The DOI matches its Crossref record; 46 of the 46 references it cites were found in a registry or an index.
A kinetic model for hydrothermal pretreatment of sugarcane straw
Open accessAbstract
This work presents kinetic models of cellulose and hemicellulose extraction during hydrothermal pretreatment of sugarcane straw. Biomass was treated under conditions of 180, 195, and 210°C, using a solid/liquid ratio of 1:10 (w/v). In this study, cellobiose, glucose, formic acid and hydroxymethylfurfural (from cellulosic fraction) and xylose, arabinose, acetic acid, glucuronic acid and furfural (from hemicellulosic fraction) were taken into account in the kinetic parameters determination. The global search algorithm Simulated Annealing was used to fit the models. At 195°C/15min, 85% of hemicellulose and 21% of cellulose removal was reached. For the confidence regions, it was observed that it can be broad, which is coherent with the fact that the parameters are highly correlated. Kinetic models proposed for both cellulosic and hemicellulosic fractions degradation fitted well to the experimental data.
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“Dos Santos Rocha etal. [50] developed a more complex pathway to describe the decomposition of cellulose derived from sugarcane straw, considering cellobiose, glucose, formic acid, and hydroxymethylfurfural (HMF) in the reaction mechanism.”
From Hydrothermal Carbonization of Organic Waste and Biomass: A Review on Process, Reactor, and Plant Modeling (2021) · cites this paper as [50]
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“The model fits well experimental data in a temperature range between 180 and 195 °C, while it overestimates the degradation at 210 °C since it does not consider the difference between crystalline and amorphous cellulose.”
From Hydrothermal Carbonization of Organic Waste and Biomass: A Review on Process, Reactor, and Plant Modeling (2021) · cites this paper as [50]
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Citations
Cites
Optimization by Simulated Annealing
Kirkpatrick, S., Gelatt, C. D., & Vecchi, M. P. (1983) · Science · doi:10.1126/science.220.4598.671 · Cited by 45,134
Determination of Structural Carbohydrates and Lignin in Biomass
Sluiter, A. D., Hames, B. R., Ruiz, R. O., Scarlata, C. J., Sluiter, J. B., Templeton, D. W., & Crocker, D. P. (2012) · Cited by 5,261
Alvira, P., Tomás-Pejó, E., Ballesteros, M., & Negro, M. J. (2010) · Bioresource Technology · doi:10.1016/j.biortech.2009.11.093 · Cited by 3,912 · cited 2×
“( )/ = · + · − ( + ) · (3) Degradation Products (D) Furfural (F)”
BackgroundSaeman, J. F. (1945) · Industrial & Engineering Chemistry · doi:10.1021/ie50421a009 · Cited by 811
Determination of Sugars, Byproducts, and Degradation Products in Liquid Fraction Process Samples
Sluiter, A. D., Hames, B. R., Ruiz, R. O., Scarlata, C. J., Sluiter, J. B., & Templeton, D. J. (2008) · Cited by 793
Kinetic study of the acid hydrolysis of sugar cane bagasse
Aguilar, R., Ramírez, J. A., Garrote, G., & Vázquez, M. (2002) · Journal of Food Engineering · doi:10.1016/s0260-8774(02)00106-1 · Cited by 476
Production of oligosaccharides by autohydrolysis of brewery's spent grain
Carvalheiro, F. (2003) · Bioresource Technology · doi:10.1016/s0960-8524(03)00148-2 · Cited by 306
Differences in the chemical structure of the lignins from sugarcane bagasse and straw
del Río, J. C., Lino, A. G., Colodette, J. L., Lima, C. F., Gutiérrez, A., Martı́nez, Á. T., Lu, F., Ralph, J., & Rencoret, J. (2015) · Biomass and Bioenergy · doi:10.1016/j.biombioe.2015.07.006 · Cited by 303
Validação de metodologia para a caracterização química de bagaço de cana-de-açúcar
Gouveia, E. R., do Nascimento, R. T., Souto-Maior, A. M., & Rocha, G. J. D. M. (2009) · Química Nova · doi:10.1590/s0100-40422009000600026 · Cited by 285
Autohydrolysis of corncob: study of non-isothermal operation for xylooligosaccharide production
Garrote, G., nguez, H. D. X., & Parajó, J. C. (2002) · Journal of Food Engineering · doi:10.1016/s0260-8774(01)00108-x · Cited by 276
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Understanding biomass fractionation in subcritical & supercritical water
Cocero, M. J., Sánchez, Á. C., Abad-Fernández, N., Adamovic, T., Vaquerizo, L., Martínez, C. M., & Pazo-Cepeda, M. V. (2017) · The Journal of Supercritical Fluids · doi:10.1016/j.supflu.2017.08.012 · Cited by 286
Ischia, G., & Fiori, L. (2021) · Waste and Biomass Valorization · doi:10.1007/s12649-020-01255-3 · Cited by 234
Effect of severity factor on the hydrothermal pretreatment of sugarcane straw
Batista, G., de Souza, R. B. A., Pratto, B., Rocha, M. S. R. D. S., & Cruz, A. J. G. (2018) · Bioresource Technology · doi:10.1016/j.biortech.2018.12.073 · Cited by 204
Self-citationMunir, M. T., Mansouri, S. S., Udugama, I. A., Baroutian, S., Gernaey, K. V., & Young, B. R. (2018) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2018.07.039 · Cited by 183
Enzymatic Deconstruction of Sugarcane Bagasse and Straw to Obtain Cellulose Nanomaterials
de Aguiar, J., Bondancia, T. J., Claro, P. I. C., Mattoso, L. H. C., Farinas, C. S., & Marconcini, J. M. (2020) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.9b06806 · Cited by 161
Metadata
- Authors
- dos Santos Rocha, M. S. R., Pratto, B., de Sousa, R., Almeida, R. M. R. G., & Cruz, A. J. G. D.
- Affiliations
- Universidade Federal de São Carlos (BR)
- Universidade Federal de Alagoas (BR)
- Corresponding author
- Cruz, Antonio José Gonçalves da
- Venue
- Bioresource Technology
- Publisher
- Elsevier BV
- Published
- 2017-03
- Volume
- 228
- Pages
- 176-185
- ISSN
- 0960-8524 (ISSN-L)
- OpenAlex
- W2567293112
- Cited by
- 96
- References
- 46
- Citations by year
- 2026: 4 · 2025: 5 · 2024: 10 · 2023: 9 · 2022: 13 · 2021: 9 · 2020: 18 · 2019: 8 · 2018: 9 · 2017: 11
- FWCI
- 4.50
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Bioresource Technology (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Conselho Nacional de Desenvolvimento Científico e Tecnológico
- Ministério da Educação
- Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
- Ministério da Ciência, Tecnologia e Inovação
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Biofuel production and bioconversion
- Physical Sciences › Energy › Fuel Technology › Thermochemical Biomass Conversion Processes
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Anaerobic Digestion and Biogas Production
- Keywords
- hydrothermal pretreatment, sugarcane straw, cellulose degradation, hemicellulose degradation, simulated annealing, kinetic parameter estimation, 5-hydroxymethylfurfural, furfural, cellobiose, xylose, arabinose, glucuronic acid, acetic acid, formic acid
- MeSH terms
- Cellulose, Hydrolysis, Kinetics, Polysaccharides, Refuse Disposal, Biomass, Saccharum
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- dos Santos Rocha, M. S. R., Pratto, B., de Sousa, R., Almeida, R. M. R. G., & Cruz, A. J. G. D. (2017). A kinetic model for hydrothermal pretreatment of sugarcane straw. Bioresource Technology. https://doi.org/10.1016/j.biortech.2016.12.087
