.2020.01.005
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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