Catalytic hydrothermal liquefaction of Gracilaria corticata macroalgae: Effects of process parameter on bio-oil up-gradation
Abstract
Hydrothermal liquefaction (HTL) of Gracilaria corticata (GC) macroalgae was studied over a series of nickel-iron-layered double oxides (NiFe-LDO) supported on activated bio-char catalysts at 280 °C and different solvents medium. Maximum bio-oil yield (56.2 wt%) was found with 5%Ga/NiFe-LDO/AC catalyst at 280 °C under ethanol solvent. The catalytic HTL up-gradation decreased the bio-char yield significantly. However the bio-oil quality significantly improved with using the 5%Ga/NiFe-LDO/AC catalyst. Also, improved performance with higher amount of bio-oil and lower amounts of bio-char and gas were achieved, which is due the several reactions happening during the HTL process. Catalytic HTL also revealed that introducing NiFe-LDO nanosheets into the activated char could result in NiFe-LDO/AC catalysts of higher surface area and increased active sites. Being impregnated by 5%Ga, catalysts with improved acid sites and thereby, advanced deoxygenation and aromatization activities were achieved. Hence Ga/NiFe-LDO/AC could be considered as a promising catalyst HTL bio-oil upgrading.
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From 2018 to 2020, the number of publications in Bioresource Technology decreased until reaching three publications, and in 2021, five papers were published.
“From 2018 to 2020, the number decreased until reaching three publications, and, in 2021, five papers were published [39, 68–71].”
From Research Progress, Trends, and Future Prospects on Hydrothermal Liquefaction of Algae for Biocrude Production: A Bibliometric Analysis (2024) · cites this paper as [69]
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- Authors
- Li, Y., Zhu, C., Jiang, J., Yang, Z., Feng, W., Li, L., Guo, Y., & Hu, J.
- Affiliations
- Zhoukou Normal University (CN)
- West Virginia University (US)
- Corresponding author
- Li, Lili
- Venue
- Bioresource Technology
- Publisher
- Elsevier BV
- Published
- 2021-01
- Volume
- 319
- Pages
- 124163
- ISSN
- 0960-8524 (ISSN-L)
- OpenAlex
- W3089137087
- Cited by
- 42
- References
- 42
- Citations by year
- 2026: 4 · 2025: 5 · 2024: 6 · 2023: 8 · 2022: 9 · 2021: 10
- FWCI
- 2.12
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Bioresource Technology (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China (21477167, 21806194, 31902419)
- Science and Technology Research Plan Program of Henan Province (172102310712, 182102311110, 192102110084)
- Natural Science Research Program Foundation of High Education Schools of Henan Province (17B610009, 15A520114, CJSZ2018004)
- Opening Project of Henan Province Key Laboratory of Water Pollution Control and Rehabilitation Technology (ZKNU2014118)
- Doctoral Program of Zhoukou Normal University
- School-Based Program of Zhoukou Normal University (zknu B2201606, zknu B3201715, zknuB315213)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
- Physical Sciences › Engineering › Mechanical Engineering › Catalysis and Hydrodesulfurization Studies
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Algal biology and biofuel production
- Keywords
- catalytic hydrothermal liquefaction, Gracilaria corticata, seaweed, bio-oil upgrading, activated carbon support, ethanol solvent, deoxygenation, aromatization, acid sites, nanosheets
- MeSH terms
- Plant Oils, Seaweed, Temperature, Water, Biomass, Gracilaria, Biofuels, Polyphenols
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